Examining the Influence of Silver(I) Ion Coordination Environment in Ionic Liquids on Olefin–Paraffin Separations using Inverse Gas Chromatography
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The capture of volatile radioiodine from nuclear fuel reprocessing off-gas streams remains a critical challenge due to the high volatility, long half-life of 129I, and biological uptake of iodide from the environment. Although silver-based sorbents provide strong iodine chemisorption, their high cost and regulatory classification as mixed radioactive-hazardous waste motivate the development of alternative materials. Here, we report a silver-free Cu2O-Ti3C2Tx MXene hybrid for iodine gas capture at 150 °C. Structural and compositional analyses confirm the formation of Cu2O nanoparticles on Ti3C2Tx nanosheets and their subsequent conversion to thermodynamically stable CuI upon static iodine gas exposure, achieving an iodine mass loading of up to 1115 mg/g. These results demonstrate the potential of Cu2O-Ti3C2Tx MXene as a copper-based alternative to silver sorbents for elevated-temperature iodine gas capture.
ITRPV silver consumption of standard low-temperature and high-temperature paste as compared to reactive silver ink. As little as 16.4 mg of silver is consumed when a busbarless cell is metallized with reactive silver ink.
Silver oxide diffusion tests on separator membranes for use in silver oxide-cadmium and silver oxide-zinc electrochemical cells
The optical properties of silver films and their oxides are measured to better characterize such films for use as sensors for atomic oxygen. Good agreement between properties of measured pure silver films and reported optical constants is observed. Similar comparisons for silver oxide have not been possible because of a lack of reported constants, but self-consistencies and discrepancies in our measured results are described.
Self-metallizing. flexible polyimide films with highly reflective surfaces are prepared by an in situ self-metallization procedure involving thermally initiated reduction of polymer-soluble silver(I) complexes. Polyamic acid solutions are doped with silver(I) acetate and solubilizing agents. Thermally curing the silver(I) doped resins leads to flexible. metallized films which have reflectivities as high as 100%. abrasion-resistant surfaces. thermal stability and, in some cases, electrical conductivity, rendering them useful for space applications.
Separators for silver oxide-zinc and silver oxide- cadmium cells for spacecraft application
Improved separators for silver oxide-zinc and silver oxide-cadmium cells - flexibility and electrolytic conductivity in modified methyl cellulose polyacid films
Improved separators for silver oxide-zinc and silver oxide-cadmium cells for spacecraft application
Tritium tracer and thermogravimetric analysis used to investigate reactions of zinc-silver and cadmium-silver batteries
Barrier properties of membrane separators for silver oxide-zinc and silver oxide-cadmium spacecraft batteries
Wrapping and preswelling techniques, and materials for improved separators for zinc-silver oxide and cadmium-silver oxide cells
Zinc precipitates and thermogravimetric studies of silver oxide for zinc-silver and cadmium-zinc batteries
Formation of silver chloride by action of silver ion on carbon tetrachloride in 2-butanol and methanol
Chemical reactions pertaining to zinc-silver and cadmium-silver batteries
Thermoelectric powers of silver-gold and silver-germanium alloys
Reactions pertaining to zinc-silver and cadmium-silver batteries
Silver-gold and silver-germanium alloys tested for Fermi surface changes with alloying, using thermoelectric power measurements