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At least 19 records

Carbon Storage Site Mapping Inquiry Tool (MapIT)

The Carbon Storage Site Mapping Inquiry Tool (MapIT) is an online web mapping tool designed to help users discover available public-sourced data to facilitate data exploration in support of Underground Injection Control (UIC) Program Class VI Well Site permitting for the geologic sequestration of carbon dioxide.

Pantaleone, Scott↗

Carbon Storage Site Mapping Inquiry Tool (MapIT)

To date, 48 projects, consisting of 139 wells, are currently under review with the Environmental Protection Agency’s (EPA) Underground Injection Control (UIC) Program for Class VI – wells used for geologic sequestration of carbon dioxide. The number of applications submitted is expected to increase in coming years with the increase of the 45Q tax credit available to projects that initiate construction prior to 2033. The amount of data collected to submit a Class VI permit is vast, and often disparate, coming from state, federal, and commercial entities, as well as field-specific data collected within an area of interest. When preparing for site selection and permitting, the initial aggregation of relevant public data can be time intensive. The Carbon Storage Site Mapping Inquiry tool (MapIT) was created to support and accelerate the discovery and accessibility of open-source data and information available across the USA. Data was aggregated and organized based on data types described within the EPA UIC Class VI permit documentation. The online tool enables users to explore hundreds of geospatial data layers and connect to additional external resources, leveraging API and REST services where possible to ensure updates to data in real time. MapIT enables users to explore state and federal data related to geologic, geophysical, structural, hydrologic, and contextual information. In addition to displaying spatial data and linking to external resources, MapIT leverages custom widgets to ensure that internal data and external data are discoverable and accessible. The widgets connect users to resources such as the USGS publications and the USGS Earthquake Catalog based on a user-defined location. This talk will describe data aggregation workflows, data types, data preparation, and tool development for MapIT. The Carbon Storage Site Mapping Inquiry Tool and underlying database are valuable, intuitive resources that empower government, academic, commercial and industry stakeholders to explore, analyze, and acquire carbon storage related data.

Morkner, Paige↗

Waste Site Mapping

Old aircraft considered not restorable are melted down in on-site furnaces to reclaim the aluminum in their airframes. The process produces aluminum ingots and leaves a residue known as "dross." Because dross contains contaminants like lead silver cadmium and copper, Pima County, the dross dumping site, wanted to locate areas where dross had been dumped. Dr. Larry Lepley and Sandra L. Perry used the Landsat Thematic Mapper to screen for dross. A special two-step procedure was developed to separate the dross dumps (typically no larger than 50 meters across) from the desert background. The project has opened the door for similar applications.

Source record↗

The Solvation of the E. coli CheY Phosphorylation Site Mapped by XFMS

The Escherichia coli CheY protein belongs to a large bacterial response regulator superfamily. X-ray hydroxy radical foot-printing with mass spectroscopy (XFMS) has shown that allosteric activation of CheY by its motor target triggers a concerted internalization of aromatic sidechains. We reanalyzed the XFMS data to compare polar versus non-polar CheY residue positions. The polar residues around and including the 57D phosphorylated site had an elevated hydroxy radical reactivity. Bioinformatic measures revealed that a water-mediated hydrogen bond network connected this ring of residues with the central 57D. These residues solvated 57D to energetically stabilize the apo-CheY fold. The abundance of these reactive residues was reduced upon activation. This result was supported by the bioinformatics and consistent with the previously reported activation-induced increase in core hydrophobicity. It further illustrated XFMS detection of structural waters. Direct contacts between the ring residues and the phosphorylation site would stabilize the aspartyl phosphate. In addition, we report that the ring residue, 18R, is a constant central node in the 57D solvation network and that 18R non-polar substitutions determine CheY diversity as assessed by its evolutionary trace in bacteria with well-studied chemotaxis. These results showcase the importance of structured water dynamics for phosphorylation-mediated signal transduction.

59 BASIC BIOLOGICAL SCIENCES↗

Catalytically Active Site Mapping Realized through Energy Transfer Modeling

Abstract The demands of a sustainable chemical industry are a driving force for the development of heterogeneous catalytic platforms exhibiting facile catalyst recovery, recycling, and resilience to diverse reaction conditions. Homogeneous‐to‐heterogeneous catalyst transitions can be realized through the integration of efficient homogeneous catalysts within porous matrices. Herein, we offer a versatile approach to understanding how guest distribution and evolution impact the catalytic performance of heterogeneous host–guest catalytic platforms by implementing the resonance energy transfer (RET) concept using fluorescent model systems mimicking the steric constraints of targeted catalysts. Using the RET‐based methodology, we mapped condition‐dependent guest (re)distribution within a porous support on the example of modular matrices such as metal–organic frameworks (MOFs). Furthermore, we correlate RET results performed on the model systems with the catalytic performance of two MOF‐encapsulated catalysts used to promote CO 2 hydrogenation and ring‐closing metathesis. Guests are incorporated using aperture‐opening encapsulation, and catalyst redistribution is not observed under practical reaction conditions, showcasing a pathway to advance catalyst recyclability in the case of host–guest platforms. These studies represent the first generalizable approach for mapping the guest distribution in heterogeneous host–guest catalytic systems, providing a foundation for predicting and tailoring the performance of catalysts integrated into various porous supports.

Thompson, William J.↗

Catalytically Active Site Mapping Realized through Energy Transfer Modeling

Abstract The demands of a sustainable chemical industry are a driving force for the development of heterogeneous catalytic platforms exhibiting facile catalyst recovery, recycling, and resilience to diverse reaction conditions. Homogeneous‐to‐heterogeneous catalyst transitions can be realized through the integration of efficient homogeneous catalysts within porous matrices. Herein, we offer a versatile approach to understanding how guest distribution and evolution impact the catalytic performance of heterogeneous host–guest catalytic platforms by implementing the resonance energy transfer (RET) concept using fluorescent model systems mimicking the steric constraints of targeted catalysts. Using the RET‐based methodology, we mapped condition‐dependent guest (re)distribution within a porous support on the example of modular matrices such as metal–organic frameworks (MOFs). Furthermore, we correlate RET results performed on the model systems with the catalytic performance of two MOF‐encapsulated catalysts used to promote CO 2 hydrogenation and ring‐closing metathesis. Guests are incorporated using aperture‐opening encapsulation, and catalyst redistribution is not observed under practical reaction conditions, showcasing a pathway to advance catalyst recyclability in the case of host–guest platforms. These studies represent the first generalizable approach for mapping the guest distribution in heterogeneous host–guest catalytic systems, providing a foundation for predicting and tailoring the performance of catalysts integrated into various porous supports.

Thompson, William J.↗

Utilizing remote sensing data for land use decisions for Indian lands in South Dakota.

Evaluation of photographic and thermal infrared imagery acquired at an altitude of 11,500 ft above ground level (in southwestern South Dakota) on Oct. 15, 1970, June 30, 1971, and Aug. 2, 1971, for use in mapping range sites and soils. A density slicing system was used to enhance film optical density differences associated with range sites and soils. The range site boundaries in native rangeland areas were found to be delineated best by a density slicing analysis of color infrared film obtained in August 1971. The range site maps produced by density slicing were superior to existing range inventory maps. The density slicing analysis of color infrared film from the August 1971 flight was best for locating soil boundaries in rangeland areas. To adequately map soils in rangeland areas, data based on density slicing used in conjunction with slope gradient information derived from stereoscopic analyses provided more detailed and accurate information than is presently available from range site and soil maps of the area.

Frazee, C. J.↗

Preliminary analysis of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) for mineralogic mapping at sites in Nevada and Colorado

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data for sites in Nevada and Colorado were evaluated to determine their utility for mineralogical mapping in support of geologic investigations. Equal energy normalization is commonly used with imaging spectrometer data to reduce albedo effects. Spectra, profiles, and stacked, color-coded spectra were extracted from the AVIRIS data using an interactive analysis program (QLook) and these derivative data were compared to Airborne Imaging Spectrometer (AIS) results, field and laboratory spectra, and geologic maps. A feature extraction algorithm was used to extract and characterize absorption features from AVIRIS and laboratory spectra, allowing direct comparison of the position and shape of absorption features. Both muscovite and carbonate spectra were identified in the Nevada AVIRIS data by comparison with laboratory and AIS spectra, and an image was made that showed the distribution of these minerals for the entire site. Additional, distinctive spectra were located for an unknown mineral. For the two Colorado sites, the signal-to-noise problem was significantly worse and attempts to extract meaningful spectra were unsuccessful. Problems with the Colorado AVIRIS data were accentuated by the IAR reflectance technique because of moderate vegetation cover. Improved signal-to-noise and alternative calibration procedures will be required to produce satisfactory reflectance spectra from these data. Although the AVIRIS data were useful for mapping strong mineral absorption features and producing mineral maps at the Nevada site, it is clear that significant improvements to the instrument performance are required before AVIRIS will be an operational instrument.

Kruse, Fred A.↗

Experimental application of LANDSAT to geobotanical prospecting of serpentine outcrops in the central Appalachian Piedmont of North America

The use of LANDSAT as a tool for geobotanical prospecting was studied in a 13,137 sq km area from southeastern Pennsylvania to northern Virginia. Vegetation differences between known serpentine and non-sepentine sites were most easily distinguished on early summer images. A multispectral signature was derived from vegetation of two known serpentine sites and a map was produced of 159 similar signatures of vegetation in the study area. Authenticity of the serpentine nature of the mapped sites was checked via geochemical analysis of collected soils from 14% of the sites. Overall success of geobotanical prospecting was about 35% for the total study area. When vegetation distribution was taken into account, the success rate was 67% for the region north of the Potomac, demonstrates the effectiveness of the multispectral satellite for quickly and accurately locating mineral sensitive vegetation communities over vast tracts of land.

Mielke, H. W.↗

Industrial Stormwater Pollution Prevention Plan (SWPPP) for SNL/CA Reporting Year 2022-2023

The Sandia National Laboratories, California (SNL/CA) site comprises approximately 410 acres and is located in the eastern portion of Livermore, Alameda County, California. The property is owned by the United States Department of Energy and is being managed and operated by National Technology & Engineering Solutions of Sandia, LLC. The facility location is shown on the Site Map(s) in Appendix A. This Stormwater Pollution Prevention Plan (SWPPP) is designed to comply with California’s General Permit for Stormwater Discharges Associated with Industrial Activities (General Permit) Order No. 2015-0122-DWQ (NPDES No. CAS000001) issued by the State Water Resources Control Board (State Water Board) (Ref. 6.1). This SWPPP has been prepared following the SWPPP Template provided on the California Stormwater Quality Association Stormwater Best Management Practice Handbook Portal: Industrial and Commercial (CASQA 2014). In accordance with the General Permit, Section X.A, this SWPPP contains the following required elements: Facility Name and Contact Information; Site Map; List of Significant Industrial Materials; Description of Potential Pollution Sources; Assessment of Potential Pollutant Sources; Minimum BMPs; Advanced BMPs, if applicable; Monitoring Implementation Plan (MIP); Annual Comprehensive Facility Compliance Evaluation (Annual Evaluation); and, Date that SWPPP was Initially Prepared and the Date of Each SWPPP Amendment, if Applicable.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Remote sensing techniques for mapping range sites and estimating range yield

Image interpretation procedures for determining range yield and for extrapolating range information were investigated for an area of the Pine Ridge Indian Reservation in southwestern South Dakota. Soil and vegetative data collected in the field utilizing a grid sampling design and digital film data from color infrared film and black and white films were analyzed statistically using correlation and regression techniques. The pattern recognition techniques used were K-class, mode seeking, and thresholding. The herbage yield equation derived for the detailed test site was used to predict yield for an adjacent similar field. The herbage yield estimate for the adjacent field was 1744 lbs. of dry matter per acre and was favorably compared to the mean yield of 1830 lbs. of dry matter per acre based upon ground observations. Also an inverse relationship was observed between vegetative cover and the ratio of MSS 5 to MSS 7 of ERTS-1 imagery.

Benson, L. A.↗

ES-FE Dataset Exploratory Tool Database Link

The Energy Storage - Fossil Energy (ES-FE) Dataset Explorer tool allows the user to take a deep dive into existing energy storage plant sites mapped to fossil generation sites. The tool also allows users to explore proposed energy storage sites. The explorer creates a dataset of all proposed and existing energy storage plant sites giving the user the ability to inspect various attributes of generation plants and storage plants, including but not limited to generating capacity, generating technology, and storage capacity.

Pena-Cabra, Ivonne A.↗

Kilauea Magnetotelluric Dataset

In 2002 and 2003 a collaborative effort was undertaken between Lawrence Berkeley National Laboratory, Sandia National Laboratories, the USGS Menlo Park, the USGS Hawaiian Volcano Observatory, and Electromagnetic Instruments Inc. to study the Kilauea volcano in Hawaii using the magnetotelluric (MT) technique. The work was motivated by a desire to improve understanding of the magma reservoirs and conduits within Kilauea and the East and Southwest Rift zones, which has implications for understanding Kilaueas plumbing system. An improved understanding of the rift zones has implications in understanding large-scale landslides that are generated in the Hilina Slump, which produce significant impacts on coastal communities. Up to eight stations operated simultaneously, with multiple remote reference sites, and data were processed using multi-station robust processing techniques. In total, data were acquired at 70 sites over the Southwest and East rift zones. Good to excellent quality data were obtained even in the harshest conditions, such as those encountered on the fresh lava flows of the East Rift Zone (ERZ), where electrical contact resistances are on the order of 100 kOhm. This data supports the continuing efforts to increase geothermal power on the island of Hawaii. Each of the 70 EDI files are the MT impedance tensors for 1 site. There is also a description of the processing of the data and a site map showing the locations of each site.

15 GEOTHERMAL ENERGY↗

The Deep Space 1 and Space Technology 4/Champollion Missions

NASA's New Millennium Program (NMP) is designed to develop, test, and flight validate new, advanced technologies for planetary and Earth exploration missions, using a series of low cost spacecraft. Two of NMP's current missions include encounters with comets and asteroids. The Deep Space 1 mission was launched on October 24, 1998 and will fly by asteroid 1992 KD on July 29, 1999, and possibly Comet Wilson-Harrington and/or Comet Borrelly in 2001. The Space Technology 4/Champollion mission will be launched in April, 2003 and will rendezvous with, orbit and land on periodic Comet Tempel 1 in 2006. ST-4/Champollion is a joint project with CNES, the French space agency. The DS-1 mission is going well since launch and has already validated several major technologies, including solar electric propulsion (SEP), solar concentrator arrays, a small deep space transponder, and autonomous navigation. The spacecraft carries two scientific instruments: MICAS, a combined visible camera and UV and IR spectrometers, and PEPE, an ion and electron spectrometer. Testing of the science instruments is ongoing. Following the asteroid encounter in July, 1999, DS-1 will go on to encounters with one or both comets if NASA approves funding for an extended mission. The ST-4/Champollion mission will use an advanced, multi-engine SEP system to effect a rendezvous with Comet P/Tempel 1 in February, 2006, after a flight time of 2.8 years. After orbiting the comet for several months in order to map its surface and determine its gravity field, ST-4/Champollion will descend to the comet's surface and will anchor itself with a 3-meter long harpoon. Scientific experiments include narrow and wide angle cameras for orbital mapping, panoramic and near-field cameras for landing site mapping, a gas chromatograph/mass spectrometer, a combined microscope and infrared spectrometer, and physical properties probes. Cometary samples will be obtained from depths up to 1.4 meters. The spacecraft is solar powered with rechargeable batteries, thus allowing a long duration mission on the nucleus surface. At the time of this writing, the ST-4/Champollion spacecraft was undergoing a major redesign to fit within NASA cost constraints, and approval of the mission is pending.

Weissman, Paul R.↗

Comet and Asteroid Missions in NASA's New Millennium Program

NASA's New Millennium Program (NMP) is designed to develop, test, and flight validate new, advanced technologies for planetary and Earth exploration missions, using a series of low cost spacecraft. Two of NMP's current missions include encounters with comets and asteroids. The Deep Space 1 mission was launched on October 24, 1998 and will fly by asteroid 1992 KD on July 29, 1999, and possibly Comet Wilson-Harrington and/or Comet Borrelly in 2001. The Space Technology 4/Champollion mission will be launched in April, 2003 and will rendezvous with, orbit and land on periodic Comet Tempel 1 in 2006. ST-4/Champollion is a joint project with CNES, the French space agency. The DS-1 mission is going well since launch and has already validated several major technologies, including solar electric propulsion (SEP), solar concentrator arrays, a small deep space transponder, and autonomous navigation. The spacecraft carries two scientific instruments: MICAS, a combined visible camera and UV and IR spectrometers, and PEPE, an ion and electron spectrometer. Testing of the science instruments is ongoing. Following the asteroid encounter in July, 1999, DS-1 will go on to encounters with one or both comets if NASA approves funding for an extended mission. The ST-4/Champollion mission will use an advanced, multi-engine SEP system to effect a rendezvous with Comet P/Tempel 1 in February, 2006, after a flight time of 2.8 years. After orbiting the comet for several months in order to map its surface and determine its gravity field, ST-4/Chainpollion will descend to the comet's surface and will anchor itself with a 3-meter long harpoon. Scientific experiments include narrow and wide angle cameras for orbital mapping, panoramic and near-field cameras for landing site mapping, a gas chromatograph/mass spectrometer, a combined microscope and infrared spectrometer, and physical properties probes. Cometary samples will be obtained from depths up to 1.4 meters. The spacecraft is solar powered with rechargeable batteries, thus allowing a long duration mission on the nucleus surface. At the time of this writing, the ST-4/Champollion spacecraft was undergoing a major redesign to fit within NASA cost constraints, and approval of the mission is pending.

Weissman, Paul R.↗