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At least 19 records

Limits to solar power conversion efficiency with applications to quantum and thermal systems

An analytical framework is presented that permits examination of the limit to the efficiency of various solar power conversion devices. Thermodynamic limits to solar power efficiency are determined for both quantum and thermal systems, and the results are applied to a variety of devices currently considered for use in space systems. The power conversion efficiency for single-threshold energy quantum systems receiving unconcentrated air mass zero solar radiation is limited to 31 percent. This limit applies to photovoltaic cells directly converting solar radiation, or indirectly, as in the case of a thermophotovoltaic system. Photoelectrochemical cells rely on an additional chemical reaction at the semiconductor-electrolyte interface, which introduces additional second-law demands and a reduction of the solar conversion efficiency. Photochemical systems exhibit even lower possible efficiencies because of their relatively narrow absorption bands. Solar-powered thermal engines in contact with an ambient reservoir at 300 K and operating at maximum power have a peak conversion efficiency of 64 percent, and this occurs for a thermal reservoir at a temperature of 2900 K. The power conversion efficiency of a solar-powered liquid metal magnetohydrodydnamic generator, a solar-powered steam turbine electric generator, and an alkali metal thermoelectric converter is discussed.

Byvik, C. E.↗

Tandem photovoltaic solar cells and increased solar energy conversion efficiency

Tandem photovoltaic cells, as proposed by Jackson (1955) to increase the efficiency of solar energy conversion, involve the construction of a system of stacked p/n homojunction photovoltaic cells composed of different semiconductors. It had been pointed out by critics, however, that the total power which could be extracted from the cells in the stack placed side by side was substantially greater than the power obtained from the stacked cells. A reexamination of the tandem cell concept in view of the development of the past few years is conducted. It is concluded that the use of tandem cell systems in flat plate collectors, as originally envisioned by Jackson, may yet become feasible as a result of the development of economically acceptable solar cells for large scale terrestrial power generation.

Loferski, J. J.↗

A new strategy for efficient solar energy conversion: Parallel-processing with surface plasmons

This paper introduces an advanced concept for direct conversion of sunlight to electricity, which aims at high efficiency by tailoring the conversion process to separate energy bands within the broad solar spectrum. The objective is to obtain a high level of spectrum-splitting without sequential losses or unique materials for each frequency band. In this concept, sunlight excites a spectrum of surface plasma waves which are processed in parallel on the same metal film. The surface plasmons transport energy to an array of metal-barrier-semiconductor diodes, where energy is extracted by inelastic tunneling. Diodes are tuned to different frequency bands by selecting the operating voltage and geometry, but all diodes share the same materials.

Anderson, L. M.↗

Toward a III-V Multijunction Space Cell Technology on Si

High efficiency compound semiconductor solar cells grown on Si substrates are of growing interest in the photovoltaics community for both terrestrial and space applications. As a potential substrate for III-V compound photovoltaics, Si has many advantages over traditional Ge and GaAs substrates that include higher thermal conductivity, lower weight, lower material costs, and the potential to leverage the extensive manufacturing base of the Si industry. Such a technology that would retain high solar conversion efficiency at reduced weight and cost would result in space solar cells that simultaneously possess high specific power (W/kg) and high power density (W/m2). For terrestrial solar cells this would result in high efficiency III-V concentrators with improved thermal conductivity, reduced cost, and via the use of SiGe graded interlayers as active component layers the possibility of integrating low bandgap sub-cells that could provide for extremely high conversion efficiency.1 In addition to photovoltaics, there has been an historical interest in III-V/Si integration to provide optical interconnects in Si electronics, which has become of even greater relevance recently due to impending bottlenecks in CMOS based circuitry. As a result, numerous strategies to integrate GaAs with Si have been explored with the primary issue being the approx.4% lattice mismatch between GaAs and Si. Among these efforts, relaxed, compositionally-graded SiGe buffer layers where the substrate lattice constant is effectively tuned from Si to that of Ge so that a close lattice match to subsequent GaAs overlayers have shown great promise. With this approach, threading dislocation densities (TDDs) of approx.1 x 10(exp 6)/sq cm have been uniformly achieved in relaxed Ge layers on Si,5 leading to GaAs on Si with minority carrier lifetimes greater than 10 ns,6 GaAs single junction solar cells on Si with efficiencies greater than 18%,7 InGaAs CW laser diodes on Si,8 and room temperature GaInP red laser diodes on Si.9 Here we report on the first high performance dual junction GaInP/GaAs solar cells grown on Si using this promising SiGe engineered substrate approach.

Ringel, S. A.↗

Effects of Solar Photovoltaic Panels on Roof Heat Transfer

Building Heating, Ventilation and Air Conditioning (HVAC) is a major contributor to urban energy use. In single story buildings with large surface area such as warehouses most of the heat enters through the roof. A rooftop modification that has not been examined experimentally is solar photovoltaic (PV) arrays. In California alone, several GW in residential and commercial rooftop PV are approved or in the planning stages. With the PV solar conversion efficiency ranging from 5-20% and a typical installed PV solar reflectance of 16-27%, 53-79% of the solar energy heats the panel. Most of this heat is then either transferred to the atmosphere or the building underneath. Consequently solar PV has indirect effects on roof heat transfer. The effect of rooftop PV systems on the building roof and indoor energy balance as well as their economic impacts on building HVAC costs have not been investigated. Roof calculator models currently do not account for rooftop modifications such as PV arrays. In this study, we report extensive measurements of a building containing a flush mount and a tilted solar PV array as well as exposed reference roof. Exterior air and surface temperature, wind speed, and solar radiation were measured and thermal infrared (TIR) images of the interior ceiling were taken. We found that in daytime the ceiling surface temperature under the PV arrays was significantly cooler than under the exposed roof. The maximum difference of 2.5 C was observed at around 1800h, close to typical time of peak energy demand. Conversely at night, the ceiling temperature under the PV arrays was warmer, especially for the array mounted flat onto the roof. A one dimensional conductive heat flux model was used to calculate the temperature profile through the roof. The heat flux into the bottom layer was used as an estimate of the heat flux into the building. The mean daytime heat flux (1200-2000 PST) under the exposed roof in the model was 14.0 Watts per square meter larger than under the tilted PV array. The maximum downward heat flux was 18.7 Watts per square meters for the exposed roof and 7.0 Watts per square meters under the tilted PV array, a 63% reduction due to the PV array. This study is unique as the impact of tilted and flush PV arrays could be compared against a typical exposed roof at the same roof for a commercial uninhabited building with exposed ceiling and consisting only of the building envelope. Our results indicate a more comfortable indoor environment in PV covered buildings without HVAC both in hotter and cooler seasons.

Dominguez, A.↗

Single-cell concepts for obtaining photovoltaic conversion efficiency over 30 percent

Although solar photovoltaic conversion efficiencies over 30 percent (one sun, AM1) can be expected for multiple-cell configurations using spectral splitting techniques, the highest practical single-cell conversion efficiency that can be attained using present concepts is estimated to be about 27-28 percent. To achieve conversion efficiencies above 30 percent using single-cell configurations it will be necessary to employ different concepts, such as spectral compression and broad-band detection. The implementation of these concepts would require major breakthroughs that are not anticipated in the near future.

Fan, John C. C.↗

Thermodynamic limits to the efficiency of solar energy conversion by quantum devices

The second law of thermodynamics imposes a strict limitation to the energy converted from direct solar radiation to useful work by a quantum device. This limitation requires that the amount of energy converted to useful work (energy in any form other than heat) can be no greater than the change in free energy of the radiation fields. Futhermore, in any real energy conversion device, not all of this available free energy in the radiation field can be converted to work because of basic limitations inherent in the device itself. A thermodynamic analysis of solar energy conversion by a completely general prototypical quantum device is presented. This device is completely described by two parameters, its operating temperature T sub R and the energy threshold of its absorption spectrum. An expression for the maximum thermodynamic efficiency of a quantum solar converter was derived in terms of these two parameters and the incident radiation spectrum. Efficiency curves for assumed solar spectral irradiance corresponding to air mass zero and air mass 1.5 are presented.

Buoncristiani, A. M.↗

A theoretical analysis of the current-voltage characteristics of solar cells

Various mechanisms which limit the conversion efficiency of silicon solar cells were studied. The effects of changes in solar cell geometry such as layer thickness on performance were examined. The effects of various antireflecting layers were also examined. It was found that any single film antireflecting layer results in a significant surface loss of photons. The use of surface texturing techniques or low loss antireflecting layers can enhance by several percentage points the conversion efficiency of silicon cells. The basic differences between n(+)-p-p(+) and p(+)-n-n(+) cells are treated. A significant part of the study was devoted to the importance of surface region lifetime and heavy doping effects on efficiency. Heavy doping bandgap reduction effects are enhanced by low surface layer lifetimes, and conversely, the reduction in solar cell efficiency due to low surface layer lifetime is further enhanced by heavy doping effects. A series of computer studies is reported which seeks to determine the best cell structure and doping levels for maximum efficiency.

Dunbar, P. M.↗

Status of high-efficiency module design and fabrication

The fabrication of high efficiency solar energy conversion modules (13% efficiency at NOCT - Nominal Operating Cell Temperature) is discussed, with emphasis placed on reducing NOCT, since reduced operating temperature improves both efficiency and module lifetime.

Spitzer, M. B.↗

Solar energy conversion using surface plasmons for broadband energy transport

A new strategy for efficient solar energy conversion based on parallel processing with surface plasmons is introduced. The approach is unique in identifying: (1) a broadband carrier with suitable range for energy transport, and (2) a technique to extract more energy from the more energetic photons, without sequential losses or unique materials for each frequency band. The aim is to overcome the fundamental losses associated with the broad solar spectrum and to achieve a higher level of spectrum splitting than has been possible in semiconductor systems.

Anderson, L. M.↗

NASA's high efficiency and radiation damage solar cell program

The conversion efficiency and the life expectancy of solar cells and arrays were evaluated for space applications. Efforts were made to improve the understanding of the conversion of electromagnetic radiation to useful forms of energy. A broad range of advanced concepts were evaluated.

Randolph, L. P.↗

Tandem concentrator solar cells with 30 percent (AMO) power conversion efficiency

Very high efficiency concentrator solar panels are envisioned as economical and reliable electrical power subsystems for space based platforms of the future. GaAs concentrator cells with very high efficiencies and good sub-bandgap transmissions can be fabricated on standard wafers. GaSb booster cell development is progressing very well; performance characteristics are still improving dramatically. Consistent GaAs/GaSb stacked cell AMO efficiencies greater than 30 percent are expected.

Avery, J. E.↗