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At least 19 records

Analyzing existing and planned nuclear facilities as potential sources for unusual xenon radionuclides (127Xe, 129mXe, 125Xe, 122Xe)

Unusual xenon radionuclides (127Xe, 129mXe, 125Xe, 122Xe) were observed during temporary operation of a radioxenon monitoring station in the vicinity of a high flux nuclear reactor and a spallation neutron source. Meteorological modeling showed that these two facilities were the most likely source of these emissions. Because 127Xe by itself, and this mix of radionuclides together can lead to false-positive reports for the four xenon radionuclides of interest (135Xe, 133Xe, 133mXe, and 131mXe), it is important for radioxenon monitoring station operators to be aware of potential sources of these interfering radionuclides. This work will look at the location and source intensities of both high flux nuclear reactors, and spallation neutron sources around the world, to see if the potential exists in other regions for production and observance of the unusual xenon radionuclides (127Xe, 129mXe, 125Xe, 122Xe).

07 ISOTOPE AND RADIATION SOURCES↗

Potential Sources of Polarized Light from a Plant Canopy

Field measurements have demonstrated that sunlight polarized during a first surface reflection by shiny leaves dominates the optical polarization of the light reflected by shiny-leafed plant canopies having approximately spherical leaf angle probability density functions ("Leaf Angle Distributions" - LAD). Yet for other canopies - specifically those without shiny leaves and/or spherical LADs - potential sources of optically polarized light may not always be obvious. Here we identify possible sources of polarized light within those other canopies and speculate on the ecologically important information polarization measurements of those sources might contain.

Polarized Light↗

Dissociation of metastable O2 as a potential source of atmospheric odd oxygen

An analysis of the possible dissociation of metastable oxygen molecules subject ot constraints imposed by selection rules for molecular transitions, airglow observations, and atmospheric chemistry leads to the following conclusions. Dissociation of O2(b1Sigma g +) must produce a negligible number of oxygen atoms at all altitudes in the earth's atmosphere. However, if the dissociation cross section of O2(a1Delta g) has a maximum value in the range 10 to the -20th to 10 to the -19th/sq cm, then the process O2(a1Delta g) + h(nu) yields O2(C3Delta u) yields O(3P) + O(3P) will constitute a significant, and potentially the major, source of odd oxygen in the uppermost stratosphere and mesosphere.

Frederick, J. E.↗

Machine learning-assisted identification of potential sources of bias in measurements of prompt-fission neutron spectra

Unrecognized sources of uncertainty (USU) can bias the reported mean and/or covariance of experimental nuclear data. These biases, in turn, can propagate through evaluated nuclear data to application simulations or may poorly inform nuclear theory that is fitted to the experimental data. Such unknown sources of bias must be tied to the inherent physical constituents of the measurements such as the characteristics of a detector response or a background reduction technique. Here, in this article, a sparse Bayesian learning model is used to support experts in their efforts to identify and characterize USU in experimental prompt fission neutron spectra (PFNS) for spontaneous fissioning of 252 Cf by linking observed biases to features of the measurement system. Three different bias components were found. The first acts as a verification case for the algorithm as it identifies a bias coming from a well-known source related to the use of 6 Li in the neutron detection system. The second two cases demonstrate how this method can benefit the evaluation of experimental nuclear data by identifying, quantifying, and relating unknown biases to potential causes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Decarboxylation of Carbon Compounds as a Potential Source for CO2 and CO Observed by SAM at Yellowknife Bay, Gale Crater, Mars

Martian carbon was detected in the Sheepbed mudtsone at Yellowknife Bay, Gale Crater, Mars by the Sample Analysis at Mars (SAM) instrument onboard Curiosity, the rover of the Mars Science Laboratory missio]. The carbon was detected as CO2 thermally evolved from drilled and sieved rock powder that was delivered to SAM as a <150-micron-particle- size fraction. Most of the CO2 observed in the Cumberland (CB) drill hole evolved between 150deg and 350deg C. In the John Klein (JK) drill hole, the CO2 evolved up to 500deg C. Hypotheses for the source of the the CO2 include the breakdown of carbonate minerals reacting with HCl released from oxychlorine compounds, combustion of organic matter by O2 thermally evolved from the same oxychlorine minerals, and the decarboxylation of organic molecules indigenous to the martian rock sample. Here we explore the potential for the decarboxylation hypothesis.

Eigenbrode, J. L.↗

Martian Magmatic-Driven Hydrothermal Sites: Potential Sources of Energy, Water, and Life

Magmatic-driven processes and impact events dominate the geologic record of Mars. Such recorded geologic activity coupled with significant evidence of past and present-day water/ice, above and below the martian surface, indicate that hydrothermal environments certainly existed in the past and may exist today. The identification of such environments, especially long-lived magmatic-driven hydrothermal environments, provides NASA with significant target sites for future sample return missions, since they (1) could favor the development and sustenance of life, (2) may comprise a large variety of exotic mineral assemblages, and (3) could potentially contain water/ice reservoirs for future Mars-related human activities. If life developed on Mars, the fossil record would presumably be at its greatest concentration and diversity in environments where long-term energy sources and water coexisted such as at sites where long-lived, magmatic-driven hydrothermal activity occurred. These assertions are supported by terrestrial analogs. Small, single-celled creatures (prokaryotes) are vitally important in the evolution of the Earth; these prokaryotes are environmentally tough and tolerant of environmental extremes of pH, temperature, salinity, and anoxic conditions found around hydrothermal vents. In addition, there is a great ability for bacteria to survive long periods of geologic time in extreme conditions, including high temperature hydrogen sulfide and sulfur erupted from Mount St. Helens volcano. Our team of investigators is conducting a geological investigation using multiple mission-derived datasets (e.g., existing geologic map data, MOC imagery, MOLA, TES image data, geophysical data, etc.) to identify prime target sites of hydrothermal activity for future hydrological, mineralogical, and biological investigations. The identification of these sites will enhance the probability of success for future missions to Mars.

Anderson, R. C.↗

Critical mineral source potential from oil & gas produced waters in the United States

The volume of produced water, a by-product of oil & gas operations and other energy processes, has been growing across the United States (U.S.) along with the need to manage or recycle this wastewater. Produced water contains many naturally occurring elements of varying concentrations, including critical minerals which are essential to the clean energy transition. However, the current understanding of critical mineral concentrations in produced water and the associated volumes across the U.S. is limited. This study has assessed available databases and literature to gain insight into the presence and concentration of five high priority critical minerals, namely cobalt, lithium, magnesium, manganese, and nickel. The U.S. Geological Survey's National Produced Waters Geochemical Database was the main data source used for determining average critical mineral concentrations in produced water from the major oil and gas reservoirs in the U.S. The volumes of produced water for these major reservoirs were coupled with these concentrations to provide insights into where critical minerals are likely to have high abundance and therefore more recovery options. The analysis indicated the highest recovery potential for lithium and magnesium from produced water in the Permian basin and the Marcellus shale region. However, these assessments should be considered conservative due to the limited availability of reliable concentration data. Finally, it is expected more critical mineral recovery options could emerge with comprehensive characterization data from more recent and representative sources of produced water.

54 ENVIRONMENTAL SCIENCES↗

Binary neutron star mergers as potential sources for ultrahigh-energy cosmic rays and high-energy neutrinos

Recent studies suggest that the most energetic cosmic rays, exceeding 100 EeV, may primarily consist of 𝑟-process nuclei. This highlights binary neutron star mergers and collapsars as promising sources of ultrahigh-energy cosmic rays (UHECRs). Building on these insights, we examine the conditions that facilitate the efficient production of UHE 𝑟-process nuclei during the prompt radiation (PR), extended emission (EE), and plateau emission phases of short gamma-ray bursts (sGRBs) following neutron star mergers. Our study reveals that jets associated with the PR phase, characterized by typical bulk Lorentz factors (≳ 400–500), dissipation radii, and magnetic field strengths, can accelerate 𝑟-process nuclei to energies ≳ 100 EeV, while preserving them during propagation within the source. Additionally, we investigate the production of HE neutrinos from photomeson and hadronic interactions, as well as from the 𝛽 decay of accelerated 𝑟-process nuclei. We find that the HE neutrino fluxes from sGRBs, mainly produced via photomeson interactions, are significantly limited to preserve the accelerated heavy nuclei, leading to lower fluxes than the predictions without allowing for contributions to UHECRs. Our results suggest that sGRBs may potentially contribute to UHECRs during the PR phase and to HE neutrinos during the EE phase—a scenario that can be tested by future neutrino observatories.

Cosmic ray sources↗

Ejection of Dust From the Ocean as a Potential Source of Marine Ice Nucleating Particles

Oceans are, generally, relatively weak sources of ice nucleating particles (INPs). Thus, dust transported from terrestrial regions can dominate atmospheric INP concentrations even in remote marine regions. Studies of ocean-emitted INPs have focused upon sea spray aerosols containing biogenic species. Even though large concentrations of dust are transported over marine regions, resuspended dust has never been explicitly considered as another possible source of ocean-emitted INPs. Current models assume that deposited dust is not re-emitted from surface waters. Our laboratory studies of aerosol particles produced from coastal seawater and synthetic seawater doped with dust show that dust can indeed be ejected from water during bubble bursting. INP concentration measurements show these ejected dust particles retain ice nucleating activity. Doping synthetic seawater to simulate a strong dust deposition event produced INPs active at temperatures colder than -13 °C and INP concentrations one to two orders of magnitude greater than either lab sea spray or marine boundary layer measurements. The relevance of these laboratory findings is highlighted by single particle composition measurements along the Californian coast where at least 9% of dust particles were mixed with sea salt. Additionally, global modeling studies show that resuspension of dust from the ocean could exert the most impact over the Southern Ocean, where ocean-emitted INPs are thought to dominate atmospheric INP populations. More work characterizing the factors governing the resuspension of dust particles is required to understand the potential impact upon clouds.

54 ENVIRONMENTAL SCIENCES↗

Transient desorption of water vapor - A potential source of error in upper atmosphere rocket experiments

Results of measurements of the outgassing rates of samples of materials and surface finishes used on the outer skins of rocket-borne experiment packages in simulated rocket ascents. The results showed outgassing rates for anodized aluminum in the second minute of flight which are two to three orders of magnitude higher than those given in typical tables of outgassing rates. The measured rates for aluminum with chromate conversion surface coatings were also abnormally high. These abnormally high initial rates fell quickly after about five to ten minutes to values comparable with those in the published literature. It is concluded that anodized and chromate conversion coatings on the aluminum outer surfaces of a sounding rocket experiment package will cause gross distortion of the true water vapor environment.

Kendall, B. R. F.↗

An evaluation of discarded tires as a potential source of fuel

The destructive distillation of rubber tire samples was studied by thermogravimetry, differential scanning calorimetry, combustion calorimetry, and mass spectroscopy. The decomposition reaction was found to be exothermic and produced a mass loss of 65%. The products from the distillation process were a solid residue with a heating value of about -30 MJ/kg, a liquid with a heating value of about -40 MJ/kg, and a combustible gas of undetermined heating value. The gas evolution curves which were obtained indicate that a variety of organic materials are evolved simultaneously during decomposition of the rubber polymer.

Collins, L. W.↗

Characterization of potential sources of magnetic anomalies within the crust in a tectonically active region: Amphibolites and migmatites from Potrillo Maar, New Mexico

The purpose was to characterize the oxide mineralogy and petrology of samples collected from Potrillo Maar, New Mexico with the goal of explaining the magnetic anamoly that is observed over this region from remote sensing. Potrillo Maar is a diatreme that has brought rocks from all depths in the crust to the surface almost instantaneously. The samples are therefore thought to be representative of the crust as it exists today below this portion of the Rio Grande Rift. It is generally believed that oxide minerals (magnetite, hematite, etc.) are responsible for the magnetic signature of the crust. The samples from Portillo Maar therefore offer a unique opportunity to examine the magnetic mineralogy of the entire crust. The results indicate that the magnetic anamoly observed over Rio Grande Rift may be consequence of the tectonic activity that caused mylonitization of the rocks and allowed the infiltration of oxidizing fluids.

Spear, F. S.↗

Laser microprobe study of cosmic dust (IDPs) and potential source materials

The study of cosmic dust or interplanetary dust particles (IDP) can provide vital information about primitive materials derived primarily from comets and asteroids along with a small unknown fraction from the nearby interstellar medium. The study of these particles can enhance our understanding of comets along with the decoding of the history of the early solar system. In addition the study of the cosmic dust for IDP particles can assist in the elucidation of the cosmic history of the organogenic elements which are vital to life processes. Studies to date on these particles have shown that they are complex, heterogeneous assemblages of both amorphous and crystalline components. In order to understand the nature of these particles, any analytical measurements must be able to distinguish between the possible sources of these particles. A study was undertaken using a laser microprobe interfaced to a quadrupole mass spectrometer for the analysis of the volatile components present in cosmic dust particles, terrestrial contaminants present in the upper atmosphere, and primitive carbonaceous chondrites. From the study of the volatiles released from the carbonaceous materials it is hoped that one could distinguish between components and sources in the IDP particles analyzed. The technique is briefly described and results for the CI, CM, and CV chondrites and cosmic dust particle W7027B8 are presented.

Gibson, E. K., Jr.↗

Iron-rich clay minerals on Mars - Potential sources or sinks for hydrogen and indicators of hydrogen loss over time

Although direct evidence is lacking, indirect evidence suggests that iron-rich clay minerals or poorly-ordered chemical equivalents are widespread on the Martian surface. Such clays can act as sources or sinks for hydrogen ('hydrogen sponges'). Ferrous clays can lose hydrogen and ferric clays gain it by the coupled substitution Fe(3+)O(Fe(2+)OH)-1, equivalent to minus atomic H. This 'oxy-clay' substitution involves only proton and electron migration through the crystal structure, and therefore occurs nondestructively and reversibly, at relatively low temperatures. The reversible, low-temperature nature of this reaction contrasts with the irreversible nature of destructive dehydroxylation (H2O loss) suffered by clays heated to high temperatures. In theory, metastable ferric oxy-clays formed by dehydrogenation of ferrous clays over geologic time could, if exposed to water vapor, extract the hydrogen from it, releasing oxygen.

Burt, D. M.↗

Near-Surface Geologic Units Exposed Along Ares Vallis and in Adjacent Areas: A Potential Source of Sediment at the Mars Pathfinder Landing Site

A sequence of layers, bright and dark, is exposed on the walls of canyons, impact craters and mesas throughout the Ares Vallis region, Chryse Planitia, and Xanthe Terra, Mars. Four layers can be seen: two pairs of alternating dark and bright albedo. The upper dark layer forms the top surface of many walls and mesas. The upper dark-bright pair was stripped as a unit from many streamlined mesas and from the walls of Ares Valles, leaving a bench at the top of the lower dark layer, approximately 250 m below the highland surface on streamlined islands and on the walls of Ares Vallis itself. Along Ares Vallis, the scarp between the highlands surface and this bench is commonly angular in plan view (not smoothly curving), suggesting that erosion of the upper dark-bright pair of layers controlled by planes of weakness, like fractures or joints. These near-surface layers in the Ares Vallis area have similar thicknesses, colors, and resistances to erosion to layers exposed near the tops of walls in Valles Marineris (Treiman et al.) and may represent the same pedogenic hardpan units. From this correlation, and from analogies with hardpans on Earth, the light-color layers may be cemented by calcite or gypsum. The dark layers are likely cemented by an iron-bearing mineral. Mars Pathfinder instruments should permit recognition and useful analyses of hardpan fragments, provided that clean uncoated surfaces are accessible. Even in hardpan-cemented materials, it should be possible to determine the broad types of lithologies in the Martian highlands. However, detailed geochemical modeling of highland rocks and soils may be compromised by the presence of hardpan cement minerals.

Treiman, Allan H.↗

New Potential Sources for Black Onaping Carbon

One intriguing and important issue of the Sudbury Structure concerns the source of the relatively large amount of C in the Onaping Formation Black member. This dilemma was recently addressed, and the conclusion was reached that an impactor could not have delivered all of the requisite C. Becker et al. have suggested that much of the C came from the impactor and reported the presence of interstellar He "caged" inside some fullerenes that may have survived the impact. So, conceivably, the C inventory in the Sudbury Structure comes from both target and impactor materials, although the known target rocks have little C. We discuss here the possibility of two terrestrial sources for at least some of the C: (1) impact evaporation/dissociation of C from carbonate target rocks and (2) the presence of heretofore-unrecognized C-rich (up to 26 wt%) siliceous "shale," fragments, which are found in the upper, reworked Black member. Experimental: Hypervelocity impact of a 0.635-diameter Al projectile into dolomite at 5.03 km/s (performed at the Ames Research Center vertical gun range) produced a thin, black layer (= 0.05 mm thick) that partially lined the crater and coated impactor remnants. Scanning electronic microscope (SEM) imagery shows this layer to be spongelike on a submicron scale and Auger spectroscopic analyses yield: 33% C, 22% Mg, 19% 0, and 9% Al (from the projectile). Elemental mapping shows that all of the available 0 is combined with Ca and Mg, Al is not oxidized, and C is in elemental form. Dissociation efficiency of C from CO2 is estimated to be <10% of crater volume. Raman spectroscopy indicates that the C is highly disorganized graphite. Another impact experiment [4] also produced highly disordered graphite from a limestone target (reducing collector), in addition to small amounts of diamond/lonsdaleite/chaoite (oxidizing collector). These experiments confirm the reduction of C from carbonates in impact vapor plumes. Observational: SEM observations and microprobe analyses of small, black shalelike inclusions in the upper Black Onaping indicate high C contents (7-26 wt% avg. = 16%). They contain mostly quartz and carbonaceous matter with small amounts of altered K-feldspar, clays, Fe oxide, and a sulfide. No evidence of shock is seen in quartz, and overall characteristics indicate a natural, lightly metamorphosed carbonaceous shale or mudstone that probably existed as a preimpact rock in the target region and distal fragments washed in during early crater filling. Fragments range in size from tens of microns to cm and increase in abundance in the upper Black toward the Onwatin contact, although their distribution is highly irregular. This increase corresponds to an increase in "organic" C with increasingly negative delta-13 C values and S, together with a decrease in fullerene abundance. In addition, we have found soot in acid-demineralized residues of the Onwatin but not in the Onaping samples. These data could be consistent with impact plume and atmospheric chemical processes, with possible diageneric ovedays. We are analyzing carbonaceous fractions of the Onaping and Onwatin to determine diagnostic C isotopic signatures Analyses by Whitehead et al. on bulk samples revealed no definitive source or processes, although delta-13 C values for "organic" C overlapped those for some meteorites. Discussion: If impact evaporation of Sudbury target carbonates did occur, then where are the carbonates? Distal carbonate (limestone/dolostone) exposures of the Espanola Formation (Huronian Supergroup) are generally thin-bedded, although remnants that partially encompass the Sudbury Crater are variable in thickness and may locally reach 250 m . If a carbonate thickness of 100-200 in existed at the target site, then copious amounts of C could have been reduced by impact processing of carbonates and also C-shale, depending on the efficiency of the processing and the amount of postimpact oxidation. Conclusion: The Sudbury crater offers a unique opportunity to study preserved characteristics of immediate carbonaceous fallback matter and particles of short-term residency in the impact plume as well as dust/aerosols from postimpact atmospheric processing.

Bunch, T. E.↗