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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Using Spectral Measurements to Characterize Solar Reference Cells on a Two-Axis Tracker

A study is commencing relating the spectral responsivity of reference cells in the field to changing spectral distribution during the day. Initial results indicate that measurements of the incident spectral distribution can be used to match results of reference cell measurements on a two-axis tracker with a standard deviation of ±0.25% under clear-sky conditions. Initial results are provided. As more data are obtained covering a variety of field conditions and locations, the robustness of these results will be tested. The website https://midcdmz.nrel.gov/apps/sitehome.pl?site=PVRES contains the data generated by this project.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Determining g A / g V with High-Resolution Spectral Measurements Using a LiInSe 2 Bolometer

Neutrinoless double beta decay (0νββ) processes sample a wide range of intermediate forbidden nuclear transitions, which may be impacted by quenching of the axial vector coupling constant (g A /g V ), the uncertainty of which plays a pivotal role in determining the sensitivity reach of 0νββ experiments. Here we present measurements performed on a high-resolution LiInSe 2 bolometer in a “source = detector” configuration to measure the spectral shape of the fourfold forbidden β decay of 115 In . The value of g A /g V is determined by comparing the spectral shape of theoretical predictions to the experimental β spectrum taking into account various simulated background components as well as a variety of detector effects. We find evidence of quenching of g A /g V at >5 σ with a model-dependent quenching factor of 0.655 ± 0.002 as compared to the free-nucleon value for the interacting shell model. We also measured the 115 In half-life to be [5.18 ± 0.06(stat) $^{+0.005}_{- 0.015}$(sys)] x 10 14 yr within the interacting shell model framework. This Letter demonstrates the power of the bolometeric technique to perform precision nuclear physics single-β decay measurements, which along with improved nuclear modeling can help reduce the uncertainties in the calculation of several decay nuclear matrix elements including those used in 0νββ sensitivity calculations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Improved field evaluation of reference cells using spectral measurements

Output from an IMT reference solar cell mounted on a one-axis tracking surface is investigated using spectral measurements covering the 350–1650 nm range for selected days throughout the year. Comparisons are made to a Class-A pyranometer also mounted on the one-axis tracking surface. Systematic biases over the day and year are observed in the ratio of the reference cell’s measurements to reference pyranometer measurements. This systematic bias is associated with the spectral, temperature, and angle-of-incident effects that differ between the reference cell and the reference pyranometer. The comparison is done for selected clear and totally cloudy days to determine the magnitude of the effects and to characterize the influence of these effects on the reference cell measurements. A model to calculate the reference cell output based on spectral irradiance and reference cell temperature is introduced.

14 SOLAR ENERGY↗

Effect of Time Window and Spectral Measurement Options on Empirical Green’s Function Analysis Using DAS Array and Seismic Stations

The recorded seismic waveform is a convolution of event source term, path term, and station term. Removing high-frequency attenuation due to path effect is a challenging problem. Empirical Green’s function (EGF) method uses nearly collocated small earthquakes to correct the path and station terms for larger events recorded at the same station. However, this method is subject to variability due to many factors. Here, we focus on three events that were well recorded by the seismic network and a rapid response distributed acoustic sensing (DAS) array. Using a suite of high-quality EGF events, we assess the influence of time window, spectral measurement options, and types of data on the spectral ratio and relative source time function (RSTF) results. Increased number of tapers (from 2 to 16) tends to increase the measured corner frequency and reduce the source complexity. Extended long time window (e.g., 30 s) tends to produce larger variability of corner frequency. The multitaper algorithm that simultaneously optimizes both target and EGF spectra produces the most stable corner-frequency measurements. The stacked spectral ratio and RSTF from the DAS array are more stable than two nearby seismic stations, and are comparable to stacked results from the seismic network, suggesting that DAS array has strong potential in source characterization.

58 GEOSCIENCES↗

Study of Classifiers for U-235 Source Signatures Using Gamma Spectral Measurements

Signatures associated with low-level U-235 sources are studied from a classification analytics perspective, using NaI gamma-ray spectral measurements from detectors located at various distances from the source. Data sets collected at a shielded facility are utilized, wherein the source is introduced via a conduit into a formation of 21 NaI detectors deployed over 6 x 6 meters area in a formation of two concentric circles and one spiral. The activity levels in the spectral regions associated with potential U-235 signatures are estimated as counts at 1 second intervals, and are used as features to train classifiers for detecting the presence of the source. Eight different classifiers are trained and tested using the background and source measurements collected over multiple experimental runs. As expected, the classifier performance improved overall as measurements from the detectors closer to source are used, but also revealed unexpectedly low performance by two detectors that are identically produced and configured as others. Six of eight classifiers have an overall comparable performance, for example, three of them achieved zero training error and 99% detection at 4% false alarm rate for a detector located 1.3 meters away from the source. Also, larger training sets led to improved classification performance across all classifiers, and interestingly, the classifiers with the minimum training error did not necessarily achieve the highest classification performance on test data.

Rao, Nageswara↗

Direct spectral measurements of midinfrared radiation from a laser wakefield accelerator

The formation of plasma waves during laser wakefield acceleration (LWFA) produces time-dependent frequency shifts in the driving laser pulse, extending its spectral content to the infrared. We present direct spectral measurements of multi-mJ infrared pulses from an LWFA. Experimental beam profile measurements and three-dimensional particle-in-cell simulations suggest high focusability of these pulses. Further, particle-in-cell simulations demonstrate that the measurement of side-scattered infrared radiation may serve as a diagnostic of plasma waves and the efficiency of spectral broadening during LWFA.

43 PARTICLE ACCELERATORS↗

Neutron spectral measurements at the BNL NSLS-II synchrotron facility

During the first week of August 2022, Tim Gildea of Los Alamos National Laboratory’s (LANL) RP-SVS group performed a series of neutron spectral measurements at the National Synchrotron Light Source II (NSLS-II) 3GeV facility located at Brookhaven National Lab (BNL)1 . These measurements were conducted under Memorandum Purchase Order (MPO) 413911 with the objective of gaining an accurate understanding of the photoneutron fields generated under normal and selected fault conditions. The spectral data collected during the course of the study was analyzed at LANL and the results form the basis of this report.

61 RADIATION PROTECTION AND DOSIMETRY↗

First spectral measurement of deuterium-tritium fusion γ rays in inertial fusion experiments

Here, the R-matrix analysis of A = 5 nuclear systems has been partially validated by applying the technique to the 5 Li system and comparing the predicted γ-ray spectrum with historical data. R-matrix analysis of the similar 5 He system was then used to predict the γ-ray spectral shape for the deuterium-tritium (DT) reaction. The resulting spectra have been used in the analysis of DT implosions on the Omega laser where the γ-ray interaction rate was measured by a gas Cherenkov detector. Comparison of predictions to experiment confirmed the presence of both 16.75 and ≈ 13 MeV γ-ray contributions; analysis, using R-matrix spectra, yielded a ratio of γ-ray emission from a transition to the intermediate excited state to that from a transition to the ground state of (2.1 ± 0.4):1, substantiating the first spectral measurement of the DT fusion γ ray in an inertial fusion environment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Photon counting with intensified charge coupled device (ICCD) – II. Laser induced breakdown spectroscopy (LIBS) spectral measurement

This study explores the application of photon counting (PC) to enhance the resolution of spectra acquired by an intensified charge-coupled device (ICCD) detector, with a focus on analytical atomic emission spectrometry using laser-induced breakdown spectroscopy (LIBS) as a use-case example. It demonstrates that, for spectra obtained with the same spectrometer–ICCD system, PC provides higher spectral resolution compared to conventional analog detector readout. This enhancement is particularly evident in the line wings of spectral peaks, facilitating better discrimination of isotopic peaks in the measured spectra. Although PC does not improve the resolution of an optical spectrometer directly, it rectifies the resolution lost caused by signal spreading in conventional ICCD analog measurement. However, similar to other counting techniques, excessive photons compromise detector linearity due to signal pileup. A correction model is proposed to mitigate the pileup effect, resulting in improved linearity and dynamic range in PC measurements. Additionally, the study reveals unexpected periodic structures in the flatfield image of the ICCD, which cause non-uniform detector gain in conventional analog as well as PC measurement modes and must be addressed for high-precision measurements.

47 OTHER INSTRUMENTATION↗

Climate-Relevant Gas Absorption Properties from AWARE and Other ARM Spectral Measurements (Final Report)

The objective of this project has been to use measurements from the Atmospheric Emitted Radiance Interferometer (AERI) deployed at ARM sites to improve our knowledge of uncertain infrared spectroscopic parameters of importance to climate, remote sensing, and data assimilation. A primary focus has been the water vapor continuum in the infrared atmospheric window. Radiation codes used to predict climate and weather base their representation of the water vapor continuum in this window on the MT_CKD model, but in this spectral region the MT_CKD water vapor continuum absorption coefficients were derived almost two decades ago by an analysis of AERI measurements for conditions with a limited range of precipitable water vapor (PWV) and temperature values, leading to uncertainty in the derived coefficients. This project has included a new, comprehensive analysis of all aspects of the water vapor continuum in the atmospheric window -- the self continuum, the foreign continuum, and the self continuum temperature dependence, all resolved spectrally. Having a wide range of PWV amounts and temperatures from deployments of the ARM Mobile Facility for GoAmazon as well as the more than a decade of AERI measurements at SGP has provided an appropriate foundation for such a comprehensive analysis.

54 ENVIRONMENTAL SCIENCES↗

Temporal X-ray Reconstruction using Temporal and Spectral Measurements at LCLS

Transverse deflecting structures (TDSs) are widely used in accelerator physics to measure the longitudinal density of particle bunches. When used in combination with a dispersive section, the whole longitudinal phase space density can be imaged. At the Linac Coherent Light Source (LCLS), the installation of such a device downstream of the undulators enables the reconstruction of the X-ray temporal intensity profile by comparing longitudinal phase space distributions with lasing on and lasing off. However, the resolution of this TDS is limited to around 1 fs rms (root mean square), and therefore, it is not possible to resolve single self-amplified spontaneous emission (SASE) spikes within an X-ray photon pulse. By combining the power spectrum from a high resolution photon spectrometer and the temporal structure from the TDS, the overall resolution is enhanced, thus allowing the observation of temporal, single SASE spikes. The combined data from the spectrometer and the TDS is analysed using an iterative algorithm to obtain the actual intensity profile. In this paper, we present some improvements to the reconstruction algorithm as well as real data taken at LCLS.

47 OTHER INSTRUMENTATION↗

Evaluation of Solar Reference Cells on a Two-Axis Tracker Using Spectral Measurements

A simple model calculating the performance of an IMT solar reference cell is proposed and tested under clear sky periods. One-minute data from EKO spectroradiometers collocated with an IMT reference cell are used for the analysis. Data are obtained at the NREL Solar Radiation Research Laboratory in Golden, Colorado and the UO Solar Radiation Monitoring Laboratory in Eugene, Oregon. The model is also applied and evaluated under cloudy conditions. A match of better than 1% is found between calculated clear sky values and IMT measurements for July, 2020. One- minute cloudy sky comparisons show a much larger variation, but when averaged over one hour, a standard deviation of 4% between the calculated and measured values is found.

atmospheric radiation↗

PV module spectral response measurements - Data and Resources

"This dataset includes spectral response curves for 12 commercial silicon module types that are deployed at SNL in Albuquerque. The modules chosen for evaluation were originally purchased by SNL for the PV Lifetime project (renamed to Systems Long-Term Evaluation [SLTE]). The majority of those modules are deployed outdoors for long-term evaluation, but several modules of each type were placed in storage for future comparison purposes. One stored module of each type was sent to NREL for the spectral response measurements. NREL used the recently developed Module Quantum Efficiency (QE) test bed. What makes this system unique is that it scans the entire module automatically, taking one or more measurements on each cell. Using the mean of these measurements at each wavelength leads to improvements in spectral mismatch correction and module power measurements but having the individual measurements also makes it possible to identify outlier cells, which could be useful for investigating underperforming modules. All measurements were performed nominally at 25°C"

14 SOLAR ENERGY↗

Global horizontal spectral irradiance and module spectral response measurements: an open dataset for PV research

This report describes the creation process and final content of a spectral irradiance dataset for Albuquerque, New Mexico accompanied by a set of spectral response measurements for modules deployed at the same location. The spectral irradiance measurements were made using horizontally mounted spectroradiometers; therefore, they represent global horizontal irradiance. The dataset combines non-continuous spectroradiometer and weather measurements from a two-year period into a single calendar year. The data files are accompanied by extensive metadata as well as example calculations and graphs to demonstrate the potential uses of this database. The spectral response measurements were carried out by the National Renewable Energy Laboratory using 12 commercial silicon modules types that are undergoing long-term evaluation at Sandia National Laboratories in Albuquerque.

14 SOLAR ENERGY↗

Spectral emittance measurements of micro/nanostructures in energy conversion: a review

Micro/nanostructures play a key role in tuning the radiative properties of materials and have been applied to the high-temperature energy conversion systems for improved performance. Among the various radiative properties, spectral emittance is of integral importance for the design and analysis of materials that function as radiative absorbers or emitters. This article presents an overview of the spectral emittance measurement techniques using both the direct and indirect methods. Several micro/nanostructures are also introduced, and a special emphasis is placed on the emissometers developed for characterizing engineered micro/nanostructures in high-temperature applications (e.g., solar energy conversion and thermophotovoltaic devices). Both experimental facilities and measured results for different materials are summarized. Future prospects in developing instrumentation and micro/nanostructured surfaces for practical applications are also outlined. This study provides a comprehensive source of information for the application of micro/nanostructures in high-temperature energy conversion engineering.

14 SOLAR ENERGY↗

Factors That Influence Variability in Stress-Drop Measurements Using Spectral Decomposition and Spectral-Ratio Methods for the 2019 Ridgecrest Earthquake Sequence

Stress drop is a fundamental parameter related to earthquake source physics, but is hard to measure accurately. To better understand how different factors influence stress-drop measurements, we compare two different methods using the Ridgecrest stress-drop validation data set: spectral decomposition (SD) and spectral ratio (SR), each with different processing options. Here, we also examine the influence of spectral complexity on source parameter measurement. Applying the SD method, we find that frequency bandwidth and time-window length could influence spectral magnitude calibration, while depth-dependent attenuation is important to correctly map stress-drop variations. For the SR method, we find that the selected source model has limited influence on the measurements; however, the Boatwright model tends to produce smaller standard deviation and larger magnitude dependence than the Brune model. Variance reduction threshold, frequency bandwidth, and time-window length, if chosen within an appropriate parameter range, have limited influence on source parameter measurement. For both methods, wave type, attenuation correction, and spectral complexity strongly influence the result. The scale factor that quantifies the magnitude dependence of stress drop show large variations with different processing options, and earthquakes with complex source spectra deviating from the Brune-type source models tend to have larger scale factor than earthquakes without complexity. Based on these detailed comparisons, we make a few specific suggestions for data processing workflows that could help future studies of source parameters and interpretations.

58 GEOSCIENCES↗

Performance of plane wavefront Fizeau interferometers in power spectral density measurements with tilted plane optics

Binary pseudo-random array (BPRA) test samples are useful devices for calibrating the instrument transfer function (ITF) of Fizeau interferometers, interferometric microscopes, and other optical and non-optical surface and wavefront metrology instruments. The intrinsic white noise character of the power spectral density (PSD) function of the BPRA pattern simplifies the extraction of the ITF from the measured PSD. The ITF determined in a dedicated calibration experiment can be used to reconstruct the surface height profile from the measured data, effectively enhancing the instrument’s spatial resolution. For a high confidence reconstruction procedure, a reliable analytical model of the IFT is desirable. Usually, the model accounts for the contributions to the ITF related the imperfections of the instrument’s optical and detector systems. Here, we experimentally demonstrate that in the case of surface height metrology with Fizeau interferometers, the PSD measurements and, therefore, the efficacy of the ITF calibration of the tool, are strongly affected by the instrument data acquisition and processing procedures, as well as by the shape of the optic under test and its alignment with respect to the interferometer.

Yashchuk, V V↗