Spectroscopic factors from /d, p/ reactions.
Spectroscopic factor dependence of revised model for deuteron stripping in /d, p/ reactions, noting scattering cross section role
Garcia, J. D.↗
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Scattering of 42 MeV alpha particles from copper-65
Beams of 42-MeV alpha particles were elastically and inelastically scattered from Cu-65 in an attempt to excite states which may be described in terms of an excited core model. Angular distributions were measured for 17 excited states. Seven of the excited states had angular distributions similar to a core quadrupole excitation and eight of the excited states had angular distributions similar to a core octupole excitation. The excited state at 2.858 MeV had an angular distribution which suggests that it may have results from the particle coupling to a two-phonon core state. An extended particle-core coupling calculation was performed and the predicted energy levels and reduced transition probabilities compared to the experimental data. The low lying levels are described quite well and the wavefunctions of these states explain the large spectroscopic factors measured in stripping reactions. For Cu-65 the coupling of the particle to the core is no larger weak as in the simpler model, and configuration mixing results.
Stewart, W. M.↗
Air Mass Factor Formulation for Spectroscopic Measurements from Satellites: Application to Formaldehyde Retrievals from the Global Ozone Monitoring Experiment
We present a new formulation for the air mass factor (AMF) to convert slant column measurements of optically thin atmospheric species from space into total vertical columns. Because of atmospheric scattering, the AMF depends on the vertical distribution of the species. We formulate the AMF as the integral of the relative vertical distribution (shape factor) of the species over the depth of the atmosphere, weighted by altitude-dependent coefficients (scattering weights) computed independently from a radiative transfer model. The scattering weights are readily tabulated, and one can then obtain the AMF for any observation scene by using shape factors from a three dimensional (3-D) atmospheric chemistry model for the period of observation. This approach subsequently allows objective evaluation of the 3-D model with the observed vertical columns, since the shape factor and the vertical column in the model represent two independent pieces of information. We demonstrate the AMF method by using slant column measurements of formaldehyde at 346 nm from the Global Ozone Monitoring Experiment satellite instrument over North America during July 1996. Shape factors are cumputed with the Global Earth Observing System CHEMistry (GEOS-CHEM) global 3-D model and are checked for consistency with the few available aircraft measurements. Scattering weights increase by an order of magnitude from the surface to the upper troposphere. The AMFs are typically 20-40% less over continents than over the oceans and are approximately half the values calculated in the absence of scattering. Model-induced errors in the AMF are estimated to be approximately 10%. The GEOS-CHEM model captures 50% and 60% of the variances in the observed slant and vertical columns, respectively. Comparison of the simulated and observed vertical columns allows assessment of model bias.
Palmer, Paul I.↗
ENDOR and ESR studies of a stable radical in irradiated cytidine
A model is proposed for a stable radical species formed by X-irradiation in a single crystal of cytidine and studied by electron nuclear double resonance (ENDOR) and electron spin resonance (ESR) techniques at room temperature. ENDOR and ESR spectra are analyzed to obtain the principal values of the spectroscopic splitting factor and the spectroscopic and hyperfine splitting tensors. The results show hyperfine coupling of an unpaired electron to one hydrogen nucleus and two slightly different geometric forms of the radical with small differences in hyperfine couplings. It is proposed that this radical is formed in the ribose sugar group with a hydrogen atom in a beta position coupling with respect to a carbon-centered unpaired electron and a spin density of approximately 0.2 on a carbon atom.
Allison, D. L.↗
Computational chemistry and aeroassisted orbital transfer vehicles
An analysis of the radiative heating phenomena encountered during a typical aeroassisted orbital transfer vehicle (AOTV) trajectory was made to determine the potential impact of computational chemistry on AOTV design technology. Both equilibrium and nonequilibrium radiation mechanisms were considered. This analysis showed that computational chemistry can be used to predict (1) radiative intensity factors and spectroscopic data; (2) the excitation rates of both atoms and molecules; (3) high-temperature reaction rate constants for metathesis and charge exchange reactions; (4) particle ionization and neutralization rates and cross sections; and (5) spectral line widths.
Cooper, D. M.↗
Spectroscopic measurements of element abundances in the solar corona: Variations on the FIP theme
Solar wind and solar energetic particle (SEP) data yield systematic differences between elemental abundances in the corona and in the photosphere related to the first ionization potential (FIP) of the elements: low-FIP elements are preferentially enhanced relative to high-FIP elements by about a factor of four. Spectroscopic studies of the inner corona show that such a pattern may apply on average but not in detail for coronal loops: substantial abundance differences occur between different types of coronal structures, and variations have been found from flare to flare, from one active region to another, and over time in the same region; further, in some flares, anomalies such as enhanced Ne:O ratios, distinctly at odds with the FIP pattern, show that a competing element selection mechanism sometimes operates. Details of the observed abundance variability -- such as the magnitude of the variations, the relevant temporal and spatial scales, and correlations with other properties of the given coronal structure -- may give important clues to the processes which supply and heat the corona, or they may reflect the changing physical conditions or locations where those processes take place. However, many such details remain to be established definitively. At present, abundance variability is primarily a major complication to data analysis and interpretation. However, once it is better understood, it may provide a new diagnostic tool for probing the lower layers of the solar atmosphere.
Saba, J. L. R.↗
Application of Laser Mass Spectrometry to Art and Archaeology
REMPI laser mass spectrometry is a combination of resonance enhanced multiphoton ionization spectroscopy and time of flight mass spectrometry, This technique enables the collection of mass specific optical spectra as well as of optically selected mass spectra. Analytes are jet-cooled by entrainment in a molecular beam, and this low temperature gas phase analysis has the benefit of excellent vibronic resolution. Utilizing this method, mass spectrometric analysis of historically relevant samples can be simplified and improved; Optical selection of targets eliminates the need for chromatography while knowledge of a target's gas phase spectroscopy allows for facile differentiation of molecules that are in the aqueous phase considered spectroscopically indistinguishable. These two factors allow smaller sample sizes than commercial MS instruments, which in turn will require less damage to objects of antiquity. We have explored methods to optimize REMPI laser mass spectrometry as an analytical tool to archaeology using theobromine and caffeine as molecular markers in Mesoamerican pottery, and are expanding this approach to the field of art to examine laccaic acid in shellacs.
Gulian, Lase Lisa E.↗
Infinite order sudden approximation for rotational energy transfer in gaseous mixtures
Rotational energy transfer in gaseous mixtures is analyzed within the framework of the infinite order sudden (IOS) approximation, and a new derivation of the IOS from the coupled states Lippman-Schwinger equation is presented. This approach shows the relation between the IOS and coupled state T matrices. The general IOS effective cross section can be factored into a finite sum of 'spectroscopic coefficients' and 'dynamical coefficients'. The evaluation of these coefficients is considered. Pressure broadening for the systems HD-He, HCl-He, CO-He, HCl-Ar, and CO2-Ar is calculated, and results based on the IOS approximation are compared with coupled state results. The IOS approximation is found to be very accurate whenever the rotor spacings are small compared to the kinetic energy, provided closed channels do not play too great a role.
Goldflam, R.↗
Chemical Fingerprinting of Materials Developed Due To Environmental Issues
This paper presents viewgraphs on chemical fingerprinting of materials developed due to environmental issues. Some of the topics include: 1) Aerospace Materials; 2) Building Blocks of Capabilities; 3) Spectroscopic Techniques; 4) Chromatographic Techniques; 5) Factors that Determine Fingerprinting Approach; and 6) Fingerprinting: Combination of instrumental analysis methods that diagnostically characterize a material.
Smith, Doris A.↗
A forward-scatter polarimeter for chemical analysis
Photopolarimeter measures two states of orthogonal polarization parallel and perpendicular to scattering plane, defined by directions of incident and scattering light, to determine effective gaseous depolarization factor. Instrument can be used for environmental, spectroscopic, and meteorological analysis.
Fymat, A. L.↗
"Ames Research Center: Linking our Origins to our Future"
Our research traces a path from interstellar materials to inhabited worlds and beyond. We examine how protoplanetary disks evolve and form terrestrial planets, the evolutionary paths of habitable planets, and how external factors (e.g., orbital eccentricity) and internal factors (atmospheric circulation) affect habitability. We trace, spectroscopically and chemically, the evolution of organic molecules from the interstellar medium onto habitable bodies. We examine how membranes might form under prebiotic planetary conditions. We evolve proteins capable of sustaining early metabolism, such as synthesis of biopolymers and transport of ions across membranes. We estimate the frequency of finding a functional prebiotic protein that formed spontaneously. We characterize the formation of diagnostic microbial biosignatures in rock-hosted ecosystems in ophiolite springs as an analog for subsurface life within our solar system, and photosynthetic microbial mats as biota that could be detected on extrasolar planets. We develop quantitative models that simulate energy relationships, biogeochemical cycling, trace gas exchange, and biodiversity. We examine the effects of climate variability on a vegetation-rich biosphere over intermediate time scales, using South American ecosystems as a model. We address natural transport of life beyond its planet of origin, such as on a meteorite, where survivors must withstand radiation, desiccation, and time in transit. We fly organisms and ecosystems in low Earth orbit to test their resistance to space. The Ames E&PO program disseminates these themes to national- and international-scale audiences through partnerships with the California Academy of Sciences, Yellow stone National Park, New York Hall of Science, and several K-14 educational organizations.
DesMarais, David J.↗
Determining the Covering Factor of Compton-Thick Active Galactic Nuclei with NuSTAR
The covering factor of Compton-thick (CT) obscuring material associated with the torus in active galactic nuclei (AGNs) is at present best understood through the fraction of sources exhibiting CT absorption along the line of sight (N(sub H) greater than 1.5 x 10(exp 24) cm(exp −2)) in the X-ray band, which reveals the average covering factor. Determining this CT fraction is difficult, however, due to the extreme obscuration. With its spectral coverage at hard X-rays (greater than 10 keV), Nuclear Spectroscopic Telescope Array (NuSTAR) is sensitive to the AGNs covering factor since Compton scattering of X-rays off optically thick material dominates at these energies. We present a spectral analysis of 10 AGNs observed with NuSTAR where the obscuring medium is optically thick to Compton scattering, so-called CT AGNs. We use the torus models of Brightman and Nandra that predict the X-ray spectrum from reprocessing in a torus and include the torus opening angle as a free parameter and aim to determine the covering factor of the CT gas in these sources individually. Across the sample we find mild to heavy CT columns, with N(sub H) measured from 10(exp 24) to 10(exp 26) cm(exp −2), and a wide range of covering factors, where individual measurements range from 0.2 to 0.9. We find that the covering factor, f(sub c), is a strongly decreasing function of the intrinsic 2-10 keV luminosity, L(sub X), where f(sub c) = (−0.41 +/- 0.13)log(sub 10)(L(sub X)/erg s(exp −1))+18.31 +/- 5.33, across more than two orders of magnitude in L(sub X) (10(exp 41.5) - 10(exp 44) erg s(exp −1)). The covering factors measured here agree well with the obscured fraction as a function of LX as determined by studies of local AGNs with L(sub X) greater than 10(exp 42.5) erg s(exp −1).
NGC 4945↗
Molecules of significance in planetary aeronomy
This monograph is basically devoted to spectroscopic information of the molecules of planetary interest. Only those molecules have been dealt with which have been confirmed spectroscopically to be present in the atmosphere of major planets of our solar system and play an important role in the aeronomy of the respective planets. An introduction giving the general conditions of planets and their atmospheres including the gaseous molecules is given. Some typical planetary spectra is presented and supported with a discussion on some basic concepts of optical absorption and molecular parameters that are important to the study of planetary atmospheres. Quantities like dipole moments, transition probabilities, Einstein coefficients and line strengths, radiative life times, absorption cross sections, oscillator strengths, line widths and profiles, equivalent widths, growth curves, bond strengths, electronic transition moments, Franck-Condon factors and r-centroids, etc., are discussed. Spectroscopic information and relevant data of 6 diatomic (HF, HCL, CO, H2, O2, N2) and 6 polyatomic (CO2, N2), O3, HeO, NH3, CH4) molecules are presented.
Mohan, H.↗
Fundamental Equations of the LIF Hydroxyl Measurements, Appendix a
The equation relating OH concentration to the observed detector count rate for a given laser flux is defined. That equation, which will be referred to henceforth as the central equation for absolute sensitivity, will be cast in terms of standard spectroscopic quantities such as oscillator strengths, Hoenl-London factors, rotational and vibrational quantum numbers, etc., such that it may be tested directly under laboratory conditions. The working expressions used by each of the OH laser induced fluorescence (LIF) groups will be related to this central equation, thereby establishing a common language for the comparison of experimental results and the definition of LIF system performance. The relevant structural details of the OH radical via a spectroscopic description of the energy levels and transitions employed in the LIF method are detailed. The central equation relating observed count rate to absolute concentration will be derived, and that equation will be related to the observed quantities cited by each of the experimental groups engaged in the measurement of OH in the Earth's atmosphere.
Source record↗
First Use of an Airborne Thermal Infrared Hyperspectral Scanner for Compositional Mapping
In May 1999, the airborne thermal infrared hyperspectral imaging system, Spatially Enhanced Broadband Array Spectrograph System (SEBASS), was flown over Mon-non Mesa, NV, to provide the first test of such a system for geological mapping. Several types of carbonate deposits were identified using the 11.25 microns band. However, massive calcrete outcrops exhibited weak spectral contrast, which was confirmed by field and laboratory measurements. Because the weathered calcrete surface appeared relatively smooth in hand specimen, this weak spectral contrast was unexpected. Here we show that microscopic roughness not readily apparent to the eye has introduced both a cavity effect and volume scattering to reduce spectral contrast. The macroroughness of crevices and cobbles may also have a significant cavity effect. The diminished spectral contrast is important because it places higher signal-to-noise ratio (SNR) requirements for spectroscopic detection and identification. This effect should be factored into instrumentation planning and interpretations, especially interpretations without benefit of ground truth. SEBASS had the required high SNR and spectral resolution to allow us to demonstrate for the first time the ability of an airborne hyperspectral thermal infrared scanner to detect and identify spectrally subtle materials.
Kirkland, Laurel↗
Near-Infrared Mass Loss Diagnostics for Massive Stars
Stellar wind mass loss is a key process which modifies surface abundances, luminosities, and other physical properties of hot, massive stars. Furthermore, mass loss has to be understood quantitatively in order to accurately describe and predict massive star evolution. Two urgent problems have been identified that challenge our understanding of line-driven winds, the so-called weak-wind problem and wind clumping. In both cases, mass-loss rates are drastically lower than theoretically expected (up to a factor 1001). Here we study how the expected spectroscopic capabilities of the James Webb Space Telescope (JWST), especially NIRSpec, could be used to significantly improve constraints on wind density structures (clumps) and deep-seated phenomena in stellar winds of massive stars, including OB, Wolf-Rayet and LBV stars. Since the IR continuum of objects with strong winds is formed in the wind, IR lines may sample different depths inside the wind than UV-optical lines and provide new information about the shape of the velocity field and clumping properties. One of the most important applications of IR line diagnostics will be the measurement of mass-loss rates in massive stars with very weak winds by means of the H I Bracket alpha line, which has been identified as one of the most promising diagnostics for this problem.
Sonneborn, George↗
Spectroscopy in the 10 keV to 10 MeV range
Spectral lines in the 10 keV to 1 MeV range carry information of fundamental importance on many astronomical objects. Since the lines are directly related to specific physical processes this information is model independent and gives the physical conditions in the objects. At the sensitivities achieved to date, approximately 0.0001 to 0.001 phsq cm. sec for steady sources and approximately 0.01 to 1 ph/sq cm sec for transient sources, lines were detected from the galactic center, gamma-ray bursts and transients, X-ray pulsators, the Crab pulsar and solar flares. Future instruments with a factor of approximately 100 sensitivity improvement will allow detailed spectroscopic study of these classes of objects as well as supernova remnants, active galaxies and the interstellar medium. This sensitivity improvement can be obtained through the use of detector technology already proven in balloon and satellite instruments.
Matteson, J. L.↗
First Results from Faint Infrared Grism Survey (Figs): First Simultaneous Detection of Ly Alpha Emission and Lyman Break From a Galaxy at Z =7.51
Galaxies at high redshifts provide a valuable tool to study cosmic dawn, and therefore it is crucial to reliably identify these galaxies. Here, we present an unambiguous and first simultaneous detection of both the Lyman-Alpha emission and the Lyman break from a z = 7.512 +/- 0.004 galaxy, observed in the Faint Infrared Grism Survey (FIGS). These spectra, taken with G102 grism on Hubble SpaceTelescope (HST), show a significant emission line detection (6 Sigma) in two observational position angles (PA), with Lyman-Alpha line flux of 1.06 +/- 0.19 x 10(exp -17) erg s(exp -1) cm(exp -2). The line flux is nearly a factor of four higher than in the archival MOSFIRE spectroscopic observations. This is consistent with other recent observations implying that ground-based near-infrared spectroscopy underestimates total emission line fluxes, and if confirmed, can have strong implications for reionization studies that are based on ground-based Lyman-Alpha measurements. A 4-Alpha detection of the NV line in one PA also suggests a weak Active Galactic Nucleus (AGN), and if confirmed would make this source the highest-redshift AGN yet found.These observations from the Hubble Space Telescope thus clearly demonstrate the sensitivity of the FIGS survey, and the capability of grism spectroscopy to study the epoch of reionization.
Faint Galaxy Z=7.51↗