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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Co-Spin With Symmetry Axis Stabilization, and De-Spin for Asteroid Capture

Consideration is given to attitude control associated with capturing a free-flying asteroid using an axisymmetric spacecraft. Asymptotically stable controllers are designed to align the spacecraft axis of symmetry with a line of descent that is fixed in the asteroid, and to eliminate all relative angular velocity before capture takes place. An analytical expression is presented for the torque required to maintain alignment of the axes of symmetry of the spacecraft and an axisymmetric asteroid. After the asteroid is securely captured, the angular velocity of the rigid composite body relative to an inertial frame is arrested; we present a controller that is asymptotically stable and stays within specified thrust limits.

Shen, Haijun↗

Intermediates in the Formation of Aromatics in Hydrocarbon Combustion

The formation of the first benzene ring is believed to be the rate limiting step in soot formation. Two different mechanisms have been proposed for formation of cyclic C6 species. The first involves the reaction of two acetylenes to give CH2CHCCH (vinyl acetylene), the loss of a H to give CHCHCCH (n-C41-13) or CH2CCCH (iso-C4H3), and addition of another acetylene to n-C4H3, followed by ring closure to give phenyl radical. Miller and Melius argue that only n-C4H3 leads to phenyl radical and since iso-C4H3 is more stable than n-C4H3 this mechanism is unlikely. An alternative mechanism proposed by them is formation of benzene from the dimerization of two CH2CCH (propargyl) radicals (formed by the reaction of singlet methylene with C2H2). We report reaction pathways and accurate energetics (from CASSCF/internally contracted CI calculations) for the reactions of CH(pi-2) and CH2-1 with acetylene, the reaction of vinylidene with acetylene, and the reaction of n-C4H3 and iso-C4H3 with acetylene. These calculations identify two new reactive intermediates CHCHCH ( a A"-2 ground state in Cs symmetry; spin coupling is a doublet from three singly occupied orbitals) and CHCCH (B-3 ground state in C2 symmetry) from the reaction of CH with acetylene. These species dimerize with no barrier to form benzene and para-benzyne, respectively. CHCCH is proposed as a reactive intermediate which can add to benzene to give higher polynuclear aromatic hydrocarbons or fullerenes. The addition of a C3H2 unit releases two C-C bond energies and thus the resulting addition product contains sufficient energy to break several CH bonds leading to a reduction in the H to C ratio as the cluster size increases. It is found that iso-C4H3 adds to acetylene to initially give a fulvene radical but that this species rearranges to phenyl radical. Thus, the reaction of acetylene with iso-C4H3 does lead to phenyl radical and the cyclization pathway may also contribute to formation of the initial benzene ring.

Walch, Stephen P.↗

Magnetic fields of the outer planets

It is difficult to imagine a group of planetary dynamos more diverse than those visited by the Pioneer and Voyager spacecraft. The magnetic field of Jupiter is large in magnitude and has a dipole axis within 10 deg of its rotation axis, comfortably consistent with the paleomagnetic history of the geodynamo. Saturn's remarkable (zonal harmonic) magnetic field has an axis of symmetry that is indistinguishable from its rotation axis (mush less than 1 deg angular separation); it is also highly antisymmetric with respect to the equator plane. According to one hypothesis, the spin symmetry may arise from the differential rotation of an electrically conducting and stably stratified layer above the dynamo. The magnetic fields of Uranus and Neptune are very much alike, and equally unlike those of the other known magnetized planets. These two planets are characterized by a large dipole tilts (59 deg and 47 deg, respectively) and quadrupole moments (Schmidt-normalized quadrupole/dipole ratio approximately equal 1.0). These properties may be characteristic of dynamo generation in the relatively poorly conducting 'ice' interiors of Uranus and Neptune. Characteristics of these planetary magnetic fields are illustrated using contour maps of the field on the planet's surface and discussed in the context of planetary interiors and dynamo generation.

Connerney, J. E. P.↗

Forced baroclinic ocean motions. II - The linear equatorial bounded case

Results obtained in the first part of this paper (1976), which studied forced baroclinic ocean motions in the linear equatorial unbounded case, are extended to the case of an ocean bounded by two meridians. A complete solution for the linear spin-up in response to a switched-on, x-dependent wind stress is obtained in terms of five components: the unbounded nonoscillatory response to the wind stress forcing; the inertia-gravity waves generated when the forcing switches on, together with their reflections; the quasi-geostrophic Rossby modes forming the eastern boundary response and a western boundary layer; and the equatorial Kelvin wave component of the western boundary response. Kelvin waves are generated if the forcings include a zonal wind component that is symmetric about the equator or an antisymmetric meridional wind stress. For non-Kelvin symmetries, spin-up occurs entirely by the effects of Rossby waves emanating from the eastern boundary. The state approaches the steady solution as increasing numbers of these reach an interior point. In Kelvin symmetries, the Rossby waves act to bring the sea surface tilt to the steady value and the spin-up of the tilt proceeds as in non-Kelvin cases.

Cane, M. A.↗

Development of New Open-Shell Perturbation and Coupled-Cluster Theories Based on Symmetric Spin Orbitals

A new spin orbital basis is employed in the development of efficient open-shell coupled-cluster and perturbation theories that are based on a restricted Hartree-Fock (RHF) reference function. The spin orbital basis differs from the standard one in the spin functions that are associated with the singly occupied spatial orbital. The occupied orbital (in the spin orbital basis) is assigned the delta(+) = 1/square root of 2(alpha+Beta) spin function while the unoccupied orbital is assigned the delta(-) = 1/square root of 2(alpha-Beta) spin function. The doubly occupied and unoccupied orbitals (in the reference function) are assigned the standard alpha and Beta spin functions. The coupled-cluster and perturbation theory wave functions based on this set of "symmetric spin orbitals" exhibit much more symmetry than those based on the standard spin orbital basis. This, together with interacting space arguments, leads to a dramatic reduction in the computational cost for both coupled-cluster and perturbation theory. Additionally, perturbation theory based on "symmetric spin orbitals" obeys Brillouin's theorem provided that spin and spatial excitations are both considered. Other properties of the coupled-cluster and perturbation theory wave functions and models will be discussed.

Lee, Timothy J.↗

The use of a movable telescoping end mass system for the time-optimal control of spinning spacecraft

The time-optimal control of a spin-stabilized spacecraft with a movable telescoping appendage (boom) is considered analytically and numerically. The motion of a control mass at the end of the boom is determined such that the terminal time will be minimized for two-axis control of a symmetric spacecraft. The equations of rotational motion are linearized about the desired state of spin about the symmetry axis. The equations for the transverse angular velocity components have the form of a coupled two dimensional harmonic oscillator with boom motion as a control force. The control function which brings the system to the desired state is known to be a series of positive and negative pulses. If the initial state is such that the system can be driven to rest in a single switch, the responses, switching and final times, and required boom motion may be determined analytically. Some typical numerical results based on these solutions are discussed.

Bainum, P. M.↗

Starting Vortex Identified as Key to Unsteady Ejector Performance

Unsteady ejectors are currently under investigation for use in some pulse-detonation-engine-based propulsion systems. Experimental measurements made in the past, and recently at the NASA Glenn Research Center, have demonstrated that thrust augmentation can be enhanced considerably when the driver is unsteady. In ejector systems, thrust augmentation is defined as = T(sup Total)/T(sup j), where T(sup Total) is the total thrust of the combined ejector and driving jet and T(sup j) is the thrust due to the driving jet alone. There are three images in this figure, one for each of the named thrust sources. The images are color contours of measured instantaneous vorticity. Each image is an ensemble average of at least 150 phase-locked measurements. The flow is from right to left, and the shape and location of each driver is shown on the far right of each image. The emitted vortex is a clearly defined "doughnut" of highly vortical (spinning) flow. In these planar images, the vortex appears as two distorted circles, one above, and one below the axis of symmetry. Because they are spinning in the opposite direction, the two circles have vorticity of opposite sign and thus are different colors. There is also a rectangle shown in each image. Its width represents the ejector diameter that was found experimentally to yield the highest thrust augmentation. It is apparent that the optimal ejector diameter is that which just "captures" the vortex: that is, the diameter bounding the outermost edge of the vortex structure. The exact mechanism behind the enhanced performance is unclear; however, it is believed to be related to the powerful vortex emitted with each pulse of the unsteady driver. As such, particle imaging velocimetry (PIV) measurements were obtained for three unsteady drivers: a pulsejet, a resonance tube, and a speaker-driven jet. All the drivers were tested with ejectors, and all exhibited performance enhancement over similarly sized steady drivers. The characteristic starting vortices of each driver are shown in these images. The images are color contours of measured instantaneous vorticity. Each image is an ensemble average of at least 150 phase-locked measurements. The flow is from right to left. The shape and location of each driver is shown on the far right of each image. The rectangle shown in each image represents the ejector diameter that was found experimentally to yield the highest thrust augmentation. It is apparent that the optimal ejector diameter is that which just "captures" the vortex: that is, the diameter bounding the outermost edge of the vortex structure. Although not shown, it was observed that the emitted vortex spread as it traveled downstream. The spreading rate for the pulsejet is shown as the dashed lines in the top image. A tapered ejector was fabricated that matched this shape. When tested, the ejector demonstrated superior performance to all those previously tested at Glenn (which were essentially of straight, cylindrical form), achieving a remarkable thrust augmentation of 2. The measured thrust augmentation is shown as a function of ejector length. Also shown are the thrust augmentation values achieved with the straight, cylindrical ejectors of varying diameters. Here, thrust augmentation is plotted as a function of ejector length for several families of ejector diameters. It can be seen that large thrust augmentation values are indeed obtained and that they are sensitive to both ejector length and diameter, particularly the latter. Five curves are shown. Four correspond to straight ejector diameters of 2.2, 3.0, 4.0, and 6.0 in. The fifth curve corresponds to the tapered ejector contoured to bound the emitted vortex. For each curve, there are several data points corresponding to different lengths. The largest value of thrust augmentation is 2.0 for the tapered ejector and 1.81 for the straight ejectors. Regardless of their diameters, all the ejectors trend toward peak performance at a particular leng. That the cross-sectional dimensions of optimal ejectors scaled precisely with the vortex dimensions on three separate pulsed thrust sources demonstrates that the action of the vortex is responsible for the enhanced ejector performance. The result also suggests that, in the absence of a complete understanding of the entrainment and augmentation mechanisms, methods of characterizing starting vortices may be useful for correlating and predicting unsteady ejector performance.

Paxson, Daniel E.↗

The spacecraft antennas

The spacecraft employs two microwave antennas for communications and a single VHF antenna for telemetry, beacon, and command functions. One microwave antenna centered at 6 gc is used to receive broadband signals from a ground transmitter while the other microwave antenna centered at 4 gc is used to transmit signals to a ground receiver. Each microwave antenna is composed of a large number of circularly polarized radiating elements equally spaced around the equator of the spacecraft and connected to the electronic receiver and transmitter by a complex precision feed system. The VHF antenna is a small multi-element helix mounted at the pole of the spacecraft and radiates a linearly polarized signal. All antennas provide nearly isotropic antenna patterns with the axis of symmetry corresponding to the spin axis of the spacecraft. The antenna systems were constructed of light, but rugged, materials and passed extensive electrical, mechanical, and thermal tests.

ANTENNA↗

Electronic energy states

One-electron wave functions are reviewed and approximate solutions of two-electron systems are given in terms of these one-electron functions. The symmetry effects associated with electron spin are reviewed and the effects of electron exchange on energy levels of the two-electron system are given. The coupling of electronic orbital and spin angular momentum is considered next and the Lande interval rule for Russell-Saunders or LS coupling is derived. The configurations possible for various multi-electron LS couplings are enumerated (examples from the first two rows of the periodic table are given), and the meaning of the spectroscopic nomenclature is discussed, particularly with respect to the degeneracies of the electron states involved. Next the nomenclature, symmetries, and degeneracies for electron states of diatomic molecules are discussed, and some examples for N2, O2, and NO are presented. The electronic partition functions and derivative thermodynamic properties are expressed in terms of these energies and degeneracies, and examples are given for some of the simple gas species encountered in the earth's atmosphere.

Source record↗

An Exact Separation of the Spin-Free and Spin-Dependent Terms of the Dirac-Coulomb-Breit Hamiltonian

The Dirac Hamiltonian is transformed by extracting the operator (sigma x p)/2mc from the small component of the wave function and applying it to the operators of the original Hamiltonian. The resultant operators contain products of Paull matrices that can be rearranged to give spin-free and spin-dependent operators. These operators are the ones encountered in the Breit-Pauli Hamiltonian, as well as some of higher order in alpha(sup 2). However, since the transformation of the original Dirac Hamiltonian is exact, the new Hamiltonian can be used in variational calculations, with or without the spin-dependent terms. The new small component functions have the same symmetry properties as the large component. Use of only the spin-free terms of the new Hamiltonian permits the same factorization over spin variables as in nonrelativistic theory, and therefore all the post-Self-Consistent Field (SCF) machinery of nonrelativistic calculations can be applied. However, the single-particle functions are two-component orbitals having a large and small component, and the SCF methods must be modified accordingly. Numerical examples are presented, and comparisons are made with the spin-free second-order Douglas-Kroll transformed Hamiltonian of Hess.

Dyall, Kenneth G.↗

The motion and stability of spin stabilized spacecraft with hinged appendages

The dynamics and stability of a spin stabilized spacecraft with a hinged appendage system are treated analytically and numerically. The hinged system consists of a central hub with masses attached to massless booms of fixed length whose orientation relative to the main part can change. The equations of motion for the hinged system, with viscous damping at both hinge points, are linearized about the nominal equilibrium position where the booms are orthogonal to the nominal spin axis. Analytic stability criteria indicate that hinge damping must be present and that for limiting cases, where the spin axis is an axis of symmetry, certain conditions relating the hinge point offset coordinates to the moment of inertia ratio and end masses must be satisfied. The hinge damping is always required for the nominal deployment of hinge members.

Sellappan, R.↗

Bridle Attachment for Aircraft Spin-Recovery Parachute

Antispin rolling moment produced by chute drag force. Parachute stowed prior to deployment. At deployment, bridle attachment produces antispin rolling moment. At recovery, parachute forces are in aircraft plane of symmetry. Attachment system reduces parachute diameter typically required for spin recovery of experimental aircraft during harzardous flight testing.

White, W. L.↗