Fabrication and field testing of spiral-wound membrane modules for CO2 capture from flue gas
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Salim, Witopo (ORCID:0000000312200918)↗
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Field trial of spiral-wound facilitated transport membrane module for CO2 capture from flue gas
Not provided.
Engineering↗
Continuous self-locking spiral wound seal
A spiral wound seal for effecting a seal between two surfaces is described. The seal consists of a strip of gasket material wound into a groove machined into one of the surfaces. The gasket strip is wider than the groove is deep so that a portion of the gasket material protrudes from the groove. The seal is effected by clamping the second surface onto the first surface and compressing the protruding gasket material.
Irick, S. C.↗
Modified spiral wound retaining ring
A spiral wound retaining ring with angled ends is described. The ring is crimped at the same angle as the ring ends to maintain a constant thickness dimension. The angling of the ends of the ring and crimp allow the ends to be positioned closer together while maintaining enough clearance to enable insertion and removal of the ring. By reducing the separation distance between the ends a stronger ring results since the double layer area of the ring is maximized.
Lawson, A. G.↗
A thermal analysis of a spirally wound battery using a simple mathematical model
A two-dimensional thermal model for spirally wound batteries has been developed. The governing equation of the model is the energy balance. Convective and insulated boundary conditions are used, and the equations are solved using a finite element code called TOPAZ2D. The finite element mesh is generated using a preprocessor to TOPAZ2D called MAZE. The model is used to estimate temperature profiles within a spirally wound D-size cell. The model is applied to the lithium/thionyl chloride cell because of the thermal management problems that this cell exhibits. Simplified one-dimensional models are presented that can be used to predict best and worst temperature profiles. The two-dimensional model is used to predict the regions of maximum temperature within the spirally wound cell. Normal discharge as well as thermal runaway conditions are investigated.
Evans, T. I.↗
Modeling and simulation of gas separations with spiral–wound membranes
Models for gas separations with spiral–wound membranes are developed and found to exhibit good agreement with experiments performed on N 2 /O 2 mixtures. The two–dimensional (2D) model can be accurately approximated by a one–dimensional (1D) surrogate model when the spacer widths are chosen to make the channel pressure drops small. Subsequently, the separation of propane/propylene mixtures from the recycle purge stream of a polypropylene reactor is investigated. Assuming ideal gas is found to lead to significant overestimations in membrane stage cuts (sometimes more than 10%), an extent comparable to that associated with extrapolating constant olefin permeance from a low–pressure condition. While olefin permeance can change significantly with pressure, using a constant–permeance formulation can result in a small (< 2.5%) underprediction in stage cut if the value for the permeance is taken from the feed condition. Finally, membrane properties and costs necessary for a viable separation process are discussed.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Spiral-wound gasket forms low-temperature seal
Spiral-wound cryogenic gasket with one component requires no encapsulant and is easily produced with self-locking features. Seal either opens and closes or is fixed. It is made by skiving strip from circumference of disk of glass-filled material. Successive turns of strip are spirally wrapped in groove machined into one flange surface. Closing joint compresses gasket.
Irick, S. C.↗
Impedance measurements on a spiral-wound nickel/metal hydride cell cycled in a simulated Leo orbit
A spiral-wound size C cell was cycled at 25 C in a low earth orbit (LEO) regime at 50 percent depth of discharge (DOD) with approximately five percent over-charge. The nominal capacity was 3.5 AH. The cell was cycled for 2000 cycles. Capacity checks and impedance measurements over the complete range of state of charge were made upon receipt and after 500, 1000, and 2000 cycles. The capacity of the cell was essentially unchanged until after the impedance measurements at 2000 cycles. Only small changes in the impedance parameters were observed, but there was somewhat more scatter in the data after 2000 cycles. When the cell was returned to LEO cycling after 2000 cycles, only 38 percent of the capacity could be obtained. It is believed that the cell failed because of an equipment failure at the end of the final impedance measurements which allowed an over-discharge.
Reid, Margaret A.↗
Measurement of the performance of a spiral wound polyimide regenerator in a pulse tube refrigerator
A regenerator for use in a pulse tube refrigerator has been constructed from a polyimide (polypyromellitimide or PPMI) whose small ratio of thermal conductivity to heat capacity make it a good candidate for a regenerator material in cryocoolers. The regenerator was fabricated using 25 micron thick photoresist strips bonded to a 50 micron thick sheet of PPMI. This composite sheet was wound in jelly-roll fashion around a mandrel and inserted into the regenerator housing. The photoresist strips, formed using a photolithographic technique, provided a 25 micron spacing for the axial flow of gas between each layer of PPMI. Ineffectiveness results are presented for this material under actual operating conditions in a pulse tube refrigerator and compared with a numerical model. The numerical model indicated that a polyimide regenerator would perform much better than one constructed of stainless steel screen, but the experimental results showed the opposite behavior. Measured values for the ineffectiveness were 0.003 for the stainless steel screen and 0.017 for the polyimide.
Rawlins, Wayne↗
FLiNaK Compatability Studies with Inconel 600 and Silicon Carbide
A small liquid fluoride salt test apparatus has been constructed and testing conducted to examine the compatibility of SiC, Inconel 600, and a spiral wound gasket material in FLiNaK salt. These tests were conducted to test materials and sealing systems that would be used in a FLiNaK salt test loop. Three months of testing at 700oC was used to assure that these materials and seals would be acceptable operating under expected test loop conditions. The SiC specimens showed little or no change over the test period while the spiral wound gasket material showed no degradation, except for the possibility of salt seeping into the outermost spirals of the gasket. The Inconel 600 specimens showed regions of voiding which penetrated the specimen surface to about 250 m in depth. Analysis indicated that the salt had leached chrome from the Inconel surface as was expected for this material. Because the test loop will have a limited working lifetime, it was concluded that these materials would be satisfactory for loop construction.
42 ENGINEERING↗
Detonation-flame arrester devices for gasoline cargo vapor recovery systems
Empirical data on the deflagration-to-detonation run-up distance for flowing mixtures of gasoline and air in 15.2-cm- (6.0-in.-) diameter piping simulating a vapor recovery system are presented. The quenching capability of eight selected flame control devices subjected to repeated stable detonations was evaluated. The successful detonation-flame arresters were: (1) spiral-wound, crimped aluminum ribbon, (2) foamed nickel-chrome metal, (3) vertically packed bed of aluminum Ballast rings, and (4) water-trap or hydraulic back-pressure valve. Installation configurations for two of the more applicable arresters, the spiral-wound, crimped stainless-steel ribbon and the vertically packed bed of aluminum Ballast rings, were further optimized by a series of parametric tests. The final configuration of these two arresters was demonstrated with repeated detonation tests at conditions that simulated vapor recovery system operation. On these tests, the combustible mixture of gasoline and air continued to flow through the piping for periods up to 120 seconds after the initial detonation had been arrested. There was no indication of continuous burning or reignition occurring on either side of the test arresters.
Bjorklund, R. A.↗
Separation and Enrichment of Xenon in Air (SBIR Phase II Final Report)
High-performance composite membranes and high-performance spiral-wound modules have been successfully developed that can be used to detect the concentration of xenon present in the atmosphere. The selective membrane material is Hyflon® AD 60, a perfluorinated polymer available from Solvay. The material has a nitrogen/xenon selectivity of at least five. The membranes were incorporated into spiral-wound modules that have special baffles in the feed channels. The baffles increase gas velocity and allow the module to be operated at stage cuts of 90% or higher, while maintaining their separation efficiency. A prototype system was constructed and tested at MTR. The system was subsequently shipped to the Savannah River National Laboratory where it was operated with local atmospheric air. The results obtained by MTR and Savannah River are equivalent and show that the system is capable of concentrating xenon by a factor of 35 at a xenon recovery of 50%.
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
Novel Inorganic/Polymer Composite Membranes for CO 2 Capture
The objective of this project is to develop a cost-effective design and manufacturing process for new membrane modules that capture CO 2 from flue gas in coal-fired power plants. The membrane consisted of a thin selective layer including inorganic (zeolite) embedded in a polymer structure so that it can be made in a continuous manufacturing process. The membrane was incorporated in spiral-wound modules for the field test with actual flue gas at the National Carbon Capture Center (NCCC) in Wilsonville, AL and bench scale tests with simulated flue gas at the Ohio State University (OSU). Using the modules for post-combustion CO 2 capture is expected to achieve the DOE target of $40/tonne CO 2 captured (in 2007 dollar) for 2025. Membranes with the amine-containing polymer cover layer on zeolite-Y (ZY) nanoparticles deposited on the polyethersulfone (PES) substrate were successfully synthesized. The membranes showed a high CO 2 permeance of about 1100 GPU (gas permeation unit, 1 GPU = 10 -6 cm 3 (STP)/(cm 2 • s • cm Hg), 3000 GPU = 10-6 mol/(m 2 • s • Pa)) with a high CO 2 /N 2 selectivity of > 200 at the typical flue gas conditions at 57°C (about 17% water vapor in feed gas) and > 1400 GPU CO 2 permeance with > 500 CO 2 /N 2 selectivity at 102°C (~ 80% water vapor). The synthesis of ZY nanoparticles was successfully scaled up, and the pilot-scale membranes were also successfully fabricated using the continuous membrane machine at OSU. The transport performance of the pilot-scale membranes agreed reasonably well with the lab-scale membranes. The results from both the lab-scale and scale-up membranes were used for the techno-economic analysis. The scale-up membranes were fabricated into prototype spiral-wound membrane modules for continuous testing with simulated or real flue gas. For real flue gas testing, we worked with NCCC, in consultation with TriSep Corporation, Gradient Technology and American Electric Power (AEP). The membrane module demonstrated > 800 GPU of CO 2 permeance and > 150 CO 2 /N 2 selectivity when tested with real flue gas at NCCC. The results obtained were used to update the techno-economic analysis. In addition, the EH&S assessment of the membranes for post-combustion CO 2 capture was conducted.
20 FOSSIL-FUELED POWER PLANTS↗
Advancements in conventional and 3D printed feed spacers in membrane modules
Plate & frame and spiral-wound modules are used for gas separation, pervaporation, reverse osmosis, nanofiltration, ultrafiltration, microfiltration, electro-dialysis, electro-deionization, membrane distillation and forward osmosis membrane processes. Feed channel spacers are an integral part of both module types – providing mechanical support for a cross-flow channel through the module and, in most cases, promoting mixing to enhance mass transfer to reduce concentration polarization and fouling. However, enhanced mass transfer comes at a cost of increased hydraulic pressure losses and stagnant zones wherever a spacer filament touches a membrane surface. Further, these stagnant zones exacerbate membrane fouling and make cleaning more difficult. Efforts to improve feed spacer performance largely focus on adjusting the chemistry or geometry of the spacer to mitigate these challenges. Additive manufacturing (i.e. 3D printing) offers new degrees of freedom in feed spacer design and production, which opens up a new area of research in membrane technology. This review critically assesses the peer-reviewed literature on conventional net- or mesh-style feed spacers in addition to various novel spacer geometries and chemistries produced via 3D printing. We further review and evaluate conventional spacer manufacturing methods and discuss advantages and disadvantages of 3D printed spacers.
3D printing↗
Gems of the Galaxy Zoos—A Wide-ranging Hubble Space Telescope Gap-filler Program*
We describe the Gems of the Galaxy Zoos (Zoo Gems) project, a gap-filler project using short windows in the Hubble Space Telescope's schedule. As with previous snapshot programs, targets are taken from a pool based on position; we combine objects selected by volunteers in both the Galaxy Zoo and Radio Galaxy Zoo citizen-science projects. Zoo Gems uses exposures with the Advanced Camera for Surveys to address a broad range of topics in galaxy morphology, interstellar-medium content, host galaxies of active galactic nuclei, and galaxy evolution. Science cases include studying galaxy interactions, backlit dust in galaxies, post-starburst systems, rings and peculiar spiral patterns, outliers from the usual color–morphology relation, Green Pea compact starburst systems, double radio sources with spiral host galaxies, and extended emission-line regions around active galactic nuclei. For many of these science categories, final selection of targets from a larger list used public input via a voting process. Highlights to date include the prevalence of tightly wound spiral structure in blue, apparently early-type galaxies, a nearly complete Einstein ring from a group lens, redder components at lower surface brightness surrounding compact Green Pea starbursts, and high-probability examples of spiral galaxies hosting large double radio sources.
79 ASTRONOMY AND ASTROPHYSICS↗
The configuration of the interplanetary magnetic field.
The idealized basic structure of the interplanetary magnetic field is the familiar spiral wound on a cone whose axis is the solar rotation axis. Variations in the radial velocity of the solar wind produce large scale variations in pitch; slight distortions are also produced by the nonradial component of the solar wind velocity. The high velocity streams in the solar wind seem to be more significant than magnetic polarity alternation in the sector structure of the interplanetary medium. Superposed on the ideal spiral are a variety of smaller structures. Outwardly propagating nonsinusoidal Alfven waves with scale lengths of .1 to 10 million kilometers are common. When sharp crested, they are recognized as rotational discontinuities. Other, less easily identified, waves are present part of the time. Tangential discontinuities and other convected structures have been identified, as have interplanetary shock waves.
Davis, L., Jr.↗