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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Tree Rings and Observations Suggest No Stable Cycles In Sierra Nevada Cool‐Season Precipitation

California's water resources rely heavily on cool‐season (November–March) precipitation in the Sierra Nevada. Interannual variability is highly volatile and seasonal forecasting has little to no skill, making water management particularly challenging. Over 1902–2020, Sierra Nevada cool‐season precipitation totals exhibited significant 2.2‐ and 13–15‐year cycles, accounting for approximately 40% of total variability and perhaps signifying potential as seasonal forecasting tools. However, the underlying climate dynamics are not well understood and it is unclear whether these cycles are stable over the long‐term. We use tree rings to reconstruct Sierra Nevada cool‐season precipitation back to 1400. The reconstruction is skillful, accounting for 55–74% of observed variability and capturing the 20th‐century 2.2‐ and 13–15‐year cycles. Prior to 1900, the reconstruction indicates no other century‐long periods of significant spectral power in the 2.2‐ or 13–15‐year bands. The reconstruction does indicate significant cyclicity over other extended periods of several decades or longer, however, with dominant periodicities in the ranges of 2.1–2.7 and 3.5–8 years. The late 1700s through 1800s exhibited the highest‐amplitude cycles in the reconstruction, with periodicities of 2.4 and 5.7–7.4 years. The reconstruction should serve to caution against extrapolating the observed 2.2‐ and 13–15‐year cycles to guide future expectations. On the other hand, observations and the reconstruction suggest that interannual variability of Sierra Nevada cool‐season precipitation is not a purely white noise process and research should aim to diagnose the dynamical drivers of extended periods of cyclicity in this critical natural resource.

Paleoclimate↗

An Integrated, Layered-Spinel Composite Cathode for Energy Storage Applications

At low operating temperatures, commercially available electrode materials for lithium-ion batteries do not fully meet the energy and power requirements for NASA fs exploration activities. The composite cathode under development is projected to provide the required energy and power densities at low temperatures and its usage will considerably reduce the overall volume and weight of the battery pack. The newly developed composite electrode material can provide superior electrochemical performance relative to a commercially available lithium cobalt system. One advantage of using a composite cathode is its higher energy density, which can lead to smaller and lighter battery packs. In the current program, different series of layered-spinel composite materials with at least two different systems in an integrated structure were synthesized, and the volumetric and gravimetric energy densities were evaluated. In an integrated network of a composite electrode, the effect of the combined structures is to enhance the capacity and power capabilities of the material to levels greater than what is possible in current state-of-the-art cathode systems. The main objective of the current program is to implement a novel cathode material that meets NASA fs low temperature energy density requirements. An important feature of the composite cathode is that it has at least two components (e.g., layered and spinel) that are structurally integrated. The layered material by itself is electrochemically inactive; however, upon structural integration with a spinel material, the layered material can be electrochemically activated, thereby delivering a large amount of energy with stable cycling. A key aspect of the innovation has been the development of a scalable process to produce submicronand micron-scale particles of these composite materials. An additional advantage of using such a composite electrode material is its low irreversible loss (.5%), which is primarily due to the unique activation of the composite. High columbic efficiency (greater than 99%) upon cycling may indicate the formation of a stable SEI (solid-electrolyte interface) layer, which can contribute to long cycle life. The innovation in the current program, when further developed, will enable the system to maintain high energy and power densities at low temperatures, improve efficiency, and further stabilize and enhance the safety of the cell.

Hagh, Nader↗

Fabrication and testing of silver-hydrogen cells

The development and life testing of single electrode and multi electrode stacks to optimize the individual components and characterize the performance of a silver hydrogen battery system are described. A NASA-developed inorganic separator material was used as the main separator within the cells. Single electrode test cells were cycled at 75% of nominal capacity out through approximately 1,000 cycles in a number of cases where deterioration in performance was observed. This deterioration appears to be a decay in usable capacity of the silver electrode; but the exact mechanism is still unidentified. Twenty ampere-hour boilerplate test cells consisting of a stack of ten silver electrodes and twenty hydrogen electrodes were cycled also at 75% depth of discharge. The oldest stack achieved 522 stable cycles to the end of the program. Weight analysis of light-weight cells showed that 50 ampere-hour cells with improved components could be capable of as much as 40 watt hours per pound.

Klein, M. G.↗

Effects of friction dampers on aerodynamically unstable rotor stages

Attention is given to the physical concepts and mathematical techniques useful in the analysis of the stabilizing effect of friction on aerodynamically unstable rotor stages. Results are presented for three-, four-, and five-bladed disks. In the present multidegree-of-freedom model of an aerodynamically unstable rotor stage, a harmonic steady state solution due to the friction dampers may be either a stability limit, a stable cycle limit, or neither. A criterion is established in the form of an energy function which determines whether the solution is a stability limit. In the event that the initial displacement and velocity exeed those associated with the steady state solution corresponding to a stability limit, the reponse becomes unbounded.

Griffin, J. H.↗

Spatial Aspects of Interspecific Competition

Using several variants of a stochastic spatial model introduced by Silvertown et al., we investigate the effect of spatial distribution of individuals on the outcome of competition. First, we prove rigorously that if one species has a competitive advantage over each of the others, then eventually it takes over all the sites in the system. Second, we examine tradeoffs between competition and dispersal distance in a two-species system. Third, we consider a cyclic competitive relationship between three types. In this case, a nonspatial treatment leads to densities that follow neutrally stable cycles or even unstable spiral solutions, while a spatial model yields a stationary distribution with an interesting spatial structure.

Durrett, Rick↗

High-Capacity, High-Voltage Composite Oxide Cathode Materials

This SBIR project integrates theoretical and experimental work to enable a new generation of high-capacity, high-voltage cathode materials that will lead to high-performance, robust energy storage systems. At low operating temperatures, commercially available electrode materials for lithium-ion (Li-ion) batteries do not meet energy and power requirements for NASA's planned exploration activities. NEI Corporation, in partnership with the University of California, San Diego, has developed layered composite cathode materials that increase power and energy densities at temperatures as low as 0 degC and considerably reduce the overall volume and weight of battery packs. In Phase I of the project, through innovations in the structure and morphology of composite electrode particles, the partners successfully demonstrated an energy density exceeding 1,000 Wh/kg at 4 V at room temperature. In Phase II, the team enhanced the kinetics of Li-ion transport and electronic conductivity at 0 degC. An important feature of the composite cathode is that it has at least two components that are structurally integrated. The layered material is electrochemically inactive; however, upon structural integration with a spinel material, the layered material can be electrochemically activated and deliver a large amount of energy with stable cycling.

Hagh, Nader M.↗

Closed-Cycle, Frequency-Stable CO2 Laser Technology

These proceedings contain a collection of papers and comments presented at a workshop on technology associated with long-duration closed-cycle operation of frequency-stable, pulsed carbon dioxide lasers. This workshop was held at the NASA Langley Research Center June 10 to 12, 1986. The workshop, jointly sponsored by the National Aeronautics and Space Administration (NASA) and the Royal Signals and Radar Establishment (RSRE), was attended by 63 engineers and scientists from the United States and the United Kingdom. During the 2 1/2 days of the workshop, a number of issues relating to obtaining frequency-stable operation and to the catalytic control of laser gas chemistry were discussed, and specific recommendations concerning future activities were drafted.

Batten, Carmen E.↗

Characterizing Observed Limit Cycles in the Cassini Main Engine Guidance Control System

The Cassini spacecraft dynamics-related telemetry during long Main Engine (ME) burns has indicated the presence of stable limit cycles between 0.03-0.04 Hz frequencies. These stable limit cycles cause the spacecraft to possess non-zero oscillating rates for extended periods of time. This indicates that the linear ME guidance control system does not model the complete dynamics of the spacecraft. In this study, we propose that the observed limit cycles in the spacecraft dynamics telemetry appear from a stable interaction between the unmodeled nonlinear elements in the ME guidance control system. Many nonlinearities in the control system emerge from translating the linear engine gimbal actuator (EGA) motion into a spacecraft rotation. One such nonlinearity comes from the gear backlash in the EGA system, which is the focus of this paper. The limit cycle characteristics and behavior can be predicted by modeling this gear backlash nonlinear element via a describing function and studying the interaction of this describing function with the overall dynamics of the spacecraft. The linear ME guidance controller and gear backlash nonlinearity are modeled analytically. The frequency, magnitude, and nature of the limit cycle are obtained from the frequency response of the ME guidance controller and nonlinear element. In addition, the ME guidance controller along with the nonlinearity is simulated. The simulation response contains a limit cycle with similar characterstics as predicted analytically: 0.03-0.04 Hz frequency and stable, sustained oscillations. The analytical and simulated limit cycle responses are compared to the flight telemetry for long burns such as the Saturn Orbit Insertion and Main Engine Orbit Trim Maneuvers. The analytical and simulated limit cycle characteristics compare well with the actual observed limit cycles in the flight telemetry. Both have frequencies between 0.03-0.04 Hz and stable oscillations. This work shows that the stable limit cycles occur due to the interaction between the unmodeled nonlinear elements and linear ME guidance controller.

stable limit cycle↗

Triggering of longitudinal combustion instabilities in solid rocket motors: Nonlinear combustion response

Pulsed oscillations in solid rocket motors are investigated with emphasis on nonlinear combustion response. The study employs a wave equation governing the unsteady motions in a two-phase flow, and a solution technique based on spatial- and time-averaging. A wide class of combustion response functions is studied to second-order in fluctuation amplitude to determine if, when, and how triggered instabilities arise. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Based on the behavior of model dynamical systems, introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be the manner in which the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse.

Wicker, J. M.↗

Nonlinear global stability analysis of compressor stall phenomena

Compressor stall phenomena are analyzed from the point of view of nonlinear control theory, based on bifurcation-catastrophe techniques. This new approach appears promising and offers insight into such well-known compressor instability problems as surge and rotating stall and suggests strategies for recovery. Three interlocking dynamic nonlinear state space models are developed. It is shown that the problem of rotating stall can be viewed as an induced bifurcation of solution of the unstalled model. Hysteresis effects are shown to exist in the stall/recovery process. Surge cycles are observed for some critical parameter values. The oscillatory behavior is seen to be due to development of limit cycles, generated by Hopf bifurcation of solutions. More specifically, it is observed that at certain critical values of parameters, a family of stable limit cycles with growning and then diminishing amplitudes is generated, then giving rise to an unstable family of limit cycles. This unstable family in turn bifurcates into other unstable families. To further illustrate the utility of the methodology, some partial computation of domains is carried out, and parameter sensitivity analysis is performed.

Razavi, H.↗

Atmospheric methane /CH4/ - Trends and seasonal cycles

On the basis of 22 months of almost continuous automated, GC/FID measurements of atmospheric CH4 and Cape Meares (45 deg N), it is shown that the concentration of CH4 is increasing at about 2% per yr (+ or - 0.5%/yr). The data also revealed stable seasonal cycles with peak concentrations in October and minimum concentrations in July. The magnitude of the seasonal variations during these months is about + or - 20 ppby from the average (+ or - 1.2%). If the current trend continues, the increased CH4 concentration may result in a 0.2 K to 0.4 K average increase in earth's surface temperature over the next 40 years or so (based on calculations of Wang et al. (1976)). The coupling of CH4 to tropospheric and stratospheric chemical processes is discussed.

Rasmussen, R. A.↗

Simulations of the HDO and H2O-18 atmospheric cycles using the NASA GISS general circulation model - Sensitivity experiments for present-day conditions

Incorporating the full geochemical cycles of stable water isotopes (HDO and H2O-18) into an atmospheric general circulation model (GCM) allows an improved understanding of global delta-D and delta-O-18 distributions and might even allow an analysis of the GCM's hydrological cycle. A detailed sensitivity analysis using the NASA/Goddard Institute for Space Studies (GISS) model II GCM is presented that examines the nature of isotope modeling. The tests indicate that delta-D and delta-O-18 values in nonpolar regions are not strongly sensitive to details in the model precipitation parameterizations. This result, while implying that isotope modeling has limited potential use in the calibration of GCM convection schemes, also suggests that certain necessarily arbitrary aspects of these schemes are adequate for many isotope studies. Deuterium excess, a second-order variable, does show some sensitivity to precipitation parameterization and thus may be more useful for GCM calibration.

Jouzel, Jean↗

Stability boundaries for aircraft with unstable lateral-directional dynamics and control saturation

Aircraft that do not possess inherent (aerodynamic) stability must rely on closed-loop control systems for stable operation. Because there are limits on the deflections of an aircraft's control surfaces, the region of stable operation also is bounded. These boundaries are investigated for a lateral-directional example in which vertical fin size is inadequate to provide directional stability and where aileron and rudder deflections are subject to saturation. Fourth-order models are used in this study, with flight control logic based on minimum-control-energy linear-quadratic-regulatory theory. It is found that the stability boundaries can be described by unstable limit cycles surrounding stable equilibrium points. Variations in regions of stability with gain levels and command inputs are illustrated. Current results suggest guidelines for permissible limits on the open-loop instability of an aircraft's lateral-directional modes.

Shrivastava, Prakash C.↗

Stability of a rigid rotor supported on oil-film journal bearings under dynamic load

Most published work relating to dynamically loaded journal bearings are directed to determining the minimum film thickness from the predicted journal trajectories. These do not give any information about the subsynchronous whirl stability of journal bearing systems since they do not consider the equations of motion. It is, however, necessary to know whether the bearing system operation is stable or not under such an operating condition. The stability characteristics of the system are analyzed. A linearized perturbation theory about the equilibrium point can predict the threshold of stability; however it does not indicate postwhirl orbit detail. The linearized method may indicate that a bearing is unstable for a given operating condition whereas the nonlinear analysis may indicate that it forms a stable limit cycle. For this reason, a nonlinear transient analysis of a rigid rotor supported on oil journal bearings under: (1) a unidirectional constant load, (2) a unidirectional periodic load, and (3) variable rotating load are performed. The hydrodynamic forces are calculated after solving the time-dependent Reynolds equation by a finite difference method with a successive overrelaxation scheme. Using these forces, equations of motion are solved by the fourth-order Runge-Kutta method to predict the transient behavior of the rotor. With the aid of a high-speed digital computer and graphics, the journal trajectories are obtained for several different operating conditions.

Majumdar, B. C.↗

Hypersonic flutter of a curved shallow panel with aerodynamic heating

The general equations describing the nonlinear fluttering oscillations of shallow, curved, heated orthotropic panels have been derived. The formulation takes into account the location of the panel on the surface of a generic hypersonic vehicle, when calculating the aerodynamic loads. It is also shown that third order piston theory produces unsteady aerodynamic loading which is in close agreement with that based upon direct solution of the Euler equations. Results, for simply supported panels, are obtained using Galerkin's method combined with direct numerical integration in time to compute stable limit cycle amplitudes. These results illustrate the sensitivity of the aeroelastic behavior to the unsteady aerodynamic assumptions, temperature, orthotropicity and flow orientation.

Bein, T.↗

Forced Oscillations of Supported Drops

Oscillations of supported liquid drops are the subject of wide scientific interest, with applications in areas as diverse as liquid-liquid extraction, synthesis of ceramic powders, growing of pure crystals in low gravity, and measurement of dynamic surface tension. In this research, axisymmetric forced oscillations of arbitrary amplitude of viscous liquid drops of fixed volume which are pendant from or sessile on a rod with a fixed or moving contact line and surrounded by an inviscid ambient gas are induced by moving the rod in the vertical direction sinusiodally in time. In this paper, a preliminary report is made on the computational analysis of the oscillations of supported drops that have 'clean' interfaces and whose contact lines remain fixed throughout their motions. The relative importance of forcing to damping can be increased by either increasing the amplitude of rod motion A or Reynolds number Re. It is shown that as the ratio of forcing to damping rises, for drops starting from an initial rest state a sharp increase in deformation can occur when they are forced to oscillate in the vicinity of their resonance frequencies, indicating the incipience of hysteresis. However, it is also shown that the existence of a second stable limit cycle and the occurrence of hysteresis can be observed if the drop is subjected to a so-called frequency sweep, where the forcing frequency is first increased and then decreased over a suitable range. Because the change in drop deformation response is abrupt in the vicinity of the forcing frequencies where hysteresis occurs, it should be possible to exploit the phenomenon to accurately measure the viscosity and surface tension of the drop liquid.

Wilkes, Edward D.↗