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NASA NTRS2000

Implications of SWAS Observations for Interstellar Chemistry and Star Formation

A long standing prediction of steady state gas-phase chemical theory is that H2O and O2 are important reservoirs of elemental oxygen and major coolants of the interstellar medium. Analysis of SWAS observations has set sensitive upper limits on the abundance Of O2 and has provided H2O abundances toward a variety of star forming regions. Based on these results, we show that gaseous H2O and O2 are not dominant carriers of elemental oxygen in molecular clouds. Instead the available oxygen is presumably frozen on dust grains in the form of molecular ices, with a significant portion potentially remaining in atomic form, along with CO, in the gas phase. H2O and O2 are also not significant coolants for quiescent molecular gas. In the case of H2O, a number of known chemical processes can locally elevate its abundance in regions with enhanced temperatures, such as warm regions surrounding young stars or in hot shocked gas. Thus, water can be a locally important coolant. The new information provided by SWAS, when combined with recent results from the Infrared Space Observatory, also provide several hard observational constraints for theoretical models of the chemistry in molecular clouds and we discuss various models that satisfy these conditions.

Bergin, Edwin A.↗

NASA NTRS1999

Submillimeter Wave Astronomy Satellite (SWAS) Launch and Early Orbit Support Experiences

The Submillimeter Wave Astronomy Satellite (SWAS) was successfully launched on December 6, 1998 at 00:58 UTC. The two year mission is the fourth in the series of Small Explorer (SMEX) missions. SWAS is dedicated to the study of star formation and interstellar chemistry. SWAS was injected into a 635 km by 650 km orbit with an inclination of nearly 70 deg by an Orbital Sciences Corporation Pegasus XL launch vehicle. The Flight Dynamics attitude and navigation teams supported all phases of the early mission. This support included orbit determination, attitude determination, real-time monitoring, and sensor calibration. This paper reports the main results and lessons learned concerning navigation, support software, star tracker performance, magnetometer and gyroscope calibrations, and anomaly resolution. This includes information on spacecraft tip-off rates, first-day navigation problems, target acquisition anomalies, star tracker anomalies, and significant sensor improvements due to calibration efforts.

Kirschner, S.↗

NASA NTRS1999

Submillimeter Wave Astronomy Satellite (SWAS) Launch and Early Orbit Support Experiences

Kirschner, S.↗

NASA NTRS1997

The Submillimeter Wave Astronomy Satellite: Science objectives and instrument description

The submillimeter wave astronomy satellite (SWAS) mission is dedicated to the investigation of star formation and interstellar chemistry. In order to perform the mission, SWAS will survey dense molecular clouds within the Milky Way Galaxy in either the ground state or a low-lying transition of five astrophysically-significant species: H2O, H2(18)O, O2, C I and (13)CO. The observation of these lines will: test theories that predict that these species are dominant coolants of molecular clouds during early stages of their collapse to form stars and planets, and supply information concerning the abundance of species central to the chemical models of dense interstellar gas. The SWAS will use two independent Schottky barrier diode mixers and a 53 x 68 sq cm, off-axis Cassegrain antenna.

Melnick, G. J.↗

NASA NTRS1995

The Submillimeter Wave Astronomy Satellite

The Submillimeter Wave Astronomy Satellite (SWAS) mission is dedicated to the study of star formation and interstellar chemistry. To carry out this mission, SWAS will survey dense (n(sub H2) greater than 10(exp 3) cm(exp -3)) molecular clouds within our galaxy in either the ground-state of a low-lying transition of five astrophysically important species: H2O, H2O-18, O2, CI, and CO-13. By observing these lines SWAS will: (1) test long-standing theories that predict that these species are the dominant coolants of molecular clouds during the early stages of their collapse to form stars and planets, and (2) supply heretofore missing information about the abundanceof key species central to the chemical models of dense interstellar gas. SWAS will employ two independent Schottky barrier diode mixers, passively cooled to approx. 150 K, coupled to a highly efficient 54 x 68 cm off-axis Cassegrain antenna. During its two year mission, SWAS will observe giant and dark cloud cores with the goal of detecting or setting an upper limit on the water abundance of 3 x 10(exp -6) and on th molecular oxygen abundances of 2 x 10(exp -6), both relative to H2. In addition, advantage will be taken of SWAS's relatively large beamsize of 3.2 x 4.0 arcminutes at 551 GHz and 3.6 x 4.5 arcminutes at 492 GHz to obtain large-area (approx. 1 deg x 1 deg) maps of giant and dark clouds in the CO-13 and CI lines. SWAS is scheduled for launch in mid-1995.

Melnick, Gary J.↗

NASA NTRS2002

Chemical structure of a protostellar core: B68

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star formation interstellar chemistry↗

NASA NTRS1996

First Astronomical Detection of the Carbene Chain H2C6

The cumulene carbenes are important components of hydrocarbon chemistry in low mass star forming cores. Here we report the first astronomical detection of the long chain cumulene carbene H(sub 2)C(sub 6), in the insterstellar cloud TMC1, from observations of two of its rotational transitions:...

interstellar molecules star formation hydrocarbon ↗

NASA NTRS2020

Early Science from GOTHAM: Project Overview, Methods, and the Detection of Interstellar Propargyl Cyanide (HCCCH2CN) in TMC-1

We present an overview of the GBT Observations of TMC-1: Hunting Aromatic Molecules Large Program on the Green Bank Telescope. This and a related program were launched to explore the depth and breadth of aromatic chemistry in the interstellar medium at the earliest stages of star formation, following our earlier detection of benzonitrile (c-C6H5CN) in TMC-1. In this work, details of the observations, use of archival data, and data reduction strategies are provided. Using these observations, the interstellar detection of propargyl cyanide (HCCCH2CN) is described, as well as the accompanying laboratory spectroscopy. We discuss these results, and the survey project as a whole, in the context of investigating a previously unexplored reservoir of complex, gas phase molecules in pre-stellar sources. A series of companion papers describe other new astronomical detections and analyses.

Brett A McGuire↗

NASA NTRS1986

Effects of stellar outflows on interstellar sulfur oxide chemistry

Interferometer Maps with 2" to 6" resolution of a number of regions with active star formation (Orion A, W49, W51, SGRB2) show that the distribution of the molecule SO is very compact around stellar outflow sources. Both SO and SO2 were studied near three outflows, OrionA/IRc2 and two sources in W49. The two molecules have similar distributions and abundances. More than 95% of the emission comes from regions whose extents are only .05 to .2 pc., being larger around the more energetic sources. Their spectra are broad, 30 km/sec or more, suggesting that the oxide production is associated with the flows. The outflows are identified by water masers and by extended bipolar flows in SiO. Maps in other molecules, such as HCO+ and CS, which have similar collisional excitation requirements, have much greater spatial extent. Thus it appears that the SO and SO2 abundances are truly compact and are closely associated with the outflows.

Welch, W. J.↗

NASA NTRS1986

Boundary conditions for the paleoenvironment: Chemical and Physical Processes in dense interstellar clouds

The present research includes searches for important new interstellar constituents; observations relevant to differentiating between different models for the chemical processes that are important in the interstellar environment; and coordinated studies of the chemistry, physics, and dynamics of molecular clouds which are the sites or possible future sites of star formation. Recent research has included the detection and study of four new interstellar molecules; searches which have placed upper limits on the abundance of several other potential constituents of interstellar clouds; quantitative studies of comparative molecular abundances in different types of interstellar clouds; investigation of reaction pathways for astrochemistry from a comparison of theory and the observed abundance of related species such as isomers and isotopic variants; studies of possible tracers of energenic events related to star formation, including silicon and sulfur containing molecules; and mapping of physical, chemical, and dynamical properties over extended regions of nearby cold molecular clouds.

Irvine, W. M.↗

NASA NTRS1995

Interstellar Grain Surface Chemistry

Chemistry on grain surfaces plays an Important role in the formation of interstellar Ices, It can also influence the composition of the gas phase through outgassing near luminous, newly formed stars. This paper reviews the chemical processes taking place on Interstellar grain surfaces with the emphasis on those transforming CO into other hydrocarbons. At low, molecular cloud temperatures (approximately equal to 10K), physisorption processes dominate interstellar grain surface chemistry and GO is largely hydrogenated through reactions with atomic H and oxidized through reactions with atomic O. The former will lead to the formation of H2CO and CH3OH ices, while the latter results in CO2 ice. The observational evidence for these ices in molecular clouds will be discussed. Very close to protostars, the gas and grain temperatures are much higher (approximately equal to 500K) and chemisorption processes, including catalytic surface reactions, becomes important. This will be illustrated based upon our studies of the Fischer-Tropsch Synthesis of CH4 from CO on metallic surfaces. Likely, this process has played an important role in the early solar nebula. Observational consequences will be pointed out.

Tielens, Alexander G. G. M.↗

NASA NTRS1988

Observations of star formation

The present observational status of objects that have some bearing on star formation are reviewed: giant molecular clouds, cloud cores and T-Tauri stars, outflows, infall, disks, and interstellar chemistry. Prospects for the future are summarized.

Welch, William J.↗

NASA NTRS1994

Ion Chemistry in Atmospheric and Astrophysical Plasmas

There are many differences and also remarkable similarities between the ion chemistry and physics of planetary ionospheres and the ion chemistry and physics of astronomical environments beyond the solar system. In the early Universe, an expanded cooling gas of hydrogen and helium was embedded in the cosmic background radiation field and ionized by it. As the Universe cooled by adiabatic expansion, recombination occurred and molecular formation was driven by catalytic reactions involving the relict electrons and protons. Similar chemical processes are effective in the ionized zones of gaseous and planetary nebulae and in stellar winds where the ionization is due to radiation from the central stars, in the envelopes of supernovae where the ionization is initiated by the deposition of gamma-rays, in dissociative shocks where the ionization arises from electron impacts in a hot gas and in quasar broad-line region clouds where the quasar is responsible for the ionization. At high altitudes in the atmospheres of the Jovian planets, the main constituents are hydrogen and helium and the ion chemistry and physics is determined by the same processes, the source of the ionization being solar ultraviolet radiation and cosmic rays. After the collapse of the first distinct astronomical entities to emerge from the uniform flow, heavy elements were created by nuclear burning in the cores of the collapsed objects and distributed throughout the Universe by winds and explosions. The chemistry and physics became more complicated. Over 90 distinct molecular species have been identified in interstellar clouds where they are ionized globally by cosmic ray impacts and locally by radiation and shocks associated with star formation and evolution. Complex molecules have also been found in circumstellar shells of evolved stars. At intermediate and low altitudes in the Jovian atmospheres, the ion chemistry is complicated by the increasing abundance of heavy elements such as carbon, and an extensive array of complex molecules has been predicted. Reactions involving heavy elements dominate the structure of the ionspheres of the terrestrial planets and the satellites Titan and Triton.

Dalgarno, A.↗

NASA NTRS2018

The Nature of Interstellar Organics and Their Relationship to the Solar System

Carbonaceous materials are a primary compo-nent of interstellar dust, forming in the outflow of carbon stars and the diffuse interstellar me-dium (DISM). Over time, the low density DISM is swept into dense molecular clouds, the principal formation sites and repositories of most interstellar molecules. Organic com-pounds created in these clouds are the first step towards the complex materials that help to make planets habitable. Ground- and space-based telescopic observations trace interstellar organics from the diffuse to dense interstellar clouds, revealing that organic material in the diffuse ISM is predominantly hydrocarbon in nature, possessing little N or O, with the C distributed between the aromatic and aliphatic forms. A remarkable similarity between the hydrocarbons in dust in our Galaxy to that of distant galaxies, indicates that this organic component of the DISM is widespread and may be an important universal reservoir of prebiotic organic carbon. Spectroscopy of background stars seen through quiescent dust in clouds with no star formation activity re-veals that chemistry occurs early-on. Mean-while, observations of certain asteroids, com-ets, interplanetary dust particles, planets and planetary satellites present an intricate inter-weaving of preserved interstellar components and those that have been subsequently altered. The composition ofinterstellar dust grains and the evolution of dust between dense clouds (where stars and planetary systems form) and the diffuse inter-stellar medium (where stardust components are ejected), will be presented in this workshop on Carbon in the Solar System.

Intersteller Organics↗

NASA NTRS2022

A GALAH View of the Chemical Homogeneity and Ages of Stellar Strings Identified in Gaia

The advent of Gaia has led to the discovery of nearly 300 elongated stellar associations (called ‘strings’) spanning hundreds of parsecs in length and mere tens of parsecs in width. These newfound populations present an excellent laboratory for studying the assembly process of the Milky Way thin disc. In this work, we use data from GALAH DR3 to investigate the chemical distributions and ages of 18 newfound stellar populations, 10 of which are strings and 8 of which are compact in morphology. We estimate the intrinsic abundance dispersions in [X/H] of each population and compare them with those of both their local fields and the open cluster (OC) M 67. We find that all but one of these groups are more chemically homogeneous than their local fields. Furthermore, half of the strings, namely Theias 139, 169, 216, 303, and 309, have intrinsic [X/H] dispersions that range between 0.01 and 0.07 dex in most elements, equivalent to those of many OCs. These results provide important new observational constraints on star formation and the chemical homogeneity of the local interstellar medium (ISM). We investigate each population’s Li and chemical clock abundances(e.g. [Sc/Ba], [Ca/Ba], [Ti/Ba], and [Mg/Y]) and find that the ages suggested by chemistry generally support the isochronal ages in all but six structures. This work highlights the unique advantages that chemistry holds in the study of kinematically related stellar groups.

Stars: abundances↗

NASA NTRS1985

Interstellar clouds - From a dynamical perspective on their chemistry

The possibility is examined that in the course of its dynamical evolution, a single mass of interstellar gas would exhibit properties of diffuse clouds, dense clouds and finally also of clouds perturbed by shocks or intense UV or X-ray radiation generated by a star of its own creation. This concept provides a common thread through the bewildering diversity of physical and chemical compositional properties shown by interstellar clouds. From this perspective, instead of being static objects, interstellar clouds are possibly incessantly evolving from initially diffuse to later dense state and then to star formation which ultimately restructures or disperses the remaining cloud material to begin the whole evolutionary process once again. Based on a simplified study of interstellar chemistry from a dynamical perspective, the ideas are presented as an heuristic: to encourage thought on the future direction of molecular astrophysics and the need to consider the chemical behavior of interstellar clouds in conjunction with, rather than in isolation from, their dynamical behavior. A physical basis must be sought for the semiempirical temperature formula which has been given a critical role in the collapse of diffuse clouds. Self-shielding effects in the chemistry of CO were neglected and this drawback should be removed; the ability of the model to explain the fractional abundances of more complex molecules, such as cyanopolyynes, should be examined.

Prasad, S. S.↗

NASA NTRS2002

Current Status of High Performance Large Format Si:As IBC Detectors for SOFIA-like Applications

Airborne and space telescope astronomical observations in the 5-25 micrometer wavelength region, are critical for understanding the physical conditions, composition, chemistry, and excitation of many environments in the interstellar medium, external galaxies, solar system objects, extra-solar systems, and stars. The scientific impact is particularly unique in the 5-8 micrometer and 14-25 micrometer regions which are inaccessible or poorly observed from ground-based observatories. Large-format area mid-infrared (MIR) detectors sensitive over these wavelengths and operable under moderate backgrounds (greater than 10(circumflex)6 e-/s at R=2000, 10(micrometers)) are essential for efficient large-area survey imaging and for taking moderate resolution spectra over a large spectral range. Both SOFIA and passively cooled Explorer observatories could benefit from this technology. Current first-light SOFIA instruments use small-format MIR FPA's of sizes 128x128 and 256x256, With the collaboration of Raytheon Infrared Operations (RIO), NASA-ARC has been testing the first device of this kind, a combination of 1) the ALADDIN III readout multiplexer, cryo-processed for 6K operation, with 2) SIRTF IRAC-like Sides IBC detector material. designed for higher QE and low dark current. Here we report requirements. design, and initial fabrication and testing of the first 1024x1024 Si:As IBC mid-IR detector array for these conditions. This device has exhibited low dark current, moderate noise levels, and greater than 200,000 electron linear well size at 6K operation. We conclude with suggestions for future device development for optimal performance under moderate background, SOFIA- and low Earth orbit observing conditions.

Ennico, Kimberly↗

NASA NTRS2020

Unusually High CO Abundance of the First Active Interstellar Comet

Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during their birth at the time of planet formation. To-date, there have been no confirmed observations of parent volatiles (gases released directly from the nucleus) of a comet from any planetary system other than our own. Here we present high-resolution, interferometric observations of 2I/Borisov, the first confirmed interstellar comet, obtained using the Atacama Large Millimeter/ submillimeter Array (ALMA) on 15th-16th December 2019. Our observations reveal emission from hydrogen cyanide (HCN), and carbon monoxide (CO), coincident with the expected position of 2I/Borisov’s nucleus, with production rates Q(HCN) = (7.0 ± 1.1) x 10(exp 23)/s and Q(CO) = (4.4 ± 0.7) x 10(exp 26)/s. While the HCN abundance relative to water (0.06–0.16%) appears similar to that of typical, previously observed comets in our Solar System, the abundance of CO (35–105%) is among the highest observed in any comet within 2 au of the Sun. This shows that 2I/Borisov must have formed in a relatively CO-rich environment — probably beyond the CO ice-line in the very cold, outer regions of a distant protoplanetary accretion disk, as part of a population of small, icy bodies analogous to our Solar System’s own proto-Kuiper Belt.

Cordiner, M. A.↗