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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

RESOLVE Mission Architecture for Lunar Resource Prospecting and Utilization

Design Reference Mission (DRM) evaluations were performed for The Regolith & Environment Science, and Oxygen & Lunar Volatile Extraction (RESOLVE) project to determine future flight mission feasibility and understand potential mission environment impacts on hardware requirements, science/resource assessment objectives, and mission planning. DRM version 2.2 (DRM 2.2) is presented for a notional flight of the RESOLVE payload for lunar resource ground truth and utilization (Figure 1) [1]. The rover/payload deploys on a 10 day surface mission to the Cabeus crater near the lunar south pole in May of 2016. A drill, four primary science instruments, and a high temperature chemical reactor will acquire and characterize water and other volatiles in the near sub-surface, and perform demonstrations of In-Situ Re-source Utilization (ISRU). DRM 2.2 is a reference point, and will be periodically revised to accommodate and incorporate changes to project approach or implementation, and to explore mission alternatives such as landing site or opportunity.

George, J. A.↗
NASA NTRS2017

Documenting Surface and Sub-surface Volatiles While Drilling in Frozen Lunar Simulant

NASA's Resource Prospector (RP) mission is intended to characterize the three-dimensional nature of volatiles in lunar polar regions and permanently shadowed regions. RP is slated to carry two instruments for prospecting purposes. These include the Neutron Spectrometer System (NSS) and Near-Infrared Volatile Spectrometer System (NIRVSS). A Honybee Robotics drill (HRD) is intended to sample to depths of 1 m, and deliver a sample to a crucible that is processed by the Oxygen Volatile Extraction Node (OVEN) where the soil is heated and evolved gas is delivered to the gas chromatograph / mass spectrometer of the Lunar Advanced Volatile Analysis system (LAVA). For several years, tests of various sub-systems have been undertaken in a large cryo-vacuum chamber facility (VF-13) located at Glenn Research Center. In these tests a large tube (1.2 m high x 25.4 cm diameter) is filled with lunar simulant, NU-LHT-3M, prepared with known abundances of water. There are thermo-couples embedded at different depths, and also across the surface of the soil tube. The soil tube is placed in the chamber and cooled with LN2 as the pressure is reduced to approx.5-6x10(exp -6) Torr. Here we discuss May 2016 tests where two soil tubes were prepared and placed in the chamber. Also located in the chamber were 5 crucibles, an Inficon mass spectrometer, and a trolly permitting x-y translation, where the HRD and NIRVSS, were mounted. The shroud surrounding the soil tube was held at different temperatures for each tube to simulate a warm and cold lunar environment.

Oxygen Volatile Extraction Node↗
NASA NTRS2016

Characterization of Potential Springs in the Lower Colorado Desert of Southern California using Satellite Radar and Landsat Time Series Analysis

Renewable energy development in southern California is receiving increasing attention due to potential impacts on wildlife habitats and water sources. This study was designed to quantify and map, for the first time, sub-surface water sources from springs in the Lower Colorado Desert area of southern California using satellite radar data and 30 years of Landsat satellite image data. Synthetic Aperture Radar (SAR) data was used to identify sub-surface water sources not already documented as springs or seeps in the National Hydrography Database. Landsat imagery starting in 1985 was used to characterize vegetation growth patterns at these suspected spring locations detected from SAR analysis. Results showed a total of 104 potential spring locations across the Lower Colorado Desert study area, 19 of which were detected within Solar Energy Zone (SEZ) development boundaries, roughly evenly split between Riverside East and Imperial East, and 13 of which (both inside and outside SEZs) showed relatively high green vegetation index values over the period of 1985 to 2015 that would depend on non-precipitation water sources associated with active springs.

DRECP↗
NASA NTRS2004

Habitat Inspection Scanner, Bio-Structure Scanner, and In Situ Sub-Surface Composition Sensor

The extension of dielectric and inductive spectroscopy into in situ observations represents a significant exploration-enabling tool. This technology can be widely applied from microscopic to macroscopic. Dielectrometry and inductometry can measure sub-surface composition and its distribution. The primary environment that we cannot easily explored is the sub-surface of solid bodies. Weather as part of our equipment that we bring with us, or the locations we are exploring. These fundamental questions lie at the core of the exploration Initiative. To answer them we must use a whole host of complimentary tools including those that allow us to practically examine the sub-surface environment. A nondestructive approach offers significant advantages for both the initial identification of likely samples but also the monitoring of ecosystems and crew health. These include materials characterization, nondestructive inspection, and process quality control, damage monitoring, and hidden object detection and identification. The identification of natural resources such as water on the Moon or Mars is of great importance to the utilization of local resource in the support of human exploration crews. On the macroscopic scale, the understanding of what resources are available and how they are distributed is of primary importance to their productive utilization. Even if initial explorations do not require the use of local resources to succeed, eventual settlement and commercial development will. The routine examination of the structural integrity (micro cracks, leaks) of hi.inafi habitats in harsh envkmments ww!d also be enabled.

VanSteenberg, Michael↗
NASA NTRS2019

SPARROW: Steam Propelled Autonomous Retrieval Robot for Ocean Worlds

The Steam Propelled Autonomous Retrieval Robot (SPARROW) for Ocean Worlds was a Phase I mission concept study funded under the NASA NIAC program. This report represents the findings of that study and recommendations for future work. SPARROW, envisioned as a soccer ball-sized payload to a primary lander mission, is a propulsively hopping robot for the exploration of Europa's rugged, icy surface. A multi-thruster, passively gimballed robot within a protective, spherical shell, SPARROW is able to freely rotate, self-right, and tumble over chaotic terrains. Europa's abundant surface ice would be harvested as an in situ propellant source. The principal objective of SPARROW is to increase the science return of a Europa landed asset by enabling access to distal, spatially distributed geologic units. The design of mobility systems for Europa is challenging, due in part to its almost entirely unconstrained surface topography and strength. Images returned by Voyager and Galileo yielded resolutions on the order of hundreds of meters per pixel, with localized regions reaching 6 meters per pixel—still far larger than a typical rover. A key benefit of SPARROW's hopping, impact-tolerant design, is that it eliminates the need for a priori information regarding terrain topography and surface strength; no surface reaction forces are required for motion. In this context, SPARROW is believed to be entirely terrain agnostic. In this report we detail the results of three study objectives: i) to quantify the energy required to collect surface ice, change its phase, and maintain propellant temperature, ii) to identify control and estimation strategies that enable SPARROW to successfully reach, and return from, regions of scientific interest, and iii) to characterize the impact of SPARROW's range on likely science return. Five water-based propellant architectures are presented alongside their mass, power, and volume requirements. Monte Carlo simulations of SPARROW hopping and tumbling over 1 km of glacial ice are summarized, characterizing SPARROW's sensitivity to uncertainty in: initial pose, thrust profile, and vehicle-terrain interaction. A science traceability matrix is presented, which details the effect of sortie range on three science goals: constraining Europa's evolutionary morphology, assessing sub-surface ocean habitability, and searching for life and/or biosignatures.

Autonomous↗
NASA NTRS2019

SPARROW: A Steam Propelled Autonomous Retrieval Robot for Ocean Worlds

This paper presents the results of a NIAC Phase I study into the use of a propulsively hopping robot for the exploration of Europa’s rugged, icy surface. Named the“Steam Propelled Retrieval Robot for Ocean Worlds,” SPARROW is a multi-thruster robot passively gimballed within a protective, spherical shell, which enables it to freely rotate, self-right, and tumble over chaotic terrains. SPARROW is envisioned as a soccerball-sized payload to a primary lander mission. Europa’s abundant surface ice would be harvested as an in situ propellant source. The principal objective of SPARROW would be to increase the science return of a Europa landed asset by enabling access to distal, spatially distributed geologic units. The design of mobility systems for Europa is challenging, due in part to its almost entirely unconstrained surface topography and strength. Images returned by Voyager and Galileo yielded resolutions on the order of hundreds of meters per pixel, with localized regions reaching 6 meters per pixel—still far larger than a typical rover. A key benefit of SPARROW’s hopping, impact-tolerant design, is that it eliminates the need for a piori information on the terrain topography and surface strength; no surface reaction forces are required for motion. In this context, SPARROW is entirely terrain agnostic. In this paper we detail the results of three study objectives: i) to quantify the energy required to collect surface ice, change its phase, and maintain propellant temperature, ii) to identify control and estimation strategies that enable SPARROW to successfully reach, and return from, regions of scientific interest, and iii) to characterize the impact of SPARROW’s range on likely science return. Five water-based propellant architectures are presented alongside their mass, power, and volume requirements. Monte Carlo simulations of SPARROW hopping and tumbling over 1 km of glacial ice are summarized, characterizing SPARROW’s sensitivity to uncertainty in: initial conditions, thrust control, and cage-terrain interaction. Finally, a science traceability matrix is presented, which details the effect of sortie range on three science goals: constraining Europa’s evolutionary morphology, assessing sub-surface ocean habitability, and searching for life and/or biosignatures.

Phillips, Cynthia↗
NASA NTRS2001

Detection of Sub-Surface Water on Mars by Controlled and Natural Source Electromagnetic Induction

Detection of subsurface liquid water on Mars is a leading scientific objective for Mars exploration in this decade. We describe electromagnetic induction (EM) methods that are both uniquely well suited for detection of subsurface liquid water on Mars and practical within the context of a Mars exploration program. EM induction methods are ideal for detection of more highly conducting (liquid water bearing) soils and rock beneath a more resistive overburden. A combined natural source and controlled source method offers an efficient and unambiguous characterization of the depth to liquid water and the extent of the aqueous region. The controlled source method employs an ac vertical dipole source (horizontal loop) to probe the depth to the conductor and a natural source method (gradient sounding) to characterize its conductivity-thickness product. These methods are proven in geophysical exploration and can be tailored to cope with any reasonable Mars crustal electrical conductivity. We describe a practical experiment and discuss experiment optimization to address the range of material properties likely encountered in the Mars crust.

Connerney, J. E. P.↗
NASA NTRS2015

Attempt of Serendipitous Science During the Mojave Volatile Prospector Field Expedition

On 23 October a partial solar eclipse occurred across parts of the southwest United States between approximately 21:09 and 23:40 (UT), with maximum obscuration, 36%, occurring at 22:29 (UT). During 21-26 October 2014 the Mojave Volatile Prospector (MVP) field expedition deployed and operated the NASA Ames Krex2 rover in the Mojave desert west of Baker, California (Fig. 1, bottom). The MVP field expedition primary goal was to characterize the surface and sub-surface soil moisture properties within desert alluvial fans, and as a secondary goal to provide mission operations simulations of the Resource Prospector (RP) mission to a Lunar pole. The partial solar eclipse provided an opportunity during MVP operations to address serendipitous science. Science instruments on Krex2 included a neutron spectrometer, a near-infrared spectrometer with associated imaging camera, and an independent camera coupled with software to characterize the surface textures of the areas encountered. All of these devices are focused upon the surface and as a result are downward looking. In addition to these science instruments, two hazard cameras are mounted on Krex2. The chief device used to monitor the partial solar eclipse was the engineering development unit of the Near-Infrared Volatile Spectrometer System (NIRVSS) near-infrared spectrometer. This device uses two separate fiber optic fed Hadamard transform spectrometers. The short-wave and long-wave spectrometers measure the 1600-2400 and 2300-3400 nm wavelength regions with resolutions of 10 and 13 nm, respectively. Data are obtained approximately every 8 seconds. The NIRVSS stares in the opposite direction as the front Krex2.

soil moisture properties↗
NASA NTRS2019

Spacecraft Induced Molecular Return Flux Considerations for Icy Moon Missions Targeting Detection of Organics with Mass Spectrometers

Science missions targeting the detection of organics from jet plumes originating from icy moons (i.e. Europa and Enceladus) will employ next-generation, state-of-the-art mass spectrometers to measure the composition of icy moon plume effluents and exospheres. During fly-bys, as mass spectrometers make their scientific measurements, molecular emissions from the spacecraft can interact with the local exosphere and associated jet plumes from the sub-surface oceans of the icy moons. Spacecraft-induced molecular effluents collide with molecules from the ambient exosphere, and a fraction of the spacecraft emissions are returned to the spacecraft and its complement of science instruments. The rate at which emitted molecules are returned to the spacecraft by collisions with other molecules (e.g. in Europa’s exosphere) is the return flux. The return flux of molecular emission from spacecraft sources is a major contributor to contaminant deposition onto the complement of contamination-sensitive instruments. Characterization of return flux is critical to the definition of requirements for materials outgassing for the spacecraft and its instruments, and for the definition of thruster operations.

Soares, C. E.↗
NASA NTRS2018

The Mars Reconnaissance Orbiter Mission: 2018 Status

The Mars Reconnaissance Orbiter (MRO) continues its dual-mode mission of scientific exploration and programmatic support. Now in its 13th year of flight (and its 12th year in its low-altitude, sun-synchronous orbit around Mars), the spacecraft continues in its normal flight mode and its science instruments continue to acquire a treasure trove of data which is being used to study the Martian environment (surface, sub-surface, and atmosphere). To date (July 2018), more than 333 TB of scientific data have been returned to Earth. Building onto the 2017 IAC paper: “The Mars Reconnaissance Orbiter Mission: Continuing a Record of Exploration from Mars Orbit,” [1] this paper provides a 2018 status update on the MRO Mission. A signature event since the 2017 writing is the onset and evolution of a planet-encircling dust event (PEDE), the first such event since 2007. Additional recent science highlights for MRO include the discovery of mid-latitude ice cliffs, polar cap characterization, daily global mapping of the 2018 PEDE dust activity and the atmospheric thermal response, further characterization of the tantalizing recurring slope lineae (RSL), and continued detection of surface changes. Programmatically, UHF relay support for the Mars Science Laboratory (MSL) rover Curiosity and the Mars Exploration Rover (MER) rover Opportunity continues at a pace that provides the engineers and scientists operating those surface vehicles timely information to support their mission planning and science analysis. Most of the landing site characterization requests for the NASA Mars 2020 rover and the ESA ExoMars Rover/Surface Platform (RSP) missions have been completed, with final acquisitions delayed due to the obscuring dust haze from the current PEDE. In parallel, the flight team has faced new engineering challenges as the spacecraft has aged. The team has developed and is implementing actions that are aimed at stretching spacecraft battery life. A new all-stellar capability using the spacecraft’s star trackers now allows for normal spacecraft operations without IMUs. In addition to its current relay duties, MRO will be synchronized to provide critical communications support for the InSight Entry, Descent, and Landing (EDL) event on November 26, 2018, and will be readied to support InSight’s critical commissioning phase with UHF relay support and environmental characterization. A new split-pass relay capability has been developed which will allow MRO to relay with two surface vehicles in “close proximity” on the same overflight, i.e. the InSight lander and the Curiosity rover. Extended for another year of operations by NASA, this paper will highlight recent scientific progress and describe actions that will extend MRO’s life well into the 2020’s as a key element of the Mars Exploration Program.

Zurek, Richard W.↗
NASA NTRS2003

On the Determination of Local Sites for Shallow Ground Water Prospection Using Low Frequency Sounding Radars on Mars

Low frequency sounding radars should be able to probe the Martian subsurface layers down to varying depths, depending on the geo-electrical properties of the sounded sites. We present in this work four frequency dependent geo-electrical models of the Martian subsurface in the 1-20 MHz frequency band, based on laboratory electromagnetic characterization of Martian soil analogues. Those models correspond to local Martian sites, where we considered particular interest for the search of water using mainly the Ground Penetrating Radar (GPR) instrument of the Netlander mission. Results and discussion are also valid for both sounding experiments MARSIS and SHARAD. The four models of the Martian subsurface are designed to represent terrains where recent fluvial like features suggest the presence of near subsurface ground ice and probably liquid water. We performed measurements on volcanic and sedimentary materials that may be present on these sites under the appropriate geophysical conditions that may exist in those terrains. We then simulated the backscattered radar echo arising from each site in the 2 MHz frequency band, using the Finite Difference Time Domain (FDTD) algorithm, in order to evaluate the instrument performances to probe the subsurface stratigraphy of each site. Our results confirm that the near subsurface rich iron oxide mineralogy controls the instrument performances in terms of penetration depth and signal to noise ratio in the 2 MHz frequency band. We also discuss the geophysical and geo-electrical sounding conditions that could lead to an ambiguous detection of shallow subsurface water on Mars for the Netlander GPR. Finally we hope to present by the conference time a terrestrial test analogue site selected according to those creteria where deep sub-surface water have been detected 600 m deep using a prototype of the 2 MHz Netlander GPR in a field survey performed last febrary in the eastern part of the Egyptian desert.

Heggy, E.↗
DOE OSTI2025

Rational Selection of Transition-Metal Oxide Electrocatalysts from Structure Electronic Structure-Activity Relations: The Role of Defects, Strain, and Sub-Surface Layering

This BES research investigates the physicochemical properties of metal oxides and how they affect electrocatalytic functionalities. The goal is to develop a predictive framework for realizing top-performing electrocatalytic materials for energy-critical reactions. The hypothesis is that well-defined thin films allow detailed mapping of structural-activity relationships because flat surfaces are more straightforward to characterize. Furthermore, the well-defined nature of thin-film metal oxides allows precise tuning of structural and chemical variables for structure-activity-relationship mapping. The proposed research has two technical objectives. The first is to experimentally assess whether the binding energies of surface oxygen can serve as an activity descriptor for oxygen electrocatalysis on metal oxides and then how to control them by tuning the structure and chemical variables. The second is to find the rate-limiting process in oxygen electrocatalysis and other small-molecule reactions. Similar mechanistic insights have been developed on well-defined platinum surfaces but not yet on oxides. This research addresses this gap and uses electrochemistry and X-ray photoemission spectroscopy to study oxide surface chemistry. The obtained insights are collectively analyzed to reveal how the oxides’ structural and chemical variables affect kinetics and can be used to design more active electrocatalysts for energy-critical reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1979

Characterization of electrical discharges on Teflon dielectrics used as spacecraft thermal control

The dual effects of system degradation and reduced life of synchronous-orbit satellites as a result of differential spacecraft charging underscore the need for a clearer understanding of the prevailing electrical discharge phenomena. In a laboratory simulation, the electrical discharge current, surface voltage, emitted particle fluxes, and photo-emission associated with discharge events on electron beam irradiated silver-backed Teflon samples were measured. Sample surface damage was examined with optical and electron beam microscopes. The results are suggestive of a model in which the entire sample surface is discharged by lateral sub-surface currents flowing from a charge deposition layer through a localized discharge channel to the back surface of the sample. The associated return current pulse appears to have a duration which may be a signature by which different discharge processes may be characterized.

Yadlowsky, E. J.↗
NASA NTRS2001

The Use of CASES-97 Observations to Assess and Parameterize the Impact of Land-Surface Heterogeneity on Area-Average Surface Heat Fluxes for Large-Scale Coupled Atmosphere-Hydrology Models

To understand the effects of land-surface heterogeneity and the interactions between the land-surface and the planetary boundary layer at different scales, we develop a multiscale data set. This data set, based on the Cooperative Atmosphere-Surface Exchange Study (CASES97) observations, includes atmospheric, surface, and sub-surface observations obtained from a dense observation network covering a large region on the order of 100 km. We use this data set to drive three land-surface models (LSMs) to generate multi-scale (with three resolutions of 1, 5, and 10 kilometers) gridded surface heat flux maps for the CASES area. Upon validating these flux maps with measurements from surface station and aircraft, we utilize them to investigate several approaches for estimating the area-integrated surface heat flux for the CASES97 domain of 71x74 square kilometers, which is crucial for land surface model development/validation and area water and energy budget studies. This research is aimed at understanding the relative contribution of random turbulence versus organized mesoscale circulations to the area-integrated surface flux at the scale of 100 kilometers, and identifying the most important effective parameters for characterizing the subgrid-scale variability for large-scale atmosphere-hydrology models.

Chen, Fei↗
NASA NTRS2004

Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling

Mars is the most Earth-like of the Solar System s planets, and the first place to look for any sign of present or past extraterrestrial life. Its surface shows many features indicative of the presence of surface and sub-surface water, while impact cratering and volcanism have provided temporary and local surface heat sources throughout Mars geologic history. Impact craters are widely used ubiquitous indicators for the presence of sub-surface water or ice on Mars. In particular, the presence of significant amounts of ground ice or water would cause impact-induced hydrothermal alteration at Martian impact sites. The realization that hydrothermal systems are possible sites for the origin and early evolution of life on Earth has given rise to the hypothesis that hydrothermal systems may have had the same role on Mars. Rough estimates of the heat generated in impact events have been based on scaling relations, or thermal data based on terrestrial impacts on crystalline basements. Preliminary studies also suggest that melt sheets and target uplift are equally important heat sources for the development of a hydrothermal system, while its lifetime depends on the volume and cooling rate of the heat source, as well as the permeability of the host rocks. We present initial results of two-dimensional (2D) and three-dimensional (3D) simulations of impacts on Mars aimed at constraining the initial conditions for modeling the onset and evolution of a hydrothermal system on the red planet. Simulations of the early stages of impact cratering provide an estimate of the amount of shock melting and the pressure-temperature distribution in the target caused by various impacts on the Martian surface. Modeling of the late stage of crater collapse is necessary to characterize the final thermal state of the target, including crater uplift, and distribution of the heated target material (including the melt pool) and hot ejecta around the crater.

Pierazzo, E.↗
NASA NTRS2007

Mission Design Overview for the Phoenix Mars Scout Mission

The Phoenix mission "follows the water" by landing in a region where NASA's Mars Odyssey orbiter has discovered evidence of ice-rich soil very near the Martian surface. For three months after landing, the fixed Lander will perform in-situ and remote sensing investigations that will characterize the chemistry of the materials at the local surface, sub-surface, and atmosphere, and will identify potential provenance of key indicator elements of significance to the biological potential of Mars, including potential organics and any accessible water ice. The Lander will employ a robotic arm to dig to the ice layer, and will analyze the acquired samples using a suite of deck-mounted, science instruments. The development of the baseline strategy to achieve the objectives of this mission involves the integration of a variety of elements into a coherent mission plan.

Phoenix↗
NASA NTRS2008

The Telesupervised Adaptive Ocean Sensor Fleet (TAOSF) Architecture: Coordination of Multiple Oceanic Robot Boats

Earth science research must bridge the gap between the atmosphere and the ocean to foster understanding of Earth s climate and ecology. Ocean sensing is typically done with satellites, buoys, and crewed research ships. The limitations of these systems include the fact that satellites are often blocked by cloud cover, and buoys and ships have spatial coverage limitations. This paper describes a multi-robot science exploration software architecture and system called the Telesupervised Adaptive Ocean Sensor Fleet (TAOSF). TAOSF supervises and coordinates a group of robotic boats, the OASIS platforms, to enable in-situ study of phenomena in the ocean/atmosphere interface, as well as on the ocean surface and sub-surface. The OASIS platforms are extended deployment autonomous ocean surface vehicles, whose development is funded separately by the National Oceanic and Atmospheric Administration (NOAA). TAOSF allows a human operator to effectively supervise and coordinate multiple robotic assets using a sliding autonomy control architecture, where the operating mode of the vessels ranges from autonomous control to teleoperated human control. TAOSF increases data-gathering effectiveness and science return while reducing demands on scientists for robotic asset tasking, control, and monitoring. The first field application chosen for TAOSF is the characterization of Harmful Algal Blooms (HABs). We discuss the overall TAOSF architecture, describe field tests conducted under controlled conditions using rhodamine dye as a HAB simulant, present initial results from these tests, and outline the next steps in the development of TAOSF.

sensor web↗
NASA NTRS2016

Indigenous Carbonaceous Matter in the Nakhla Mars Meteorite

Detailed microanalysis of the Martian meteorite Nakhla has shown there are morphologically distinct carbonaceous features spatially associated with low-T aqueous alteration phases including salts and id-dingsite. A comprehensive suite of analytical instrumentation including optical microscopy, field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, focused ion beam (FIB) microscopy, transmission electron microscopy (TEM), two-step laser mass spectrometry (mu-L(sup 2)MS), laser mu-Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and nanoscale secondary ion mass spectrometry (NanoSIMS) are being used to characterize the carbonaceous matter and host mineralogy. The search for carbonaceous matter on Mars has proved challenging. Viking Landers failed to unambiguously detect simple organics at either of the two landing sites although the Martian surface is estimated to have acquired at least 10(exp15) kg of C as a consequence of meteoritic accretion over the last several Ga. The dearth of organics at the Martian surface has been attributed to various oxidative processes including UV photolysis and peroxide activity. Consequently, investigations of Martian organics need to be focused on the sub-surface regolith where such surface processes are either severely attenuated or absent. Fortuitously since Martian meteorites are derived from buried regolith materials they provide a unique opportunity to study Martian organic geochemistry.

Clemett, S. J.↗