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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

LITE Measurements of Sea Surface Directional Reflectance

The dependence of sea surface directional reflectance on surface wind speed from space-based lidar measurements of sea surface backscatter. In particular lidar measurements in the nidir angle range from 10-30 degrees appear to be most sensitive to surface wind speed variability in the regime below 10m/s.

Sea Surface Wind Speed↗

Nonlinear theory of elastic directed surfaces.

Nonlinear theory for deformation of elastic directed surface, assuming existence of strain energy function and postulating virtual work governing mechanical behavior

ELASTIC DEFORMATION↗

Radiant heat transfer between nongray directional surfaces.

Real surface property effects on local and overall heat transfer are studied for a simple system of interacting opaque surfaces. Wavelength, temperature and directional dependence of surface properties is included in the analysis for equal and unequal temperature specularly reflecting surfaces. Tungsten is employed as a representative metal and Roberts' model is used to describe the wavelength and temperature dependence of its optical parameters. The relationships of electromagnetic theory are employed to describe the directional dependence of spectral properties. Numerical results establish that gray direction independent property analysis adequately predicts the general trends of real surface analysis. The results also establish that spectral and temperature dependence of surface properties influences radiant heat transfer to a greater degree than does directional dependence of properties. Property models which adequately account for the nongray character of engineering surfaces while neglecting directional dependence of properties can provide heat transfer results of acceptable engineering accuracy.

Fischer, W. D.↗

Retrieval of Surface Directional Reflectance Properties Using Ground Level Multiangle Measurements

Knowledge of the directional reflectance properties of natural surfaces such as soils and vegetation canopies is essential for classification studies and canopy model inversion. Atmospheric correction schemes, using various levels of approximation, are described to retrieve surface bidirectional reflectance factors (BRFs) and directional-hemispherical reftectances (albedos)from multiangle radiance measurements taken at ground level. The retrieval schemes are tested on simulated data incorporating realistic surface BRFs and atmospheric models containing aerosols. Sensitivity of the atmospherically corrected BRFs and associated directional-hemispherical reflectances to various aerosol properties and the sun-view geometry is illustrated. A measurement strategy for obtaining highly accurate surface reflectance properties also is examined in the context of instrument radiametric calibration, knowledge of the atmospheric properties, and sun-view angular coverage.

Martonchik, John V.↗

Determination of Aerosol Optical Depth and Land Surface Directional Reflectances Using Multiangle Imagery

Spectral aerosol optical depths, surface hemispherical-directional reflectance factors, and bihemispherical reflectances (albedos) are retrieved for an area of Glacier National Park using spectral, multiangle imagery obtained with the airborne advanced solid state array spectroradiometer (ASAS). The retrieval algorithms are described and are identical in principle to those being devised for use by the multiangle imaging spectroradiometer (MISR) which will fly on the EOS-AMI spacecraft in 1998. As part of its science mission, MISR will produce global coverage of both aerosol amounts an an surface reflection properties. The results in this paper represent the initial effort in applying the MISR algorithms to real data. These algorithms will undergo additional testing and validation as more multiangle data become available.

Martonchik, John V.↗

Retrieval of Surface Directional Reflectance and Hemispherical Albedo Using Multi-angle Measurements, I. Ground Level Observations

Knowledge of the directional reflectance properties of natural surfaces such as soils and vegetation canopies is essential for classification studies and canopy model inversions. Atmospheric correction schemes, using various levels of approximation, are described to retrieve surface bidirectional reflectance factors (BRFs) and directional-hemispherical reflectances (albedos) from multi-angle radiance measurements taken at ground level.

factors (BRFs) radiometric calibration sun-view an↗

The hydrodynamic role of fish squamosal integument as an analog of surfaces directly formed by turbulent flow. Report 1: Similarity between irregularities in squamosal integument and those on surfaces formed by river bed flow

The distribution of squamae on the fish body and that of the deposits in the bed of the river can be described by the same equation. The curves reflecting the relative elongation and stability of the body shape of the fish continue the curves showing the elongation of bank spit and stability of the bed of the river.

Kudryashov, A. F.↗

Synergistic Assembly of Charged Oligomers and Amino Acids at the Air–Water Interface: An Avenue toward Surface-Directed CO 2 Capture

Interfaces are considered a major bottleneck in the capture of CO 2 from air. Efforts to design surfaces to enhance CO 2 capture probabilities are challenging due to the remarkably poor understanding of chemistry and self-assembly taking place at these interfaces. In this report we leverage surface-specific vibrational spectroscopy, Langmuir trough techniques, and simulations to mechanistically elucidate how cationic oligomers can drive surface localization of amino acids (AAs) that serve as CO 2 capture agents speeding up the apparent rate of absorption. We demonstrate how tuning these interfaces provides a means to facilitate CO 2 capture chemistry to occur at the interface, while lowering surface tension and improving transport/reaction probabilities. We show that in the presence of interfacial AA-rich aggregates, one can improve capture probabilities vs that of a bare interface, which holds promise in addressing climate change through the removal of CO 2 via tailored interfaces and associated chemistries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Diamonds in the Rough: Direct Surface Enhanced Infrared Spectroscopic Evidence of Nitrogen Reduction on Boron-Doped Diamond Supported Metal Catalysts

In situ investigations of electrocatalytic processes of increasing societal interest such as the nitrogen reduction reaction (NRR) re-quire aggressive experimental conditions that are not readily compatible with surface sensitive techniques such as attenuated total reflection surface enhanced infrared absorption spectroscopy (ATR-SEIRAS). A method for performing ATR-SEIRAS studies at very negative potentials where conventional IR-active films delaminate, and fail is reported. The method relies on a thin film of very robust boron-doped diamond deposited on a micromachined Si wafer, which provides extended mid-IR transparency at long wavelengths. SEIRAS activity is achieved by electrodepositing gold nanoparticles onto the conductive BDD layer. The Au@BDD layers are shown to sustain prolonged periods of electrolysis at negative potentials with no degradation of the modifying layer. The efficacy of these substrates for electrocatalysis is demonstrated by studying the reduction of N 2 at -1.5 V vs Ag/AgCl in an aqueous-based electrolyte. So under these conditions, direct spectroscopic evidence of both NH 3 and hydrazine formed from the nitrogen reduction reaction (NRR) is provided.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrodynamic role of fish squamosal integument as an analog of the surfaces directly formed by the turbulent flow. Report 2: Hydrodynamic function of squamosal integument

The stream flowing round the slowly swimming squama free fish can be laminized with the aid of the external slime coat alone. The slime of the fish with well developed squamae can laminize the stream together with the squamatic integument. Adjustments preventing a loss of the slime during laminization are better developed in the fastest squama free fishes.

Kudryashov, A. F.↗

Comparison of Different Global Information Sources Used in Surface Radiative Flux Calculation: Radiative Properties of the Surface

Direct estimates of surface radiative fluxes that resolve regional and weather-scale variabilty over the whole globe with reasonable accuracy have only become possible with the advent of extensive global, mostly satellite, datasets within the past couple of decades. The accuracy of these fluxes, estimated to be about 10-15 W per square meter is largely limited by the accuracy of the input datasets. The leading uncertainties in the surface fluxes are no longer predominantly induced by clouds but are now as much associated with uncertainties in the surface and near-surface atmospheric properties. This study presents a fuller, more quantitative evaluation of the uncertainties for the surface albedo and emissivity and surface skin temperatures by comparing the main available global datasets from the Moderate-Resolution Imaging Spectroradiometer product, the NASA Global Energy and Water Cycle Experiment Surface Radiation Budget project, the European Centre for Medium-Range Weather Forecasts, the National Aeronautics and Space Administration, the National Centers for Environmental Prediction, the International Satellite Cloud Climatology Project (ISCCP), the Laboratoire de Meteorologie Dynamique, NOAA/NASA Pathfinder Advanced Very High Resolution Radiometer project, NOAA Optimum Interpolation Sea Surface Temperature Analysis and the Tropical Rainfall Measuring Mission (TRMM) Microwave Image project. The datasets are, in practice, treated as an ensemble of realizations of the actual climate such that their differences represent an estimate of the uncertainty in their measurements because we do not possess global truth datasets for these quantities. The results are globally representative and may be taken as a generalization of our previous ISCCP-based uncertainty estimates for the input datasets. Surface properties have the primary role in determining the surface upward shortwave (SW) and longwave (LW) flux. From this study, the following conclusions are obtained. Although land surface albedos in the near near-infrared remain poorly constrained (highly uncertain), they do not cause too much error in total surface SW fluxes; the more subtle regional and seasonal variations associated with vegetation and snow are still on doubt. The uncertainty of the broadband black-sky SW albedo for land surface from this study is about 7%, which can easily induce 5-10 W per square meter uncertainty in (upwelling) surface SW flux estimates. Even though available surface (broadband) LW emissivity datasets differ significantly (3%-5% uncertainty), this disagreement is confined to wavelengths greater than 20 micrometers so that there is little practical effect (1-3 W per square meters) on the surface upwelling LW fluxes. The surface skin temperature is one of two leading factors that cause problems with surface LW fluxes. Even though the differences among the various datasets are generally only 2-4 K, this can easily cause 10-15 W per square meter uncertainty in calculated surface (upwelling) LW fluxes. Significant improvements could be obtained for surface LW flux calculations by improving the retrievals of (in order of decreasing importance): (1) surface skin temperature, (2) surface air and near-surface-layer temperature, (3) column precipitable water amount and (4) broadband emissivity. And for surface SW fluxes, improvements could be obtained (excluding improved cloud treatment) by improving the retrievals of (1) aerosols (from our sensitivity studies but not discussed in this work), and (2) surface (black-sky) albedo, of which, NIR part of the spectrum has much larger uncertainty.

Zhang, Yuanchong↗

Modification of Surface Energy via Direct Laser Ablative Surface Patterning

Surface energy of a substrate is changed without the need for any template, mask, or additional coating medium applied to the substrate. At least one beam of energy directly ablates a substrate surface to form a predefined topographical pattern at the surface. Each beam of energy has a width of approximately 25 micrometers and an energy of approximately 1-500 microJoules. Features in the topographical pattern have a width of approximately 1-500 micrometers and a height of approximately 1.4-100 micrometers.

Wohl, Christopher J., Jr.↗