Search NASA⌕ Search

SEARCH · Search NASA

Results for “time-resolved studies”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Time-resolved double-probe study in a He-Hg afterglow plasma

An experimental double-probe technique is described which allows the He(+) ion density to be measured directly as a function of time in the afterglow of a helium-metal-vapor discharge. As an application example, two CW laser transitions of the He-Hg(+) laser at 6150 and 7944 A are considered which both arise from excited 7p (2) P terms of Hg II. The time-resolved double-probe technique is used to measure the destruction rate of the He(+) ion density, which is then compared with the spontaneous-emission decay rate for 7p (2) P terms of Hg II. The results obtained show unambiguously and directly that the dominant excitation process for the two transitions considered is a charge-transfer collisional reaction of the form He(+) plus Hg yields He plus metastable Hg(+) plus the energy defect for this reaction. It is noted that the time-resolved double-probe technique may provide a simple method for measuring ion mobilities in a multi-ion plasma.

Shay, T.↗
NASA NTRS1980

Time-resolved imaging and spectral studies of an X-ray burst from the globular cluster Terzan

The first image of an X-ray burst was recorded with the HRI detector at the Einstein Observatory while observing the globular cluster Terzan 2. The burst was coincident with a persistent X-ray source located near the center of the cluster (thus confirming an earlier suggested identification) and reached a peak luminosity exceeding 5 x 10 to the 38th (d/10 kpc) squared. After a rapid rise to peak luminosity, a double-peaked spectral variation was observed over the next approximately 20 s with anticorrelated changes in the apparent emission region radius and temperature derived from blackbody (and modified blackbody) spectral fits. A shell or disk geometry, which undergoes adiabatic expansion and contraction, may be implied for the burst emission region. Alternatively, Comptonization is required. It is also shown that the peak burst luminosity must exceed the Eddington limit.

Grindlay, J. E.↗
NASA NTRS1976

Photoionization and ion cyclotron resonance studies of the ion chemistry of ethylene oxide

The formation of the ethylene oxide molecular ion and its subsequent ion-molecule reactions leading to the products C2H5O(+) and C3H5O(+) have been studied using time-resolved photoionization mass spectroscopy, ion cyclotron resonance spectroscopy, and photoelectron spectroscopy. An examination of the effects of internal energy on reactivity shows that the ratio of C3H5O(+) to C2H5O(+) increases by an order of magnitude with a single quantum of vibrational energy. The formation of (C2H4O/+/)-asterisk in a collision-induced isomerization is found which yields a ring-opened structure by C-C bond cleavage. The relaxed ring-opened C2H4O(+) ion reacts with neutral ethylene oxide by CH2(+) transfer to yield an intermediate product ion C3H6O(+) which gives C3H5O(+) by loss of H.

Corderman, R. R.↗
NASA NTRS1977

The yield of N/2D/ atoms in the dissociative recombination of NO/+/

The quantum yield or branching ratio of N(2D) atoms formed in the reaction e + NO(+) yields N + O was measured to be 76% plus or minus 6%. Photoionization of buffered nitric oxide by a flash lamp was studied using time-resolved atomic absorption. Atoms were produced both by direct photodissociation and by dissociative recombination, and these two effects were separated by means of SF6 as an electron scavenger.

Kley, D.↗
NASA NTRS1978

Measurement of non-Maxwellian electron velocity distributions in a reflex discharge

The results of a ruby laser Thomson scattering study of the space and time-resolved electron velocity distributions in a pulsed Penning discharge in hydrogen are presented. Electron densities were to the order of 10 to the 13th/cu cm and temperatures were roughly 3 eV. This point is just prior to the cessation of the discharge ohmic heating pulse. For magnetic strengths less than 200 G, Maxwellian distributions were found over an energy range six times thermal energy. Temperatures agreed with Langmuir probe data. For fields of 450 G, chaotic plasma potentials were observed to be unstable and the Thomson scattering showed that the electron velocity distributions had central temperatures of 2 eV and wing temperatures of 15-12 eV.

Phipps, C. R., Jr.↗
NASA NTRS1982

Time-resolved spectroscopy of solid poly/1-vinyl naphthalene/ following electron beam pulse radiolysis - Pulse radiolytic studies on polymers

Transient emission studies following pulse radiolysis of solid poly(1-vinyl naphthalene) show existence of excited monomers and two excimers. Quenching experiments indicate that excimers are not formed directly by recombination of ions but probably by trapping of migrating monomeric excitation in preformed traps whose density is approximately one in 1000.

Coulter, D. R.↗
NASA NTRS1981

Image tube spectroscopic studies of rapid variables. IV - Spectroscopic and photometric observations of AE Aquarii

Photoelectric and time-resolved spectroscopic observations of the short-period eruptive binary AE Aqr are presented. The system has a period of 0.4116537 days, and emission and absorption-line components equal to 135 km/sec and 159 km/sec, respectively. The spectral type of the absorption-line component is found to be K5V, from which M1 = 0.82 solar mass, M2 = 0.69 solar mass, and i = 64 deg. A predominantly Ca II emission region occurs on the hemisphere of the K5V star facing the broad emission-line component, whose center of light is located 0.64 of the way from the inner Lagrangian point to the center of mass of the K star. This emission appears to be associated with the transfer of mass from the K5V star to the accretion disk surrounding the primary. In the absence of flare activity, the light of the system is variable in the orbital period with a range in V of about 0.16 mag; maxima occurs near the times of maximum recession velocity and during the approach of each of the two components of the system (0.25 P and 0.80 P).

Chincarini, G.↗
NASA NTRS1979

An analytical approach to evaluation of space radiation effects on materials for long-life missions

An analytical model was developed which quantifies effects on organic composite matrix materials of high energy electrons and of UV as well as interactions between the two radiations. Literature data on polyethylene were used to construct a degradation kinetics scheme corresponding to an Earth orbit at L=3. Analysis of the model showed that steady state concentrations of radicals put limits on accelerated test conditions. These conclusions were validated by an experimental study on polymethylmethacrylate using UV laser excitation. Relationships for balancing electron and UV radiations to equal acceleration factors are derived. Pulse radiolysis using an electron-beam along with time-resolved spectroscopy is shown to be able to separate primary form secondary reactions. Implications of these reactions to changes in engineering material properties are indicated. The use of mechanistic studies is discussed in the context of general test strategies for evaluating materials for space applications.

Moacanin, J.↗
NASA NTRS1972

Laser-induced gas breakdown - Spectroscopic and chemical studies.

Discussion of the results of several experimental investigations on laser-induced gas breakdown. The experiments included time-resolved spectroscopy, direct detection of H atoms with a TiO2 probe, and chemical reactions; each of them provided insight into the behavior of the medium at different times. Chemical reactions and explosions have been initiated by the laser beam when a plasma was created. No primary multiphotonic absorption and no macroscopic chemical reactions were observed below the breakdown threshold.

De Montgolfier, PH.↗
NASA NTRS1978

Temperature dependence of the rate constants for reactions of O/1D/ atoms with a number of halocarbons

Results are reported for an experimental study of the reactions of O(1D) with CCl4, CFCl3, CF2Cl2, CHFCl2, CHF2Cl, and CF2ClCFCl2 over the temperature range from 173 to 343 K, based on the time-resolved emission of O(1D) at 630 nm. The experiments involved photolysis of O3 by Nd-YAG laser pulses and measurements of 630-nm emission intensity in mixtures with He and the various halocarbons. Pseudo-first-order rate constants are derived from plots of the logarithms of the 630-nm emission intensities as a function of time for particular He/O3/halocarbon mixtures, and second-order rate constants are then obtained from plots of these pseudo-first-order rate constants as a function of halocarbon concentration at constant He and O3 concentrations. No temperature dependence of the second-order rate constants is observed over the range studied, within the precision of the measurements. It is found that the rate constants decrease as H is substituted for Cl in a halocarbon molecule and as F is substituted for H or Cl.

Davidson, J. A.↗
NASA NTRS1980

Ozone photolysis - Determination of the O/3P/ quantum yield at 266 nm

Direct production of O(3P) from the photodissociation of O3 at 266 nm has been observed by time-resolved resonance fluorescence following laser flash photolysis. The quantum yield for O(3P) production was determined to be 0.12 + or - 0.02 at this wavelength. This result confirms the qualitative observations of two previous photofragment studies and establishes an absolute value of the quantum yield for O(1D) production of 0.88. This value has been used as a basis for normalizing relative quantum yields in the fall-off region, and interpreting O(1D) kinetics studies.

Brock, J. C.↗
NASA NTRS1974

Shock-tube study of carbon monoxide dissociation kinetics

Carbon monoxide dissociation-rate data were obtained over the temperature range 5600-12,000 K. The experiments were conducted with undiluted CO to emphasize rate constants applicable to molecular gas systems. Data were obtained as time-resolved pressure measurements on the end wall of a shock tube and, in some cases, as emission histories of the C2 Swan system (0-0 band) behind incident shock waves. Results confirm the presence of C2 as an intermediate species in CO decomposition.

Hanson, R. K.↗
NASA NTRS1982

Picosecond flash spectroscopic studies on ultraviolet stabilizers and stabilized polymers

Spectroscopic and excited state decay kinetics are reported for monomeric and polymeric forms of ultraviolet stabilizers in the 2-(2'-hydroxyphenyl)-benzotriazole and 2-hydroxybenzophenone classes. For some of these molecules in various solvents at room temperature, (1) ground state absorption spectra, (2) emission spectra, (3) picosecond time-resolved transient absorption spectra, (4) ground state absorption recovery kinetics, (5) emission kinetics, and (6) transient absorption kinetics are reported. In the solid state at low temperatures, emission spectra and their temperature dependent kinetics up to approximately 200K as well as, in one case, the 12K excitation spectra of the observed dual emission are also reported.

Scott, G. W.↗
NASA NTRS1979

Experimental Studies of Radiative Base Heating of a Jovian Entry Model

To verify the validity of the theoretical predictions of Park on radiative base heating rates, two types of models are tested in the absence of ablation in shock tube flows which simulate the Jovian entry environments. The radiative fluxes are measured by pyroelectric radiometers imbedded in the models in a stream consisting of 10% hydrogen in a bath of either neon or argon. In addition, time-resolved photographs are taken to obtain information on the structure of base flows needed in Park's theory. The experimental data show that the radiative base heat fluxes are significant fractions of the radiative fluxes at the front stagnation point, the ratio being dependent upon Mach number and the configuration of the models. When the effects of the model geometry and Mach number are accounted for, the present experimental results agree with the theoretical predictions of Park.

Shirai, Hiroyuki↗
NASA NTRSDate not supplied

Fluid-Thermal-Structural Interactions Induced by an Asymmetric Shock-Wave/Boundary-Layer Interaction in a Mach-6 Compression Corner

An experimental study is conducted of the fluid-thermal-structural interaction of a clamped compliant panel exposed to a three dimensional shock-wave/boundary-layer interaction (SWBLI) induced by a Mach-6 compression ramp with a spanwise nonuniform incoming boundary layer. The nonuniform boundary layer was produced by placing trips on one side of the upstream flat plate, resulting in largely turbulent flow on the tripped side and transitional flow on the untripped side. Measurements of the flowfield confirmed that the tripped boundary layer contained elevated levels of unsteadiness, and the SWBLI was observed to vary from attached to fully separated as the ramp angle was increased from 10◦ to 38◦; the separation region on the tripped side of the panel was noticeably smaller, showing the elevated turbulence levels of the tripped-side flow to remain relatively localized rather than diffusing across the whole model. Full-field, time-resolved panel deformations were measured using high-speed photogrammetry and the vibrational response at each compression angle was characterized. Although the measured modes conformed largely to those from classical clamped-plate theory, some skewing of the mode shapes was observed. IR thermography highlighted regions of the compliant region where elevated temperatures were likely to promote thermal softening effects to the transient panel response. The quasi-static deformation and stress field was used to characterize the internal stress factor of each mode and showed a meaningful relationship between transient panel response and stress contained within each mode: modes with antinodes lying in high-stress areas of the plate tended to exhibit increases in vibrational frequency and decreases in vibrational power, whereas the opposite was true for modes with antinodes in low-stress areas.

Spectral Proper Orthogonal Decomposition↗
NASA NTRS1975

Study of the performance of antennas in magnetized plasmas

The antenna studies were performed in a large magnetized plasma source, a schematic drawing of which is shown. The plasma diagnostics consist of a 70 GHz (4 mm) microwave interferometer for density measurements and of various Langmuir probes for spatially resolved measurements of t sub e, n sub e and the shape of the electron distribution function. All diagnostic data are time-resolved by sample-and-hold techniques so as to yield information about the plasma build-up, the steady-state discharge, and the plasma decay in the afterglow. Whistler waves are excited and detected with various antennas which are inserted into the center of the plasma column through one axial and two orthogonal radial ports. The antennas were tested for their proper dipole response and then calibrated in a known field geometry in air. For the electric dipole, a parallel plate capacitor field was used; the magnetic loop is calibrated in the near-zone field of a long linear conductor of known radio frequency current distribution. Results are presented and discussed.

Stenzel, R. L.↗
NASA NTRS1981

Combined single-pulse holography and time-resolved laser schlieren for flow visualization

A pulsed ruby laser and continuous-wave argon ion laser were used in a combined setup at the Langley Expansion Tube for single pulse holography and time resolved laser schlieren with a common optical axis. The systems can be operated simultaneously for a single run. For a single frame, the pulsed holographic setup offers the options of shadowgraph, Schlieren, and interferometry from the reconstructed hologram as well as the advantage of post-run sensitivity adjustments. For flow establishment studies the time resolved laser Schlieren provides visualization of the flow field every 12.5 microns for up to 80 frames with an exposure time per frame of 5.4 microns.

Burner, A. W.↗