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Chemical Vapor Synthesis of Titanium Aluminides by Reaction of Aluminum Subchloride and Titanium Tetrachloride

A new process for developing titanium aluminides (TiAls) using chemical vapor synthesis was investigated in a laboratory experiment. Aluminum subchloride (AlCl) was used as the reducing agent in the reaction with TiCl{sub 4} and the source of aluminum for Ti-Al alloy. Two types of products, with large crystals and fine particles, were fabricated. The large crystals were determined to be TiAl, with small amounts of Ti and Ti{sub 3}Al phases. The composition of fine particles, on the other hand, varied in wide range.

36 MATERIALS SCIENCE↗

Design and Development of Low Weight, Titanium Aluminide Airfoils for High Performance Industrial Gas Turbines meeting 65% Combined Cycle Efficiency (Final Report)

This project funded under DOE-FOA-0001816 was performed with the intent of evaluating the potential of utilizing a low density, high specific strength Titanium Aluminide (TiAl) alloy in a large annulus last stage gas turbine blade with the intent of improving combined cycle gas turbine efficiency toward a goal of reaching 65% efficiency. The project consisted of identifying a potentially suitable TiAl material for manufacture of such a large blade by investment casting. This included estimation of design properties for the selected alloy, trade studies using a baseline design created for a nickel based alloy cast in the TiAl alloy to evaluate potential design changes required for the use of this material and optimization of a prototype design for the same baseline application using the selected TiAl alloy. Several rounds of optimization were completed with the intent of meeting the baseline design targets with a resulting design that showed at least equivalent performance in terms of creep, LCF/TMF, HCF and aerodynamic damping potential. While it was found that significant reductions in blade loading on the disk were possible, the design resulting from the optimization met most lifing targets at the baseline size, but showed a reduction in margins in some areas in comparison to the Ni-based baseline design. Additionally, it was found that the low strain tolerance of the TiAl alloy for temperatures at and below the operational temperature of the attachment resulted in marginal, although still acceptable, creep rupture performance of the design. Due to results indicating the reduced potential for increasing turbine annulus compared to expectations a Phase II award was not proposed and it is not recommended to pursue additional design optimization efforts until further material advances with TiAl materials are achieved.

03 NATURAL GAS↗

Microstructural Properties of Heat-Treated LENS In Situ Additively Manufactured Titanium Aluminide

This study reports on the microstructure, phase identification and hardness property of the LENS-manufactured binary Ti-Al alloy which was achieved via laser in situ alloying. The in situ alloying method, using laser beam as an energy source, indicated that it is possible to achieve a binary gamma phase microstructure from elemental powders of Ti and Al. The as-produced sample, however, was characterized of having different microstructure at the top, middle and bottom regions. The middle and top layers had similar hardness which was lower than that of the bottom region. The as heat-treated sample was characterized of lamellar grain microstructure at the top and just grains at the bottom and the middle. The observed grains were different in size, phase and hardness. This study indicated that in addition to the pores and the precipitation of α{sub 2} phase or aluminum segregation on the grain boundary veins intermetallics lead to severe cracking. Overall, the hardness values of the as-produced and heat-treated samples were similar, and due to extensive cracking, it was inferred that both samples will lack ductility.

36 MATERIALS SCIENCE↗

In-Situ Calibrated Digital Process Twin Models for Resource Efficient Manufacturing

The chief objective of manufacturing process improvement efforts is to significantly minimize process resources such as time, cost, waste, and consumed energy while improving product quality and process productivity. This paper presents a novel physics-informed optimization approach based on artificial intelligence (AI) to generate digital process twins (DPTs). The utility of the DPT approach is demonstrated in the case of finish machining of aerospace components made from gamma titanium aluminide alloy (γ-TiAl). This particular component has been plagued with persistent quality defects, including surface and sub-surface cracks, which adversely affect resource efficiency. Previous process improvement efforts have been restricted to anecdotal post-mortem investigation and empirical modeling, which fail to address the fundamental issue of how and when cracks occur during cutting. In this work, the integration of in-situ process characterization with modular physics-based models is presented, and machine learning algorithms are used to create a DPT capable of reducing environmental and energy impacts while significantly increasing yield and profitability. Based on the preliminary results presented here, we report an improvement in the overall embodied energy efficiency of over 84%, 93% in process queuing time, 2% in scrap cost, and 93% in queuing cost has been realized for γ-TiAl machining using our novel approach.

42 ENGINEERING↗

A Novel Approach for Real-Time Quality Monitoring in Machining of Aerospace Alloy through Acoustic Emission Signal Transformation for DNN

Gamma titanium aluminide (γ-TiAl) is considered a high-performance, low-density replacement for nickel-based superalloys in the aerospace industry due to its high specific strength, which is retained at temperatures above 800 °C. However, low damage tolerance, i.e., brittle material behavior with a propensity to rapid crack propagation, has limited the application of γ-TiAl. Any cracks introduced during manufacturing would dramatically lower the useful (fatigue) life of γ-TiAl components, making the workpiece surface’s quality from finish machining a critical component to product quality and performance. To address this issue and enable more widespread use of γ-TiAl, this research aims to develop a real-time non-destructive evaluation (NDE) quality monitoring technique based on acoustic emission (AE) signals, wavelet transform, and deep neural networks (DNN). Previous efforts have opted for traditional approaches to AE signal analysis, using statistical feature extraction and classification, which face challenges such as the extraction of good/relevant features and low classification accuracy. Hence, this work proposes a novel AI-enabled method that uses a convolutional neural network (CNN) to extract rich and relevant features from a two-dimensional image representation of 1D time-domain AE signals (known as scalograms), subsequently classifying the AE signature based on pedigreed experimental data and finally predicting the process-induced surface quality. The results of the present work show good classification accuracy of 80.83% using scalogram images, in-situ experimental data, and a VGG-19 pre-trained neural network, establishing the significant potential for real-time quality monitoring in manufacturing processes.

36 MATERIALS SCIENCE↗

Development and Mechanical Properties of In Situ Al{sub 3}Ti-Reinforced Nanostructured AA6061 via Mechanical Alloying

Mechanical alloying (MA) was used to disperse 10 wt.% titanium powder in AA6061 powder. The resultant powder was degassed, and differential scanning calorimetry was performed to determine the temperature for formation of titanium aluminide (Al{sub 3}Ti). The MA powder was characterized by field emission scanning electron microscopy, x-ray diffraction (XRD) and transmission electron microscopy (TEM). Subsequently, the MA powder was consolidated by spark plasma sintering (SPS) at 500 °C under a pressure of 50 MPa. XRD and x-ray energy-dispersive spectroscopy of spark plasma sintered compact revealed in situ formation of Al{sub 3}Ti. TEM micrographs of spark plasma sintered sample exhibited Al nanograins (average size 50 nm) in the AA6061 matrix along with the dispersed Al{sub 3}Ti (average size 200 nm). Hardness, yield strength and compressive strength of the SPSed samples were also evaluated and compared with AA6061.

36 MATERIALS SCIENCE↗

A comprehensive study on the fabrication and characterization of Ti–48Al–2Cr–2Nb preforms manufactured using electron beam melting

This feasibility study examines the additive manufacturing of Ti–48Al–2Cr–2Nb preforms in a quest to make more complex engine components from this promising but hard to machine, brittle material. The preforms are built using the electron beam melting technique; hot isostatic pressing (HIP) was performed as the only post-process. Microstructural characterizations were carried with scanning electron microscopy techniques, X-ray diffraction and X-ray computed tomography while mechanical properties were obtained via tensile testing. We exploited computational thermodynamic modeling (widely known as CALPHAD) approach to investigate the phase stability pertinent to Nb and Cr modified TiAl. Defect-free structures were obtained in the HIPed condition with mechanical behavior comparable to/better than traditionally manufactured counterparts. Equiaxed duplex microstructures were achieved in the as-built condition that were sustained post-HIP. The effect of the build conditions and phase transformation kinetics on the observed microstructures is discussed. Furthermore, the microstructure-mechanical behavior relationship is also discussed.

36 MATERIALS SCIENCE↗

Resolving pseudosymmetry in γ-TiAl using cross-correlation electron backscatter diffraction with dynamically simulated reference patterns

Pseudosymmetry is a phenomenon that occurs when grains with different lattice parameters produce nearly identical diffraction patterns such that conventional electron backscatter diffraction (EBSD) techniques are unable to unambiguously differentiate the lattice orientations. This commonly occurs in materials with near-unity tetragonality, such as γ-TiAl. The current study uses cross-correlation EBSD to resolve pseudosymmetry in γ-TiAl. Three dynamically simulated reference patterns are generated for each point in the scan, one for each of the three potential pseudosymmetric orientations, which are subsequently correlated with the original pattern using six different methods in order to identify the correct orientation. The methods are first applied to a scan of dynamically simulated patterns, which is used to evaluate the sensitivity of the method to pattern resolution, pattern noise and pattern center error. It was determined that all six methods were 100% successful up to about 13 µm of pattern center error and pattern resolutions of about 80 × 80 pixels, and hence the methods were applied to an experimental sample of lamellar γ-TiAl. A hybrid combination of two of the methods was shown to successfully select the correct pseudosymmetry for about 96% of the points in the scan, improving upon the 70% accuracy of the Hough-based methods for the current study and 90% accuracy for previous studies resolving pseudosymmetry in lamellar γ-TiAl.

36 MATERIALS SCIENCE↗

Microstructure evolution during near-net-shape fabrication of Ni x Al y -TiC cermets through binder jet additive manufacturing and pressureless melt infiltration

Titanium carbide-nickel aluminide (TiC-Ni x Al y ) intermetallic matrix composite materials were fabricated with additive manufacturing and pressureless melt infiltration for applications intended for high-wear and corrosive environments while maintaining low density. In this work, two compositions of nickel aluminide are infiltrated into porous, printed TiC preforms. Net shaping of a nickel-rich infiltrant is less compared to the net shaping of the aluminum-rich infiltrant due to dissolution of TiC in the molten infiltrant. The microstructures and porosity of the two infiltrants with TiC are examined after processing. The explanation of shape retention from infiltration is explained, and the excellent shape retention in an Al-rich infiltrant system is thought to be from peritectic behavior and a metered infiltration of different phases during cooling and solidification without significant dissolution. The metered infiltration contributed to some porosity, microcracking, and segregated Ni x Al y phases. We show that TiC can be shaped and infiltrated with intermetallics to provide a method of making composites with limited shrinkage and controlled geometry.

36 MATERIALS SCIENCE↗