The total scattering cross sections for H2 + H2, D2 + D2, and HD + HD for relative collision energies below 10 meV
Relative total scattering cross sections for normal H2 + normal H2, para-H2 + para-H2, normal D2 + normal D2, ortho-D2 + ortho-D2, and HD + HD were measured at energy below 10 meV by colliding particles from two inclined nozzle beams. Cross sections for the H2 + H2 pairs were measured over a relative velocity range of 200-1450 m/s; the normal H2 + normal H2 results suggest a l = 3 orbiting resonance near 375 m/s while the para-H2 + para-H2 results have a l = 4 orbiting resonance near 585 m/s. This latter resonance has a peak energy of 1.79 meV and a FWHM of 1.05 meV. The D2 + D2 cross sections were measured over the velocity range of 190 to 1000 m/s and a minimum between the l = 4 and l = 5 orbiting resonances was observed. Some preliminary measurements on HD + HD over the range of 250-1250 m/s indicate a possible l = 4 orbiting resonance near 300 m/s. The experimental work compares favorably to cross sections calculated from a theoretical potential.