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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Microgravity Transport Phenomena Experiment (MTPE) Overview

The Microgravity Transport Phenomena Experiment (MTPE) is a fluids experiment supported by the Fundamentals in Biotechnology program in association with the Human Exploration and Development of Space (BEDS) initiative. The MTP Experiment will investigate fluid transport phenomena both in ground based experiments and in the microgravity environment. Many fluid transport processes are affected by gravity. Osmotic flux kinetics in planar membrane systems have been shown to be influenced by gravimetric orientation, either through convective mixing caused by unstably stratified fluid layers, or through a stable fluid boundary layer structure that forms in association with the membrane. Coupled transport phenomena also show gravity related effects. Coefficients associated with coupled transport processes are defined in terms of a steady state condition. Buoyancy (gravity) driven convection interferes with the attainment of steady state, and the measurement of coupled processes. The MTP Experiment measures the kinetics of molecular migration that occurs in fluids, in response to the application of various driving potentials. Three separate driving potentials may be applied to the MTP Experiment fluids, either singly or in combination. The driving potentials include chemical potential, thermal potential, and electrical potential. Two separate fluid arrangements are used to study membrane mediated and bulk fluid transport phenomena. Transport processes of interest in membrane mediated systems include diffusion, osmosis, and streaming potential. Bulk fluid processes of interest include coupled phenomena such as the Soret Effect, Dufour Effect, Donnan Effect, and thermal diffusion potential. MTP Experiments are performed in the Microgravity Transport Apparatus (MTA), an instrument that has been developed specifically for precision measurement of transport processes. Experiment fluids are contained within the MTA fluid cells, designed to create a one dimensional flow geometry of constant cross sectional area, and to facilitate fluid filling and draining operations in microgravity. The fluid cells may be used singly for bulk solutions, or in a Stokes diaphragm configuration to investigate membrane mediated phenomena. Thermal and electrical driving potentials are applied to the experiment fluids through boundary plates located at the ends of the fluid cells. In the ground based instrument, two constant temperature baths circulate through reservoirs adjacent to the boundary plates, and establish the thermal environment within the fluid cells. The boundary plates also serve as electrodes for measurement and application of electrical potentials. The Fluid Manipulation System associated with the MTA is a computer controlled system that enables storage and transfer of experiment fluids during on orbit operations. The system is used to automatically initiate experiments and manipulate fluids by orchestrating pump and valve operations through scripted sequences. Unique technologies are incorporated in the MTA for measurement of fluid properties. Volumetric Flow Sensors have been developed for precision measurement of total fluid volume contained within the fluid cells over time. This data is most useful for measuring the kinetics of osmosis, where fluid is transported from one fluid cell to another through a semipermeable membrane. The MicroSensor Array has been designed to perform in situ measurement of several important fluid parameters, providing simultaneous measurement of solution composition at multiple locations within the experiment fluids. Micromachined sensors and interface electronics have been developed to measure temperature, electrical conductivity, pH, cation activity, and anion activity. The Profile Refractometer uses a laser optical system to directly image the fluid Index of Refraction profile that exists along the MTA fluid cell axis. A video system acquires images of the RI profile over time, and records the transport kinetics that occur upon application of chemical, thermal, or electrical driving potentials. Image processing algorithms have been developed to analyze the refractometer images on a pixel by pixel basis, calibrating and scaling the measured Index of Refraction profile to correlated solution properties of interest such as density, concentration, and temperature. Additional software has been developed to compile the processed images into a three dimensional matrix that contains fluid composition data as a function of experiment time and position in the fluid cell. These data are combined with data from the other sensor systems, and analyzed in the context of transport coefficients associated with the various transport phenomena. Analysis protocols have been developed to measure the transient kinetics, and steady state distribution of fluid components that occur in response to the applied driving potentials. The results are expressed in terms of effective transport coefficients. Experiments have been performed using a variety of solutes, and results generated are that are in agreement with published transport coefficient values.

Mason, Larry W.↗
NASA NTRS1967

Boundary-layer combustion in propulsion.

Propulsion-oriented subsonic boundary layer combustion research, discussing turbulent and diffusion-limited conditions, radiant heat transfer, chemical kinetics and transient phenomena

RADIATIVE HEAT TRANSFER↗
NASA NTRS1984

Transient Response Dynamic Module Modifications to Include Static and Kinetic Friction Effects

A methodology that supports forced transient response dynamic solutions when both static and kinetic friction effects are included in a structural system model is described. Modifications that support this type of nonlinear transient response solution are summarized for the transient response dynamics (TRD) NASTRAN module. An overview of specific modifications for the NASTRAN processing subroutines, INITL, TRD1C, and TRD1D, are described with further details regarding inspection of nonlinear input definitions to define the type of nonlinear solution required, along with additional initialization requirements and specific calculation subroutines to successfully solve the transient response problem. The extension of the basic NASTRAN nonlinear methodology is presented through several stages of development to the point where constraint equations and residual flexibility effects are introduced into the finite difference Newmark-Beta recurrsion formulas. Particular emphasis is placed on cost effective solutions for large finite element models such as the Space Shuttle with friction degrees of freedom between the orbiter and payloads mounted in the cargo bay. An alteration to the dynamic finite difference equations of motion is discussed, which allows one to include friction effects at reasonable cost for large structural systems such as the Space Shuttle. Data are presented to indicate the possible impact of transient friction loads to the payload designer for the Space Shuttle. Transient response solution data are also included, which compare solutions without friction forces and those with friction forces for payloads mounted in the Space Shuttle cargo bay. These data indicate that payload components can be sensitive to friction induced loads.

Misel, J. E.↗
NASA NTRS1985

Transient Eddies in the UCLA GCM

The simulation of transient eddies in the nine level UCLA general circulation model (GCM) was examined and compared to observations, with emphasis on the Northern Hemisphere winter. Qualitatively, the UCLA GCM reproduces many features of the observed circulation and the relationship between the time mean flow and transient eddies; however, the magnitudes of transient eddies in the UCLA GCM, particularly at frequencies lower than those associated with baroclinic instability, appear to be much less than those observed. The pattern of low level transient eddy heat fluxes were similar to observations and acted to dissipate the low level seasonal mean temperature field. The simulated transient eddy kinetic energy at 300 mb is given for eddies of all time scales shorter than a season.

White, G. H.↗
NASA NTRS2022

The Future Intensification of the North Atlantic Winter Storm Track: The Key Role of Dynamic Ocean Coupling

Climate models project an intensification of the wintertime North Atlantic storm track, over its downstream region, by the end of this century. Previous studies have suggested that ocean-atmosphere coupling plays a key role in this intensification, but the precise role of the different components of the coupling has not been explored and quantified. In this paper, using a hierarchy of ocean coupling experiments, we isolate and quantify the respective roles of thermodynamic (changes in surface heat fluxes) and dynamic (changes in ocean heat flux convergence) ocean coupling in the projected intensification of North Atlantic transient eddy kinetic energy (TEKE). We show that dynamic coupling accounts for nearly all of the future TEKE strengthening as it overcomes the much smaller effect of surface heat flux changes to weaken the TEKE. We further show that by reducing the Arctic amplification in the North Atlantic, ocean heat flux convergence increases the meridional temperature gradient aloft, causing a larger eddy growth rate, and resulting in the strengthening of North Atlantic TEKE. Our results stress the importance of better monitoring and investigating the changes in ocean heat transport, for improving climate change adaptation strategies.

North Atlantic winter storms↗
NASA NTRS1984

CREKID: A computer code for transient, gas-phase combustion of kinetics

A new algorithm was developed for fast, automatic integration of chemical kinetic rate equations describing homogeneous, gas-phase combustion at constant pressure. Particular attention is paid to the distinguishing physical and computational characteristics of the induction, heat-release and equilibration regimes. The two-part predictor-corrector algorithm, based on an exponentially-fitted trapezoidal rule, includes filtering of ill-posed initial conditions, automatic selection of Newton-Jacobi or Newton iteration for convergence to achieve maximum computational efficiency while observing a prescribed error tolerance. The new algorithm was found to compare favorably with LSODE on two representative test problems drawn from combustion kinetics.

Pratt, D. T.↗
NASA NTRS1972

A Numerical Analysis of the Transient Response of an Ablation System Including Effects of Thermal Nonequilibrium, Mass Transfer and Chemical Kinetics

The differential equations governing the transient response of a one-dimensional ablative thermal protection system undergoing stagnation ablation are derived. These equations are for thermal nonequilibrium effects between the pyrolysis gases and the char layer and kinetically controlled chemical reactions and mass transfer between the pyrolysis gases and the char layer. The boundary conditions are written for the particular case of stagnation heating with surface removal by oxidation or sublimation and pyrolysis of the uncharred layer occurring in a plane. The governing equations and boundary conditions are solved numerically using the modified implicit method (Crank-Nicolson method). Numerical results are compared with exact solutions for a number of simplified cases. The comparison is favorable in each instance.

Clark, R. K.↗
NASA NTRS1982

Picosecond flash spectroscopic studies on ultraviolet stabilizers and stabilized polymers

Spectroscopic and excited state decay kinetics are reported for monomeric and polymeric forms of ultraviolet stabilizers in the 2-(2'-hydroxyphenyl)-benzotriazole and 2-hydroxybenzophenone classes. For some of these molecules in various solvents at room temperature, (1) ground state absorption spectra, (2) emission spectra, (3) picosecond time-resolved transient absorption spectra, (4) ground state absorption recovery kinetics, (5) emission kinetics, and (6) transient absorption kinetics are reported. In the solid state at low temperatures, emission spectra and their temperature dependent kinetics up to approximately 200K as well as, in one case, the 12K excitation spectra of the observed dual emission are also reported.

Scott, G. W.↗
NASA NTRS1983

Conductive damping of coronal motions

Time-dependent motions in the solar corona are subject to modification through conductive transport of thermal energy away from compression regions and into rarefaction regions. The evolution depends on how the energy is introduced - by an essentially thermal perturbation or by a density perturbation. The net effect of thermal conduction is to convert local kinetic energy in the transient into widely distributed thermal energy, which then may in turn be partially converted into kinetic energy of the bulk flow. Local motion in the transient is thereby damped. These effects are modeled here using a numerical solution of the time-dependent solar wind equations for single-fluid thermally conductive flow. The simulations of transient phenomena are made for ordinary collisional thermal conduction and compared with similar simulations done using polytropic flow. Between one and five solar radii, the gross character in the two cases is very similar. However, there are effects with thermal conduction that cannot be modeled with polytropic flow, illustrated here by temperature and velocity forerunners and a delayed and large-amplitude trailing velocity low. If thermal conduction is artificially inhibited by simple reduction of the thermal conduction coefficient, relative velocity amplitudes remain larger in approximate proportion to the amount the coefficient is reduced.

Suess, S. T.↗
NASA NTRS1994

What can we learn from relaxation measurements of a laser-perturbed atmosphere? A modeling study

The chemical kinetic aspects of a transient increase in OH and HO2 by several orders of magnitude are explored in three model tropospheres. This chemical kinetic modeling effort was undertaken to support the operation of a pump-and-probe LIDAR instrument. A powerful excimer laser pulse perturbs the troposphere after which its relaxation back to steady state is examined by remote sensing, for example by DIAL or LIF. Instead of probing ambient levels of key free radicals, a study of the relaxation kinetics in real time enables chemical mechanistic studies in situ.

Clericetti, Agostino↗
NASA NTRS1987

A spectral view of nonlinear fluxes and stationary-transient interaction in the atmosphere

Nonlinear spectral transfers of kinetic energy and enstrophy, and stationary-transient interaction, are studied using global FGGE data for January 1979. The spectral transfers are found to be dominated by two dynamically distinct components, one due to nonlinear self-interactions within the transient flow and the other arising from coupled interactions between the stationary and transient parts of the flow. The former seems to be attributable to two-dimensional homogeneous turbulence, while the second cannot be understood within that theory. It is argued that the mixed stationary-transient interactions can be understood physically as a process of shear-induced spectral transfer of transient enstrophy along lines of constant zonal wavenumber. The transients act mainly to strengthen the stationary flow, and this 'forcing' operates on a timescale comparable to presumed viscous timescales.

Shepherd, Theodore G.↗
NASA NTRS1986

Transient gain-versus-absorption laser probing of spin-orbit states, kinetics and dynamics

The spin-orbit populations of excited (2P1/2) and ground (2P3/2) state Br atoms at 2714 nm and I atoms at 1315 nm are examined using a tunable F-center laser and a diode laser. The transient laser gain-versus-absorption measurements are utilized to estimate quantum yields of the spin-orbit states in the photodissociation of Br- and I-containing compounds; the continuum yields for Br2 are investigated in terms of temperature. The collisional release, Doppler velocity effects, and differing reactivity of the spin-orbit excited and ground state atoms are studied. It is noted that the transient gain versus absorption technique is applicable to the analysis of kinetic phenomena due to its high sensitivity and excellent time resolution.

Smedley, John E.↗
NASA NTRS2010

Oxidation of SiC Fiber-Reinforced SiC Matrix Composites with a BN Interphase

SiC-fiber reinforced SiC matrix composites with a BN interphase were oxidized in reduced oxygen partial pressures of oxygen to simulate the environment for hypersonic vehicle leading edge applications. The constituent fibers as well as composite coupons were oxidized in oxygen partial pressures ranging from 1000 ppm O2 to 5% O2 balance argon. Exposure temperatures ranged from 816 C to 1353 C (1500 F to 2450 F). The oxidation kinetics of the coated fibers were monitored by thermogravimetric analysis (TGA). An initial rapid transient weight gain was observed followed by parabolic kinetics. Possible mechanisms for the transient oxidation are discussed. One edge of the composite coupon seal coat was ground off to simulate damage to the composite which allowed oxygen ingress to the interior of the composite. Oxidation kinetics of the coupons were characterized by scanning electron microscopy since the weight changes were minimal. It was found that sealing of the coupon edge by silica formation occurred. Differences in the amount and morphology of the sealing silica as a function of time, temperature and oxygen partial pressure are discussed. Implications for use of these materials for hypersonic vehicle leading edge materials are summarized.

Opila, Elizabeth↗
NASA NTRS1988

Laminar diffusion flames under micro-gravity conditions

Laminar methane and propane gas-jet diffusion flames have been theoretically and experimentally studied at NASA-Lewis under microgravity conditions. It is noted that laminar diffusion flames are strongly affected by the combined effects of kinetics, radiation, and such transient phenomena as flame ignition, stabilization, and extinction. Observations on the distinctive nature of the flame color and luminosity parameters in microgravity are presented, and flame behavior under transient, high-deceleration rates is discussed. Test hardware and instrumentation design are described.

Edelman, Raymond B.↗
NASA NTRS1988

Nonlinear instability of a forced baroclinic Rossby wave

The nonlinear instability of forced baroclinic Rossby waves to finite-amplitude perturbations was investigated using a simple two-layer quasi-geostrophic weakly nonlinear model and a low-order spectral model, developed for this purpose. The results were applied to a study of the interaction of planetary-scale stationary eddies with synoptic-scale transient eddies. A comparison of the energetics of the weakly nonlinear solution with that seen in observational analysis and in GCM experiments indicate three basic properties of the interaction between the two types of eddies: (1) eddy available potential energy is transferred from the planetary-scale stationary eddies to the synoptic-scale transient eddies, (2) eddy kinetic energy is transferred in the opposite direction, and (3) the eddy available potential energy transfer dominates the transfer of eddy kinetic energy. It is concluded that the simple weakly nonlinear model used in these studies does indeed capture much of the fundamental behavior of wave-wave interactions seen in the atmosphere.

Feldstein, Steven B.↗