Search NASA⌕ Search

SEARCH · Search NASA

Results for “transport limitations”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records

Improved opportunities for the investigation of crystal growth phenomena on Space Station Freedom

Space Station Freedom is intended to provide long-duration access to a microgravity environment crewed by a team of well-trained astronaut scientists. To illustrate the benefits afforded by such a facility, a general review of crystal growth (CG) from liquids is given, concentrating on the basic elements of the underlying physics and chemistry. Two examples of CG techniques illustrating the effect of mass transport limitations on growth rate and thus experiment duration are presented. Thermodynamic and thermophysical properties and suggested thermal boundary and growth conditions are used to estimate the experiment duration of two mass-transport-limited CG scenarios. A hypothetical study that probes a large processing space via a number of short-duration experiments is described.

Wargo, M. J.↗

Recent advances in solid polymer electrolyte fuel cell technology with low platinum loading electrodes

High power density fuel cell systems for defense and civilian applications are being developed. Taking into consideration the main causes for efficiency losses (activation, mass transport and ohmic overpotentials) the only fuel cell systems capable of achieving high power densities are the ones with alkaline and solid polymer electrolyte. High power densities (0.8 W/sq cm at 0.8 V and 1 A/sq cm with H2 and O2 as reactants), were already used in NASA's Apollo and Space Shuttle flights as auxiliary power sources. Even higher power densities (4 W/sq cm - i.e., 8 A sq cm at 0.5 V) were reported by the USAF/International Fuel Cells in advanced versions of the alkaline system. High power densities (approximately 1 watt/sq cm) in solid polymer electrolyte fuel cells with ten times lower platinum loading in the electrodes (i.e., 0.4 mg/sq cm) were attained. It is now possible to reach a cell potential of 0.620 V at a current density of 2 A/sq cm and at a temperature of 95 C and pressure of 4/5 atm with H2/O2 as reactants. The slope of the linear region of the potential-current density plot for this case is 0.15 ohm-sq cm. With H2/air as reactants and under the same operating conditions, mass transport limitations are encountered at current densities above 1.4 A/sq cm. Thus, the cell potential at 1 A/sq cm with H2/air as reactants is less than that with H2/O2 as reactants by 40 mV, which is the expected value based on electrode kinetics of the oxygen reduction reaction, and at 2 A/sq cm with H2/air as reactant is less than the corresponding value with H2/O2 as reactants by 250 mV, which is due to the considerably greater mass transport limitations in the former case.

Srinivasan, Supramaniam↗

Modeling the Hydrodynamics, Sediment Transport, and Valley Incision of Outlet-forming Floods from Martian Crater Lakes

Open-basin lakes that have outlets, formed where the stored water breached the basin-confining topography (e.g., crater rims), have been recognized on Mars for decades. However, the mechanics involved in formation of these outlets has not been studied in detail. Here, we study this outlet formation process through a series of numerical experiments accomplished by adding erosion and sediment transport routines to an existing hydrodynamic simulation, ANUGA. These experiments are consistent with outlets being carved in single flood events, at least if sediment was available throughout outlet formation as in a transport-limited regime. Peak discharges from these open-basin lakes, including from Jezero crater, were 10^4–10^6 m^3/s, and the outlet-forming floods lasted for days to weeks, depending on lake size. Moreover, we find that sediment transport by suspension was likely important during these floods – outlets could not have reached their observed sizes if flow was limited to bedload transport alone. This in turn may explain why small open-basin lakes are less commonly recognized on Mars, as small lakes had less inherent capacity to transport sediment in suspension and thus incise confining topography catastrophically. Geometry, topographic setting, and earlier fluvial valley development may have played a significant role in influencing the magnitude of outlet-forming floods and resulting outlet canyon incision.

Mars↗

Numerical modeling of physical vapor transport under microgravity conditions: Effect of thermal creep and stress

One of the most promising applications of microgravity (micro-g) environments is the manufacture of exotic and high-quality crystals in closed cylindrical ampoules using physical vapor transport (PVT) processes. The quality enhancements are believed to be due to the absence of buoyant convection in the weightless environment - resulting in diffusion-limited transport of the vapor. In a typical experiment, solid-phase sample material is initially contained at one end of the ampoule. The sample is made to sublime into the vapor phase and deposit onto the opposite end by maintaining the source at an elevated temperature with respect to the deposit. Identification of the physical factors governing both the rates and uniformity of crystal growth, and the optimization of the micro-g technology, will require an accurate modeling of the vapor transport within the ampoule. Previous micro-g modeling efforts have approached the problem from a 'classical' convective/diffusion formulation, in which convection is driven by the action of buoyancy on thermal and solutal density differences. The general conclusion of these works have been that in low gravity environments the effect of buoyancy on vapor transport is negligible, and vapor transport occurs in a diffusion-limited mode. However, it has been recently recognized than in the non-isothermal (and often low total pressure) conditions encountered in ampoules, the commonly-assumed no-slip boundary condition to the differential equations governing fluid motion can be grossly unrepresentative of the actual situation. Specifically, the temperature gradients can give rise to thermal creep flows at the ampoule side walls. In addition, temperature gradients in the vapor itself can, through the action of thermal stress, lead to bulk fluid convection.

Mackowski, Daniel W.↗

Testing of a high capacity research heat pipe

Tests were performed on a high-capacity channel-wick heat pipe to assess the transport limitations of v-grooves and the effects of boiling. The results showed that transport can vary significantly (less than 50 W) under similar conditions and the continuous boiling was observed at power levels as low as 40 W. In addition, some evidence was found to support the predictions using a groove transport model which shows that transport increases with lower groove densities and longer evaporators. However, due to transport variations, these results were not consistent throughout the program. When a glass fiber wick was installed over the grooves, a relatively low transport level was achieved (80 to 140 W). Based on these results and the identification of some potential causes for them, several design suggestions were recommended for reducing the possibility of boiling and improving groove transport.

Source record↗

Experimental investigation of freezing blowby in a copper/water heat pipe

An experimental investigation designed to evaluate and better define the overall characteristics of freezing blowby in a copper/water heat pipe was conducted. The results from various rates of restart heat addition and channel blockage, indicate that upon breakthrough the depressurization of the evaporator may result in an effective heat transport capacity far in excess of the steady-state transport limit. The resulting transient conditions imposed on the heat pipe by the effective increased heat transport capacity can cause a loss of liquid in the evaporator and potential dryout. Evidence is presented which indicates that in order to prevent either temporary or permanent dryout, sufficient liquid inventory must be present in the evaporator wicking structure to accommodate the increased transient thermal load and allow sufficient time for the capillary wicking structure to reprime.

Ochterbeck, J. M.↗

Kinetic limitations on the diffusional control theory of the ablation rate of carbon.

It is shown that the theoretical maximum oxidation rate is limited in many cases even at temperatures much higher than 1650 deg K, not by oxygen transport, but by the kinetics of the carbon-oxygen reaction itself. Mass-loss rates have been calculated at air pressures of 0.01 atm, 1 atm, and 100 atm. It is found that at high temperatures the rate of the oxidation reaction is much slower than has generally been assumed on the basis of a simple linear extrapolation of Scala's 'fast' and 'slow' rate expressions. Accordingly it cannot be assumed that a transport limitation inevitably must be reached at high temperatures.

Maahs, H. G.↗

Functional and performance tests of two capillary pumped loop engineering models

This paper presents the results of the functional and performance tests for two capillary pumped loop (CPL) engineering models. Both CPL systems are aluminum/ammonia transport systems which contain eight parallel evaporators and six parallel condensers in a single loop. Tests conducted include the transport limit, heat load shearing between evaporators, liquid inventory/temperature control by the reservoir, pressure priming under heat load, diode function of condensers, and isolation of a single deprimed evaporator. Consistent performance results were obtained for both systems. Transport capabilities of up to 70 kw-m with individual evaporators managing up to 1.7 kw, with a corresponding input heat flux of 15w/sq cm, were demonstrated. These tests demonstrated the ability of a CPL system to operate over a wide range of conditions and thus established the viability of these systems for high power thermal management of large spacecraft, such as the NASA Space Station.

Ku, J.↗

Growth of zinc selenide single crystals by physical vapor transport in microgravity

The goals of this research were the optimization of growth parameters for large (20 mm diameter and length) zinc selenide single crystals with low structural defect density, and the development of a 3-D numerical model for the transport rates to be expected in physical vapor transport under a given set of thermal and geometrical boundary conditions, in order to provide guidance for an advantageous conduct of the growth experiments. In the crystal growth studies, it was decided to exclusively apply the Effusive Ampoule PVT technique (EAPVT) to the growth of ZnSe. In this technique, the accumulation of transport-limiting gaseous components at the growing crystal is suppressed by continuous effusion to vacuum of part of the vapor contents. This is achieved through calibrated leaks in one of the ground joints of the ampoule. Regarding the PVT transport rates, a 3-D spectral code was modified. After introduction of the proper boundary conditions and subroutines for the composition-dependent transport properties, the code reproduced the experimentally determined transport rates for the two cases with strongest convective flux contributions to within the experimental and numerical error.

Rosenberger, Franz↗

Denouement of Jovian radiation belt theory

Predictions of theoretical models of Jupiter's radiation belts are compared with Pioneer 10 measurements. A brief quasi-historical review is given of the evolution of the basic theoretical ideas with emphasis on the three physical processes that were believed to be dominant in the Jovian electron fluxes: radial-diffusion transport, limitation of particle fluxes by plasma wave turbulence, and particle losses from collisional sweep-up by the Galilean satellites. Pioneer 10 data on the inner zone are discussed which yield the clearest evidence for radial diffusion being the dominant transport process, the synchrotron flux density is estimated using Pioneer 10 measurements, and the observed outer-zone electron fluxes are favorably compared with the qualitative and quantitative predictions of the whistler-mode stable-trapping model. The outer-zone electron-precipitation flux is estimated, and it is suggested that precipitation could affect the structure of the Jovian ionosphere. Satellite sweep-up is shown to be less severe than had been anticipated.

Coroniti, F. V.↗

Escarpment evolution on high-elevation rifted margins: Insights derived from a surface processes model that combines diffusion, advection and reaction

Experiments with a surface processes model of large-scale (1-1000 km) long-term (1-100 m.y.) erosional denudation are used to establish the controls on the evolution of a model escarpment that is related to the rifting of a continent. The mdoel describes changes in topographic form as a result of sumultaneous short- and long-range mass transport representing hillslope (diffusive) processes and fluvial transport (advection), repsectively. Fluvial entrainment is modeled as a first-order kinetic reaction which reflects the erodibility of the substrate, and therefore the fluvial system is not necessarily carrying at capacity. One dimensional and planform models demonstrate that the principal controls on the evolution of an initially steep model escarpment are (1) antecedent topography/drainage; (2) the timesale (or equivalently a length scale) in the fluvial entrainment reaction; (3) the flexural response of the lithosphere to denudation; and (4) the relative efficiencies of the short- and long-range transport processes. When rainfall and substrate lithology are uniform, a significant amount of discharge draining over the escarpment top causes it to degrade. Only when the top of the model escarpment coincides with a drainage divide can escarpment retreat occur for these conditions. An additional requirement for retreat of a model escarpment without decline is a long reaction time scale for fluvial entrainment. This corresponds to a substrate that is hard to detach by flucial erosion, and therefore to fluvial erosion that is not transport limited. Coninuous backtilting of an escarpment due ot flexural isostatic uplift in response to denudational unloading helps maintain the scarp top as a divide. It is essntial if the escarpment gradient is to be preserved during retreat in a uniform lithology. Low flexural rigidieties propote steep and slowly retreating escarpments. For given rainfall and substrate conditions, the morphology of a retraeating model escarpment is determined by the ratio of hte short-range diffusive and long range advective transport efficiencies. A low ration (which is interpreted to correspond to a more humid, temperate climate) produces a convex upper slope, and concave lower slope morphology and only major escarpments are predicted to preserve a high scarp gradient. Lithological contrasts in hte model produce more complex morphologies and predict the formation of scarps crowned by an erosionaly resistant caprock. However, resistant caprocks are not an essential requirement for model scarps to retreat. We conclude that the inferred controls and model behavior are both consistent with the present-day morphology of rifted continental margins and with modern conceptual models of landscape evolution.

Kooi, Henk↗

Effects of vibration (G-jitters) on convection in micro-gravity

To obtain high quality crystals, it is desirable to maintain a diffusion-limited transport process in a planar solidification surface between the solid and the melt during the crystal growth process. Due to the presence of buoyancy-driven convection, however, this situation is difficult to maintain on Earth. The microgravity environment of an orbiting space laboratory presents an alternative worth pursuing. With reduced gravity, convections very much suppressed in a space laboratory, making the environment more conducive for growing crystals with better quality. However, a space laboratory is not immune from any undesirable disturbances. Nonuniform and transient accelerations such as vibrations, g-jitters, and impulsive accelerations exist as a result of crew activities, space maneuvering, and the operations of on-board equipment. Measurements conducted on-board a U.S. Spacelab mission showed the existence of vibrations in the frequency range of 1 to 100 Hz. It was reported that a dominant mode of 17 Hz and harmonics of 54 Hz were observed and these were attributed to antenna operations. The vibration is not limited to any single plane but exists in all directions. Some data from the Russian MIR space station indicates the existence of vibration also at this frequency range.

Wang, Francis C.↗

Nonlocal thermal transport in solar flares

A flaring solar atmosphere is modeled assuming classical thermal transport, locally limited thermal transport, and nonlocal thermal transport. The classical, local, and nonlocal expressions for the heat flux yield significantly different temperature, density, and velocity profiles throughout the rise phase of the flare. Evaporation of chromospheric material begins earlier in the nonlocal case than in the classical or local calculations, but reaches much lower upward velocities. Much higher coronal temperatures are achieved in the nonlocal calculations owing to the combined effects of delocalization and flux limiting. The peak velocity and momentum are roughly the same in all three cases. A more impulsive energy release influences the evolution of the nonlocal model more than the classical and locally limited cases.

Karpen, Judith T.↗

Systems evaluation of thermal bus concepts

Thermal bus concepts, to provide a centralized thermal utility for large, multihundred kilowatt space platforms, were studied and the results are summarized. Concepts were generated, defined, and screened for inclusion in system level thermal bus trades. Parametric trade studies were conducted in order to define the operational envelope, performance, and physical characteristics of each. Two concepts were selected as offering the most promise for thermal bus development. All of four concepts involved two phase flow in order to meet the required isothermal nature of the thermal bus. Two of the concepts employ a mechanical means to circulate the working fluid, a liquid pump in one case and a vapor compressor in another. Another concept utilizes direct osmosis as the driving force of the thermal bus. The fourth concept was a high capacity monogroove heat pipe. After preliminary sizing and screening, three of these concepts were selected to carry into the trade studies. The monogroove heat pipe concept was deemed unsuitable for further consideration because of its heat transport limitations. One additional concept utilizing capillary forces to drive the working fluid was added. Parametric system level trade studies were performed. Sizing and weight calculations were performed for thermal bus sizes ranging from 5 to 350 kW and operating temperatures in the range of 4 to 120 C. System level considerations such as heat rejection and electrical power penalties and interface temperature losses were included in the weight calculations.

Stalmach, D. D.↗

User's Manual for Thermal Analysis Program of Axially Grooved Heat Pipe (HTGAP)

A computer program that numerically predicts the steady state temperature distribution inside an axially grooved heat pipe wall for a given groove geometry and working fluid under various heat input and output modes is described. The program computes both evaporator and condenser film coefficients. The program is able to handle both axisymmetric and nonaxisymmetric heat transfer cases. Non-axisymmetric heat transfer results either from non-uniform input at the evaporator or non-uniform heat removal from the condenser, or from both. The presence of a liquid pool in the condenser region under one-g condition also causes non-axisymmetric heat transfer, and its effect on the pipe wall temperature distribution is included in the present program. The hydrodynamic aspect of an axially grooved heat pipe is studied in the Groove Analysis Program (GAP). The present thermal analysis program assumes that the GAP program (or other similar programs) is run first so that the heat transport limit and optimum fluid charge of the heat pipe are known a priori.

Kamotani, Y.↗

The role of unneutralized surface ions in negative potential arcing

The observed arcing on negatively biased solar arrays exposed to plasma environments is shown to be due to an effective charge layer on the interconnect formed by ion collection from the plasma. Time scales to form this layer are shown to be in agreement with experimental observations. A quantitative theory is presented which predicts arcing threshold dependence on plasma density and external potentials. After breakdown, the discharge process is modeled as space charge limited transport to nearby coverslips. Peak currents and decay times predicted by this model are compared with experimental observations.

Jongeward, G. A.↗

Effect of structure on current and potential distributions in porous electrode

Porous electrodes generally contain constricted macropores and localized micropores. The effects of the macropore constrictions on the resistance of a capillary were studied and an analytical model was developed for predicting the current distribution in a constricted macropore which directly includes constriction effects and does not require an empirical tortuosity parameter. The current and concentration distributions in localized micropores were also investigated and it was shown that the microporous area is fully accessible to charge and mass transfer processes. From these analyses it was concluded that the micropores primarily affect the kinetics of the interfacial processes by contributing to the interfacial area, while the macropores impose ohmic and mass transport limitations through the volume of the porous electrode.

Lanzi, Oscar↗