Results for “water/wastewater”

DOE OSTI2025

Recent Progress on Cerium Oxide‐Based Nanostructures for Energy and Environmental Applications

Cerium oxide (CeO 2 ) photo/electrocatalysts for energy storage and environmental applications have attracted considerable interest because of stable crystal structure, low toxicity/cost, superior chemical stability, stable redox (Ce 3+ /Ce 4+ ) pairs, abundant oxygen defects, and capablility for intense interaction with other materials. However, the wide bandgap and poor conductivity lower the CeO 2 photo/electrocatalytic and energy storage performances. To overcome these limitations, various modification strategies (tuning morphology, doping or loading of metal nanoparticles, and heterostructures) have been applied for the improvement of photocatalytic (removal of organic contaminants from water/wastewater and H 2 production and CO 2 reduction reactions) efficiency, electrocatalytic (hydrogen/oxygen evolution reactions and CO 2 reduction reactions), and energy storage performances (supercapacitor) of CeO 2 ‐based materials. Herein, the recent progress of CeO 2 ‐based materials for electro(photo)catalysis and energy storage applications has been discussed. The challenges and possible direction of CeO 2 ‐based materials for electro(photo)catalysis and energy storage applications have been emphasized. Furthermore, this comprehensive review is expected to advance the design of CeO 2 ‐based materials and their applications in electro(photo)catalysis and energy.

Ray, Schindra Kumar [Department of Chemistry North↗

DOE OSTI2022

Novel catalysts with multivalence copper for organic pollutants removal from wastewater with excellent selectivity and stability in Fenton‐like process under neutral pH conditions

Abstract Fenton‐like reaction has been widely used for organics degradation. However, most Fenton‐like reaction works at low pH range (pH < 4) with uncontrollable selectivity of hydroxyl radicals from H 2 O 2 activation, and unsatisfied catalyst stability, which is compromised advanced oxidation performance for water/wastewater treatments. In this work, to solve the drawbacks, novel copper catalysts were fabricated via hydrogen reduction/calcination of Cu 2+ ‐supported Al/MCM‐41 with precisely controllable copper valence state. Compared with catalysts with monovalence copper (i.e., CuO, Cu, and Cu 2+ ), the obtained catalysts with multivalence copper present higher selectivity, excellent stability towards •OH radical pathways, and outperformance in p CBA degradation efficiency at neutral state. In addition, the fabricated catalysts also exhibited excellent phenol removal efficiency (75.5%) and H 2 O 2 utilization efficiency (47.9%) within neutral environment. Moreover, the degradation efficiency of phenol approaches to 100% within only 2 h. The catalyst also shows good stability for organic pollutants removal, which shows good potential in catalytic oxidation for phenolic compounds‐containing wastewater in Fenton‐like reaction, especially under neutral pH conditions. Practitioner Points Multivalence copper presents great potentials for organic compounds removal at neutral condition. Multivalence copper shows higher selectivity toward •OH and good stability at neutral condition. Multivalence copper exhibiters outperformed phenol removal efficiency at neutral condition.

Li, Haitao↗

DOE OSTI2022

Demand Response in Industrial Facilities: Peak Electric Demand

The US Department of Energy’s (DOE’s) Better Buildings, Better Plants Program (Better Plants) is a voluntary energy efficiency leadership initiative for US manufacturers and water/wastewater entities. The program encourages organizations to commit to reducing the energy intensity of their US operations over a 10-year period, typically by 25%. Companies joining Better Plants are recognized by DOE for their leadership in implementing energy efficiency practices and for reducing their energy intensity. Better Plants Partners are assigned to a Technical Account Manager, who can help companies establish energy intensity baselines, develop energy management plans, and identify key resources and incentives from DOE, other federal agencies, states, utilities, and other organizations that can enable them to reach their goals. Better Plants Partners are expected to report their progress to DOE once a year. This involves establishing an energy intensity baseline upon joining the program and then tracking their progress over time. Demand Response in Industrial Facilities: Peak Electrical Demand is intended to help companies understand peak demand response programs offering by their local utility. Manufacturing industries can learn about time-varying rates and smart technologies they can use to help them reduce their energy bills. This guidance document is applicable to companies participating at either the program or challenge level. Although this guide is intended primarily to assist companies participating in Better Plants, the methodologies and guidance within the document are applicable to any organization interested in understanding peak demand response programs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2022

Demand Response in Industrial Facilities: Peak Electric Demand

The US Department of Energy’s (DOE’s) Better Buildings, Better Plants Program (Better Plants) is a voluntary energy efficiency leadership initiative for US manufacturers and water/wastewater entities. The program encourages organizations to commit to reducing the energy intensity of their US operations over a 10-year period, typically by 25%. Companies joining Better Plants are recognized by DOE for their leadership in implementing energy efficiency practices and for reducing their energy intensity. Better Plants Partners are assigned to a Technical Account Manager, who can help companies establish energy intensity baselines, develop energy management plans, and identify key resources and incentives from DOE, other federal agencies, states, utilities, and other organizations that can enable them to reach their goals. Better Plants Partners are expected to report their progress to DOE once a year. This involves establishing an energy intensity baseline upon joining the program and then tracking their progress over time. Demand Response in Industrial Facilities: Peak Electrical Demand is intended to help companies understand peak demand response programs offering by their local utility. Manufacturing industries can learn about time-varying rates and smart technologies they can use to help them reduce their energy bills. This guidance document is applicable to companies participating at either the program or challenge level. Although this guide is intended primarily to assist companies participating in Better Plants, the methodologies and guidance within the document are applicable to any organization interested in understanding peak demand response programs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2025

PFAS Waste Management for Industrial, Water, and Wastewater Treatment Facilities

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), are widely used in industrial and consumer products due to their unique water and oil repelling properties. These slow-degrading and bio-accumulating compounds, often called "forever chemicals," are not typically removed by conventional industrial and municipal water/wastewater (W/WW) treatment. This tip of the month provides comprehensive strategies for managing PFAS-contaminated waste streams. Understanding the various types of PFAS waste streams is the first step in managing them. Primary PFAS waste includes contaminated process W/WW and solid materials directly from the production and processing of PFAS-containing materials. These might come from manufacturing facilities, firefighting training areas, or other industrial operations where PFAS compounds are used or were historically present. Secondary PFAS waste results from treatment and disposal mechanisms of primary PFAS waste streams, including spent activated carbon, used ion exchange resins, membrane reject streams, PFAS-laden backwash water, landfill leachate, incineration residuals, etc. TABLE 1 lists examples of the most common PFAS waste streams in different industrial facilities.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS1991

Two new advanced forms of spectrometry for space and commercial applications

Reagentless ultraviolet absorption spectrometry (UVAS) and Liquid Atomic Emission Spectrometry (LAES) represent new forms of spectrometry with extensive potential in both space and commercial applications. Originally developed under KSC sponsorship for monitoring nutrient solutions for the Controlled Ecological Life Support System (CELSS), both UVAS and LAES have extensive analytical capabilities for both organic and inorganic chemical compounds. Both forms of instrumentation involve the use of remote fiber optic probes and real-time measurements for on-line process monitoring. Commercial applications exist primarily in environmental analysis and for process control in the chemical, pulp and paper, food processing, metal plating, and water/wastewater treatment industries.

Schlager, Kenneth J.↗

NASA NTRS1997

Application of NASA's Advanced Life Support Technologies in Polar Regions

The problems of obtaining adequate pure drinking water and disposing of liquid and solid waste in the U.S Arctic, a region where virtually all water is frozen solid for much of the year, has led to unsanitary solutions. Sanitation and a safe water supply are particularly problems in rural villages. These villages are without running water and use plastic buckets for toilets. The outbreak of diseases is believed to be partially attributable to exposure to human waste and lack of sanitation. Villages with the most frequent outbreaks of disease are those in which running water is difficult to obtain. Waste is emptied into open lagoons, rivers, or onto the sea coast. It does not degrade rapidly and in addition to affecting human health, can be harmful to the fragile ecology of the Arctic and the indigenous wildlife and fish populations. Current practices for waste management and sanitation pose serious human hazards as well as threaten the environment. NASA's unique knowledge of water/wastewater treatment systems for extreme environments, identified in the Congressional Office of Technology Assessment report entitled An Alaskan Challenge: Native Villagt Sanitation, may offer practical solutions addressing the issues of safe drinking water and effective sanitation practices in rural villages. NASA's advanced life support technologies are being combined with Arctic science and engineering knowledge to address the unique needs of the remote communities of Alaska through the Advanced Life Systems for Extreme Environments (ALSEE) project. ALSEE is a collaborative effort involving the NASA, the State of Alaska, the University of Alaska, the North Slope Borough of Alaska, Ilisagvik College in Barrow and the National Science Foundation (NSF). The focus is a major issue in the State of Alaska and other areas of the Circumpolar North; the health and welfare of its people, their lives and the subsistence lifestyle in remote communities, economic opportunity, and care for the environment. As advanced technologies are transferred to the commercial sector the ALSEE project Offers the potential for development of new industries in Alaska to supply the products to support remote communities of the globe.

Bubenheim, David L.↗

DOE OSTI2021

Future of Water Infrastructure and Innovation Summit

Energy and water systems are interdependent, and the U.S. Department of Energy (DOE) has invested in energy and water for several years, including the Energy-Water Desalination Hub (led by the National Alliance for Water Innovation, NAWI), and research and development (R&D) in resource recovery from wastewater, among other areas. The Advanced Manufacturing Office (AMO) at the U.S. Department of Energy (DOE) held The Future of Water Infrastructure and Innovation Summit to inform the understanding of future opportunities in the water space. The virtual summit was held on October 27 and 28, 2020. The organizers gathered information from a diverse group of relevant water and wastewater stakeholders representing academia, industry, government, nongovernmental organizations, and local/regional utilities. Topics from Day 1 discussions included: desalination, water and wastewater treatment/recovery, produced water, industrial management of water, and hydropower, conveyance, and water systems.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗