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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Development and Airborne Operation of a Compact Water Isotope Ratio Infrared Spectrometer

A sensitive laser spectrometer, named IRIS (water isotope ratio infrared spectrometer), was developed for the in situ detection of the isotopic composition of water vapour in the upper troposphere and the lower stratosphere. Isotope ratio measurements can be used to quantify troposphere stratosphere exchange, and to study the water chemistry in the stratosphere. IRIS is based on the technique of optical feedback cavity-enhanced absorption spectroscopy. It uses a room temperature near-infrared laser, and does not require cryogenic cooling of laser or detectors. The instrument weighs 51 kg including its support structure. Airborne operation was demonstrated during three flights aboard the European M55-Geophysica stratospheric research aircraft, as part of the AMMA/SCOUT-03 (African Monsoon Multidisciplinary Analysis/Stratospheric Climate links with emphasis on the Upper Troposphere and lower stratosphere) campaign in Burkina Faso in August 2006. The data are discussed with reference to a Rayleigh distillation model. As expected, there is no indication of non-mass-dependent fractionation (also known as mass-independent fractionation) in the troposphere. Furthermore, improvements to the thermal management system and a move to a (cryogen-free) longer-wavelength laser source are discussed, which together should result in approximately two orders of magnitude improvement of the sensitivity

Iannone, Rosario Q.↗
NASA NTRS1997

Validity of the Temperature Reconstruction from Water Isotopes in Ice Cores

Well-documented present-day distributions of stable water isotopes (HDO and others) show the existence, in middle and high latitudes, of a linear relationship between the mean annual isotope content of precipitation (SD and 51"0) and the mean annual temperature at the precipitation site. Paleoclimatologists have used this relationship, which is particularly well obeyed over Greenland and Antarctica, to infer paleotemperatures from ice core data. There is, however, growing evidence that spatial and temporal isotope/ surface temperature slopes differ, thus complicating the use of stable water isotopes as paleothermometers. In this paper we review empirical estimates of temporal slopes in polar regions and relevant information that can be inferred from isotope models: simple, Rayleigh-type distillation models and (particularly over Greenland) general circulation models (GCMS) fitted with isotope tracer diagnostics. Empirical estimates of temporal slopes appear consistently lower than present-day spatial slopes and are dependent on the timescale considered. This difference is most probably due to changes in the evaporative origins of moisture, changes in the seasonality of the precipitation, changes in the strength of the inversion layer, or some combination of these changes. Isotope models have not yet been used to evaluate the relative influences of these different factors. The apparent disagreement in the temporal and spatial slopes clearly makes calibrating the isotope paleothermometer difficult. Nevertheless, the use of a (calibrated) isotope paleothermometer appears justified; empirical estimates and most (though not all) GCM results support the practice of interpreting ice core isotope records in terms of local temperature changes.

Jouzel, J.↗
NASA NTRS2005

Models for Water Isotopes Constrained with Data from Crystal Face

During the year covered by this proposal we conducted work on several different topics, as reflected by our publications listed below. One major activity was to work with a group of about 10 scientists from around the country to prepare a science-planning document (Tropical Composition, Cloud and Climate Coupling Experiment (TC4)) that outlined the rationale, locations, strategy to accomplish the goals, and possible payloads for a set of three tropical missions. We also prepared background materials for various NRAs being prepared at NASA Headquarters for missions in Costa Rica, Darwin and Guam. Unfortunately budgetary constraints prevented these missions from moving forward. In conjunction with the group NASA Ames we built a new numerical model for deep convection and have applied that model to simulate the CRYSTAL isotope data. Our goal in particular has been to better understanding how convection distributes water vapor isotopes. CRYSTAL observations of water isotopes are very different from those suggested by previous workers who assumed the isotopes would obey Rayleigh fractionation. The water isotope study has several implications. First it is a check on the realism of the deep convection model. Second, the isotopes are a measure of the precipitation removal in the atmosphere. Hence they provide a constraint on a parameter that is difficult to otherwise measure. Finally it has been suggested that isotopes may be the key to unraveling the water transport into the stratosphere and upper troposphere. Such transport is critical both for the radiation balance and for stratospheric chemistry. Ours is the first model that is able to treat this transport. Our initial results are now in press in Geophys. Res. Lett. Essentially we are able to explain the vertical profiles of isotopes in the tropical tropopause transition layer. We are also able to account for stratospheric humidity ana isotope abundances with this model. The data suggest that isotopes do not provide a clear constraint on the mechanism by which water enters the stratosphere- whether by convection, or by slow ascent. Our work is relevant for the water isotope comparison experiments recently done by NASA. We are conducting numerical experiments related to this project to help understand that data.

Toon, Owen B.↗
DOE OSTI2026

Stable Water Isotope Data for the East River Watershed, Colorado (2014-2025)

The stable water isotope data for the East River Watershed, Colorado, consists of delta2H (hydrogen) and delta18O (oxygen) values from samples collected at multiple, long-term monitoring sites including streams, groundwater wells, springs, and a precipitation collector used to establish a local meteoric water line (LMWL) for the watershed. These locations represent important and/or unique end-member locations for which stable isotope values can be diagnostic of the connection between precipitation inputs as snow and rain and riverine export. Such locations include drainages underline entirely or largely by shale bedrock, land covered dominated by conifers, aspens, or meadows, and drainages impacted by historic mining activity and the presence of naturally mineralized rock. Developing a long-term record of water isotope values from a diversity of environments is a critical component of quantifying the impacts of both climate change and discrete climate perturbations, such as drought, forest mortality, and wildfire, on water export. Such data may be combined with stream gaging stations co-located at each surface water monitoring site to relate seasonal variations in water export to their stable isotopic signature. Data for liquid water delta2H and delta18O values are reported in units of parts per thousand (per-mil; ‰). This data package contains (1) a zip file (isotope_data_2014-2025.zip) containing a total of 95 files: 96 data files of isotope data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v6_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; and (3) a data dictionary (v6_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type. Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 43 locations containing isotope data. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated isotope data for all locations up to 2021-12-31 and (2) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-03-13. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2024-02-19. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available isotope data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available isotope data was added, up until the end of WY2025 (September 30, 2025).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Water isotope data for the TEMPEST study site, 2023-2026

This dataset contains water isotope (deuterium (dD) and oxygen (d18O)) data from porewater, experimental source water, and aquifer sources from the Terrestrial Ecosystem Manipulation to Probe the Effects of Storm Treatments (TEMPEST) experimental field site in Edgewater, MD. Samples were taken from 2023-2026 and included in file "TEMPEST_Water_Isotope_LANL_2023-2026.csv". Porewater samples were taken from 15cm depth at multiple locations in each experimental plot (i.e., control, freshwater, and saltwater). Water samples were stored in 2 ml amber glass vials with septum caps under refrigeration until analysis. A L2140-i Picarro cavity ringdown spectrometer connected to an A0211 Picarro vaporization module was used to run water samples. Standards (United States Geological Survey (USGS) 47 and 48) were used to check instrument accuracy during each run of samples. Post-processing codes were run to calculate isotopic values from raw data. Reported isotope data is post-processed. Raw data CSV files from the Picarro were processed using a Python script and output as excel files containing data calibrated to Vienna Standard Mean Ocean Water (VSMOW). Standardization is based on USGS47 and USGS48 standards that are measured before and after every 5-10 unknowns. Every measurement is comprised of 10 injections. Processing involved discarding the first 4 injections due to a known memory effect. Raw means of the last 6 injections are taken for each measurement and then corrected from the linear calibration relationship of the USGS standards expected vs measured values to obtain corrected compositions relative to VSMOW. Reported isotope data are corrected mean results.

Aquifer↗
NASA NTRS1994

Stable water isotope behavior during the last glacial maximum: A general circulation model analysis

Global water isotope geochemisty during the last glacial maximum (LGM) is simulated with an 8 deg x 10 deg atmospheric general circulation model (GCM). The simulation results suggest that the spatial delta O-18/temperature relationships observed for the present day and LGM climates are very similar. Furthermore, the temporal delta O-18/temperature relationship is similar to the present-day spatial relationship in regions for which the LGM/present-day temperature change is significant. This helps justify the standard practice of applying the latter to the interpretation of paleodata, despite the possible influence of other factors, such as changes in the evaportive sources of precipitation or in the seasonality of precipitation. The model suggests, for example, that temperature shifts inferred from ice core data may differ from the true shifts by only about 30%.

Jouzel, Jean↗
DOE OSTI2025

Opportunistic Short‐Term Water Uptake Dynamics by Subalpine Trees Observed via In Situ Water Isotope Measurements

Abstract Variations in tree water sources are important to understand in semi‐arid ecosystems because climatic shifts towards lower snowpack and increased drought affect water availability in subalpine forests of the western US. Here, we use daily in situ measurements of stable isotopes ( 2 H & 18 O) in soil and tree stem water, soil matric potential and sap flow to study tree water uptake dynamics. We instrumented three soil profiles down to 90 cm, as well as three aspen and engelmann spruce trees near Gothic, Colorado, in the East River watershed. We observed the fate of natural isotopic variations in rainfall, soil, and plants from June to October 2022, and in August 2023 we conducted a 2 H labeled irrigation experiment. Our observations showed that all studied aspen trees compensated for water scarcity in the shallow soil by shifting the dominant water source at 60(±20) cm to ⅔ of uptake from 90 cm within a few days of a dry period. Both species relied on snowmelt stored in the subsoil to sustain transpiration. Intense rainfall caused the plant water uptake to shift partially to top soil layers within 2 days. Spruce transpiration was lower and relied more on snowmelt, because rainfall infiltration was low in the spruce stand due to high canopy interception. Our findings highlight the important role of snowmelt stored in the deep soil layers for subalpine forest drought response and the dominant fate of monsoonal rainfall to become transpiration rather than recharging groundwater and streams in the Upper Colorado River. Plain Language Summary There is a need to understand how trees in mountainous regions respond to dry conditions that lead to water scarcity, because climate projections suggest that such conditions will become more frequent in the future. Here we present a novel data set of measurements of daily stable isotopes of water across soil profiles and in tree stems of aspen and spruce. Our data show that when the upper soil dried out, aspen trees shifted to using water from deeper layers (beneath 60 cm) to keep transpiring. For spruce trees the uptake pattern is less clear, but both types of trees mainly used snowmelt stored in the deeper soil layers to survive the dry summer. After heavy rain, aspen and spruce trees switched to using water from the top 20 cm of soil. However, for spruce, only some rain reached the soil because the dense tree canopy intercepted it, so spruce trees stayed more dependent on snowmelt and used less water overall. This study shows how important deep snowmelt water is for helping forests survive dry periods and suggests that most summer rain is quickly used by trees rather than replenishing streams and groundwater in the headwaters of the Colorado River. Key Points Tree water resources changed within a few days from snow dominated to higher share of rainfall as soils wetted up after a dry period Compensatory plant water uptake by aspen from the deep layer (90 cm), while uptake from soil depths that became drier (60 cm) declined Strong differences between water sources and availability beneath aspen and spruce, respectively

Sprenger, Matthias↗
DOE OSTI2026

California Trees Seasonally Use Augmented Water Sources: Water Isotope Tracking in a Groundwater‐Dependent Ecosystem

Sustainable groundwater management must account for the needs of groundwater dependent ecosystems. To understand the relationship of ecosystems and seasonal water use, we studied the stable isotope composition (δ 18 O and δ 2 H) of water in streamside trees in a semi-arid streamside environment (Livermore, California, USA). We sampled seven trees at two sites every other month from April 2024 through April 2025 for tree xylem stable water isotope signatures. These data were compared to potential source waters: precipitation, imported surface water, soil water and regional groundwaters. Large daily precipitation events were found to be isotopically similar to regional groundwater and were thus treated as one water source. A Bayesian mixing model using stable water isotopes was used to determine the ratios of these three potential source waters (small daily precipitation events, groundwater/large daily precipitation events and imported water) present in tree xylem water. On average, tree water sources include 32% imported water (SD = 9%), 35% small daily precipitation events (SD = 10%) and 33% groundwater (SD = 3%), with significant seasonal variation (t summer-winter = 30.8, p < 0.01), particularly drawing more imported water (more than 55%) in the summer. While small daily precipitation events contribute only 10% of the total precipitation in our dataset, it represents a third of water used by trees. In addition, while these ecosystems are designated as groundwater dependent ecosystems, the trees use approximately one third imported water and even more during dry summer months. This approach provides water managers with a practical tool for quantifying ecosystem water needs, supporting data-driven decisions and regulatory compliance. While California's Sustainable Groundwater Management Act emphasizes supporting groundwater dependent ecosystems, it allows flexibility in demonstrating benefits. In conclusion, our methodology provides a way to document that management actions (such as managed aquifer recharge with imported water) deliver measurable co-benefits to GDEs.

Geosciences↗
NASA NTRS2019

The Connected Isotopic Water Cycle in the Community Earth System Model Version 1

Because of the pervasive role of water in the Earth system, the relative abundances of stable isotopologues of water are valuable for understanding atmospheric, oceanic, and biospheric processes, and for interpreting paleoclimate proxy reconstructions. Isotopologues are transported by both largescale and turbulent flows, and the ratio of heavy to light isotopologues changes due to fractionation that can accompany condensation and evaporation processes. Correctly predicting the isotopic distributions requires resolving the relationships between largescale ocean and atmospheric circulation and smallerscale hydrological processes, which can be accomplished within a coupled climate modeling framework. Here we present the water isotopeenabled version of the Community Earth System Model version 1 (iCESM1), which simulates global variations in water isotopic ratios in the atmosphere, land, ocean, and sea ice. In a transient Last Millennium simulation covering the 850-2005 period, iCESM1 correctly captures the latetwentiethcentury structure of δ(exp 18)O and δD over the global oceans, with more limited accuracy over land. The relationship between salinity and seawater δ(exp 18)O is also well represented over the observational period, including interbasin variations. We illustrate the utility of coupled, isotopeenabled simulations using both Last Millennium simulations and freshwater hosing experiments with iCESM1. Closing the isotopic mass balance between all components of the coupled model provides new confidence in the underlying depiction of the water cycle in CESM, while also highlighting areas where the underlying hydrologic balance can be improved. The iCESM1 is poised to be a vital community resource for ongoing model development with both modern and paleoclimate applications.

Brady, E.↗
NASA NTRS1998

Water Isotopes in Precipitation: Data/Model Comparison for Present-Day and Past Climates

Variations of HDO and H2O-18 concentrations are observed in precipitation both on a geographical and on a temporal basis. These variations, resulting from successive isotopic fractionation processes at each phase change of water during its atmospheric cycle, are well documented through the IAEA/WMO network and other sources. Isotope concentrations are, in middle and high latitudes, linearly related to the annual mean temperature at the precipitation site. Paleoclimatologists have used this relationship to infer paleotemperatures from isotope paleodata extractable from ice cores, deep groundwater and other such sources. For this application to be valid, however, the spatial relationship must also hold in time at a given location as the location undergoes a series of climatic changes. Progress in water isotope modeling aimed at examining and evaluating this assumption has been recently reviewed with a focus on polar regions and, more specifically, on Greenland. This article was largely based on the results obtained using the isotopic version of the NASA/GISS Atmospheric General Circulation Model (AGCM) fitted with isotope tracer diagnostics. We extend this review in comparing the results of two different isotopic AGCMs (NASA/GISS and ECHAM) and in examining, with a more global perspective, the validity of the above assumption, i.e. the equivalence of the spatial and temporal isotope-temperature relationship. We also examine recent progress made in modeling the relationship between the conditions prevailing in moisture source regions for precipitation and the deuterium-excess of that precipitation.

Jouzel, J.↗
NASA NTRS2015

Strong Water Isotopic Anomalies in the Martian Atmosphere: Probing Current and Ancient Reservoirs

We measured maps of atmospheric water (H2O) and its deuterated form (HDO) across the martian globe, showing strong isotopic anomalies and a significant high deuterium/hydrogen (D/H) enrichment indicative of great water loss. The maps sample the evolution of sublimation from the north polar cap, revealing that the released water has a representative D/H value enriched by a factor of about 7 relative to Earth's ocean [Vienna standard mean ocean water (VSMOW)]. Certain basins and orographic depressions show even higher enrichment, whereas high-altitude regions show much lower values (1 to 3 VSMOW). Our atmospheric maps indicate that water ice in the polar reservoirs is enriched in deuterium to at least 8 VSMOW, which would mean that early Mars (4.5 billion years ago) had a global equivalent water layer at least 137 meters deep.

Research Support, U.S. Gov't, Non-P.H.S.↗
NASA NTRS2018

A Submm-Wave Comet Explorer for Water Isotopic Composition Measurements

Remote submm-wave spectrometers have the capability of providing statistically significant numbers of isotopic composition measurements within the budget constraints of available planetary missions. This talk will present a mission and instrument concept that would enable an accurate measurement of the D/H ratio on not one but several dozens of comets in a four-year mission lifetime. The instrument would utilize advanced cryogenic detectors that would allow us to measure the abundance of the para and ortho spin states of water and its isotopologues. State of the art superconducting heterodyne receivers have been developed that provide detection sensitivities approaching the quantum limit in the 500 GHz frequency range enabling the measurement of D/H ratio on around 50 comets from an observatory stationed for example at the thermally benign Lagrange point L2.

Feldman, Sabrina↗
DOE OSTI2025

Using stable isotopes in water vapor to study the interdependence of clouds, atmospheric aerosols, and precipitation processes

This project deployed water vapor isotope measurements at the La Porte, Texas TRACER site during June-September 2022 to quantify mixing processes in sea breeze circulations. Using a Picarro L2130 analyzer, we collected high-frequency measurements of δD and δ¹⁸O that revealed how marine and terrestrial air masses mix during 46 identified sea breeze events. The isotopic tracers showed systematic changes during frontal passages, with composite analyses demonstrating vertical mixing between cool marine air and warmer air aloft. We developed a transilient matrix model that explicitly treats non-local mixing and isotopic fractionation to interpret the observations. The work directly supports TRACER's core objective of understanding convective initiation by constraining the vertical transport of water vapor and its interaction with Houston's aerosol-laden urban plume during sea breeze-convection coupling.

58 GEOSCIENCES↗
NASA NTRS2026

The Significance of Water Vapor Isotopes in Improving Weather Prediction

Water vapor isotopes carry the integrated history of evaporation, condensation, mixing, and transport. Although previous studies have shown potential to improve forecasts under controlled conditions, real-world applications have been limited by systematic biases in both models and satellite retrievals arising from sparse measurements in the free troposphere. Here we assimilate mid‑tropospheric δD retrievals (peak sensitivity ~4.2 km) from the Infrared Atmospheric Sounding Interferometer into the Isotope‑incorporated Global Spectral Model and evaluate the added value beyond co‑assimilated temperature and specific humidity with identical spatial and temporal coverage. Assimilating δD improves 0–120 h forecasts of wind, temperature, specific humidity, and geopotential height, with the largest gains in the midlatitudes; heavy‑precipitation skill also increases for thresholds >3 mm per 6 h. Demonstrated in a coarse‑resolution configuration with limited observations, the results indicate that isotopic information strengthens transport tracking and hydrological constraints, motivating evaluation in operational high‑resolution forecasting systems.

Hydrology↗
NASA NTRS1991

Stratospheric profiles of heavy water vapor isotopes and CH3D from analysis of the ATMOS Spacelab 3 infrared solar spectra

The isotopic composition of stratospheric water vapor and methane was investigated. Stratospheric profiles of HDO, (H-18)2O, (H-17)2O, and CH3D were derived from solar occultation spectra recorded on April 30 - May 1, 1985 by the Atmospheric Trace Molecule Spectroscopy Fourier transform spectrometer aboard Spacelab 3. The profiles of the three water-vapor isotopes showed an increase in the volume mixing ratio with altitude. The measured profiles of D/H in water vapor showed a large depletion in the lower stratosphere (about 63 percent relative to standard mean ocean water, SMOW, at 20 km) and a small increase in D/H with altitude at higher altitudes, up to 34 km. The D/H ratio in stratospheric methane was close to the corresponding isotopic ratio in SMOW.

Rinsland, C. P.↗
DOE OSTI2026

CAPE-K_ISO: Water vapor isotopic measurements from Western Tasmania

This dataset provides processed 1-minute water vapor isotope observations from the Water Vapor Isotopic Measurements During CAPE-K project at the Kennaook/Cape Grim Baseline Air Pollution Station in northwestern Tasmania. Measurements were made with a Picarro L-2130 cavity ring-down spectroscopy analyzer during the CAPE-K deployment. The dataset includes water vapor mixing ratio, d18O, dD, deuterium excess, and propagated 1-sigma uncertainties. Isotope ratios are calibrated to the VSMOW/SLAP scale. Calibration intervals, transition periods, and obvious isotope outliers have been removed. The processed record spans 11 June 2024 to 15 October 2025 and is intended for studies of Southern Ocean marine boundary-layer moisture, isotope variability, air-sea exchange, and cloud and precipitation processes.

Water Vapor Isotopic Composition↗