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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Connectivity between Static Field and Continuous Wave Field Effects on Excitation-Induced H 2 Activation

Due to the tremendous applications of the plasmon resonance excitation process, such as improvements in catalytic efficiency due to plasmonic enhancement and/or hot-electron processes, understanding the mechanism behind these processes has become a popular topic in recent years. In this work, we focus on unraveling the mechanism of excitation-induced H 2 activation using a simplified triangular Au 6 /Ag 6 cluster to investigate the effects of the electric field on electron redistribution and bond activation. We applied both static and continuous wave fields to investigate how these fields affect the systems. Geometrical changes (such as bond lengthening), molecular orbital reordering (affecting the relative energies of orbitals corresponding to hot-electron and charge-transfer excited states), and electronic charge redistribution between the cluster and the adsorbate occur upon application of a static electric field. To study H 2 activation, we apply Ehrenfest dynamics with real-time time-dependent density functional theory and examine how different excitation frequencies and polarizations affect bond activation. Moreover, electron-only dynamics are examined with real-time time-dependent density functional theory, and the time-dependent variations in the orbital populations and electronic transitions provide information about the excitation and relaxation processes of hot electrons with applied electric fields. Here, the static field results represent structures that can be accessed during the evolution of the systems when applying continuous wave fields. Through these studies, the effects of static and continuous wave field effects on plasmon-induced H 2 activation can be understood.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Analysis of upper mantle structure using wave field continuation of P waves

Wave field continuation theory, which allows transformation of the seismic record section data directly into velocity-depth space, is tested for upper mantle analysis using a large array-recorded data set obtained at the 200-station Caltech-USGS Southern California Seismic Network that is representative of the structure beneath the gulf of California. The method's resolution capability is illustrated by the comparison of the slant stacks and downward continuation of both synthetic and data record sections. It is stressed that when high-quality, densely sampled digital data are available, the technique is easy to implement, provides an inversion which contains all the data in the global format, and produces an objective estimate of depth resolution as a function of ray parameter.

Walck, M. C.↗
NASA NTRS1983

A case study of the energy dissipation of the gravity wave field based on satellite altimeter measurements

Wave breaking is proposed as the primary energy dissipation mechanism for the gravity wave field. The energy dissipation rate is calculated based on the statistical model proposed by Longuet-Higgins (1969) with a modification of the breaking criterion incorporating the surface stress according to Phillips and Banner (1974). From this modified model, an analytic expression is found for the wave attenuation rate and the half-life time of the wave field which depend only on the significant slope of the wave field and the ratio of friction velocity to initial wave phase velocity. These expressions explain why the freshly generated wave field does not last long, but why swells are capable of propagating long distances without substantial change in energy density. It is shown that breaking is many orders of magnitude more effective in dissipating wave energy than the molecular viscosity, if the significant slope is higher than 0.01. Limited observational data from satellite and laboratory are used to compare with the analytic results, and show good agreement.

Huang, N. E.↗
NASA NTRS1982

Wave spectra of a shoaling wave field: A comparison of experimental and simulated results

Wave profile measurements made from an aircraft crossing the North Carolina continental shelf after passage of Tropical Storm Amy in 1975 are used to compute a series of wave energy spectra for comparison with simulated spectra. Results indicate that the observed wave field experiences refraction and shoaling effects causing statistically significant changes in the spectral density levels. A modeling technique is used to simulate the spectral density levels. Total energy levels of the simulated spectra are within 20 percent of those of the observed wave field. The results represent a successful attempt to theoretically simulate, at oceanic scales, the decay of a wave field which contains significant wave energies from deepwater through shoaling conditions.

Morris, W. D.↗
NASA NTRS2023

Breaking Wave Field Statistics With A Multi-Layer Model

The statistics of breaking wave fields are characterised within a novel multi-layer framework, which generalises the single-layer Saint-Venant system into a multi-layer and non-hydrostatic formulation of the Navier–Stokes equations. We simulate an ensemble of phase-resolved surface wave fields in physical space, where strong nonlinearities, including directional wave breaking and the subsequent highly rotational flow motion, are modelled, without surface overturning. We extract the kinematics of wave breaking by identifying breaking fronts and their speed, for freely evolving wave fields initialised with typical wind wave spectra. The Λ(c) distribution, defined as the length of breaking fronts (per unit area) moving with speed c to c + dc following Phillips (J. Fluid Mech., vol. 156, 1985, pp. 505–531), is reported for a broad range of conditions. We recover the Λ(c) ∝ c−6 scaling without wind forcing for sufficiently steep wave fields. A scaling of Λ(c) based solely on the root-mean-square slope and peak wave phase speed is shown to describe the modelled breaking distributions well. The modelled breaking distributions are in good agreement with field measurements and the proposed scaling can be applied successfully to the observational data sets. The present work paves the way for simulations of the turbulent upper ocean directly coupled to a realistic breaking wave dynamics, including Langmuir turbulence, and other sub-mesoscale processes.

Jiarong Wu↗
DOE OSTI2022

Error metrics for partially coherent wave fields

Lensless imaging methods that account for partial coherence have become very common in the past decade. However, there are no metrics in use for comparing partially coherent light fields, despite the widespread use of such metrics to compare fully coherent objects and wave fields. Here, we show how reformulating the mean squared error and Fourier ring correlation in terms of quantum state fidelity naturally generalizes them to partially coherent wave fields. We report these results fill an important gap in the lensless imaging literature and will enable quantitative assessments of the reliability and resolution of reconstructed partially coherent wave fields.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1997

Passive Scalar Transport by Travelling Wave Fields

We study passive scalar transport by a stochastic travelling wave field in the physically relevant limit were typical fluid velocities, are much smaller than the typical group velocity, of the waves.

Scalar Transport Stochastic wave field↗
NASA NTRS1984

The non-Gaussian joint probability density function of slope and elevation for a nonlinear gravity wave field

On the basis of the mapping method developed by Huang et al. (1983), an analytic expression for the non-Gaussian joint probability density function of slope and elevation for nonlinear gravity waves is derived. Various conditional and marginal density functions are also obtained through the joint density function. The analytic results are compared with a series of carefully controlled laboratory observations, and good agreement is noted. Furthermore, the laboratory wind wave field observations indicate that the capillary or capillary-gravity waves may not be the dominant components in determining the total roughness of the wave field. Thus, the analytic results, though derived specifically for the gravity waves, may have more general applications.

Huang, N. E.↗
NASA NTRS1983

A non-Gaussian statistical model for surface elevation of nonlinear random wave fields

Probability density function of the surface elevation of a nonlinear random wave field is obtained. The wave model is based on the Stokes expansion carried to the third order for both deep water waves and waves in finite depth. The amplitude and phase of the first-order component of the Stokes wave are assumed to be Rayleigh and uniformly distributed and slowly varying, respectively. The probability density function for the deep water case was found to depend on two parameters: the root-mean-square surface elevation and the significant slope. For water of finite depth, an additional parameter, the nondimensional depth, is also required. An important difference between the present result and the Gram-Charlier representation is that the present probability density functions are always nonnegative. It is also found that the 'constant' term in the Stokes expansion, usually neglected in deterministic studies, plays an important role in determining the details of the density function. The results compare well with laboratory and field experiment data.

Huang, N. E.↗
NASA NTRS1994

Magnetic field waves at Uranus

The research efforts funded by the Uranus Data Analysis Program (UDAP) grant to the Bartol Research Institute (BRI) involved the study of magnetic field waves associated with the Uranian bow shock. Upstream wave studies are motivated as a study of the physics of collisionless shocks. Collisionless shocks in plasmas are capable of 'reflecting' a fraction of the incoming thermal particle distribution and directing the resulting energetic particle motion back into the upstream region. Once within the upstream region, the backward streaming energetic particles convey information of the approaching shock to the supersonic flow. This particle population is responsible for the generation of upstream magnetic and electrostatic fluctuations known as 'upstream waves', for slowing the incoming wind prior to the formation of the shock ramp, and for heating of the upstream plasma. The waves produced at Uranus not only differed in several regards from the observations at other planetary bow shocks, but also gave new information regarding the nature of the reflected particle populations which were largely unmeasurable by the particle instruments. Four distinct magnetic field wave types were observed upstream of the Uranian bow shock: low-frequency Alfven or fast magnetosonic waves excited by energetic protons originating at or behind the bow shock; whistler wave bursts driven by gyrating ion distributions within the shock ramp; and two whistler wave types simultaneously observed upstream of the flanks of the shock and argued to arise from resonance with energetic electrons. In addition, observations of energetic particle distributions by the LECP experiment, thermal particle populations observed by the PLS experiment, and electron plasma oscillations recorded by the PWS experiment proved instrumental to this study and are included to some degree in the papers and presentations supported by this grant.

Smith, Charles W.↗
NASA NTRS1984

Non-Gaussian statistical models of surface wave fields for remote sensing applications

Based on the complete Stokes wave model with the bias term and using a simple mapping approach and an iteration solution method, we established a formula for the joint probability density function of the surface slope elevation of a nonlinear random wave field. The formula requires three parameters to define the whole density function: the rms surface elevation and slope values and the significant slope. This model represents the dynamics of the wave in a more direct way than the Gram-Charlier approximation. Based on this new statistical model and laboratory experiments, formula and numerical values of EM bias and dynamics bias are derived. The results indicate that various biases should be considered seriously if accuracy of the altimeter measurement is required in centimeter range.

Huang, N. E.↗
DOE OSTI2024

Identifying Topological Defects in Lamellar Phases through Contour Analysis of Complex Wave Fields

Lamellar phases frequently contain structural imperfections that significantly affect their behaviors and properties. Our previous research successfully reconstructed real-space configurations of defective lamellar phases from diffuse scattering patterns, indicating the presence of phase vortices as a potential method for identifying topological defects disrupting the smectic ordering. Here, this report presents a mathematical framework using regularized wave fields to represent defective lamellar structures in real space. Phase singularities, resulting from the interference of random waves and indicating lamellar order disruption, are identified through a contour integral. These wave fields, derived from coherent scattering in reciprocal space, were validated via computational benchmarks analyzing small-angle neutron scattering data from AOT surfactant solutions, facilitating further statistical analysis of the defects. Our study highlights the potential to extract meaningful information about topological defects in lyotropic phases by inversely analyzing experimentally measured two-point static correlations. Our method allows for detailed structural analysis of various lyotropic phases, both particulate and nonparticulate, in their quiescent states and facilitates quantitative investigation of defects’ role in phase transitions. By integrating small-angle scattering, deep learning, and vortex tangle analysis, our comprehensive approach shows promise in addressing complex challenges in the structural analysis of soft matter systems.

36 MATERIALS SCIENCE↗
NASA NTRS1985

Force on a heated sphere in a horizontal plane acoustic standing wave field

The force on a heated sphere in a horizontal plane acoustic standing wave field is the subject of this investigation. The heated sphere produces a thermal gradient in the resonance chamber. The force on the sphere in a direction perpendicular to that of gravity is measured. This force is enhanced in the region near the pressure node, and is weakened in the region near the pressure antinode. Measurements of the force on a heated sphere with sound pressure levels between 148 and 156 dB are presented.

Leung, E. W.↗
NASA NTRS1986

A study of the relationship among wind speed, sea state, and the drag coefficient for a developing wave field

Controlled laboratory experiments are reported which demonstrate directly and quantitatively the influence of wave conditions in determining the drag law at the air-sea interface under neutral stability conditions. It is concluded that the analytic form first proposed by Kitaigorodskii (1970) models the roughness scale very well when the sea is dominated by the locally generated waves. It is demonstrated that, by using a unified two-parameter wave spectral model by Huang et al. (1981), Kitaigorodskii's result can be shown to contain the formulas of Charnock (1955) and Hsu (1974) as special cases. The results also identify two wind and wave-related parameters as important in determining the drag coefficient for developing wave fields.

Huang, N. E.↗