Structure of K sub 2 BaCo /NO sub 2/ sub 6.
Three-dimensional X-ray diffraction data to determine structure of crystal of potassium barium hexanitrocobaltate, discussing Jahn-Teller effect
CRYSTAL STRUCTURE↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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X-ray powder diffraction study of poly/carbon monofluoride/, CF/1.12/
Data from X-ray diffraction studies of the poly(carbon monofluoride) with empirical formula CF(1.09-1.15) are reported, and possible intercalation arrangements for the substance are discussed. The data do not conform to true hexagonal symmetry, indicating that the carbon atoms are not coplanar. Each bond angle of carbon is 118.8 deg, and the carbon-carbon distance is 1.47 A. The interlayer distance is 5.76 A. A total absence of (hkl) reflections in the X-ray pattern shows that the separate CF layers are not regularly arranged with respect to one another.
Mahajan, V. K.↗
Thermal expansion in the nickel-chromium-aluminum and cobalt-chromium-aluminum systems to 1200 degrees C
Thermal expansion data were obtained on 12 Ni-Cr-Al and 9 Co-Cr-Al alloys by high temperature X-ray diffraction. The data were computer fit to an empirical thermal expansion equation developed in the study. It is shown that the fit is excellent to good, and that the expansion constants depend on phase but not on composition. Phases for the Ni-Cr-Al system and Co-Cr-Al system are given. Results indicate that only alpha Cr has an expansion constant low enough to minimize oxide spalling or coating cracking induced by thermal expansion mismatch.
Lowell, C. E.↗
Ceramic research
X-ray diffraction micrography data on atomic structure of magnesium oxide grain boundaries
X-RAY ANALYSIS↗
Roedderite A new mineral from the Indarch meteorite.
Chemical and mineralogical composition of roedderite found in Indarch meteorite, presenting electron probe analysis and X-ray diffraction pattern optical data
MINERALOGY↗
Electron microscopy and diffraction of layered, superconducting intercalation complexes.
Several layered, transition metal dichalcogenide intercalation complexes with unique superconducting properties have been examined by high-resolution electron microscopy and electron diffraction. Details of the crystalline lattice and of the lattice imperfections have been directly resolved. The results can be correlated with the available X-ray diffraction and chemical data, and they confirm and extend the postulated models.
Fernandez-Moran, H.↗
Relative cooling rates of mare basalts at the Apollo 12 and 15 sites as estimated from pyroxene exsolution data
X-ray single-crystal diffraction studies, supplemented by electron microprobe analyses of core pigeonites and rim augites from rocks 12031, 15085, 15475, and 15495, have been used to suggest cooling rates for these and other Apollo 12 and 15 rocks studied by similar methods. The extent of subsolidus phase separation of pyroxenes is used as a measure of the cooling rate. The results were interpreted in terms of model cooling histories of a lava flow whose thickness was estimated from the absolute cooling rates obtained by cooling rate experiments and by temperature-time variation through an extrusive flow computed by employing simplified theory of Jaeger. All available data on the exsolution and cation distributions of pyroxenes from Apollo 12 and 15 samples at present are consistent with the hypothesis that these rocks were derived from the top and interior of lava flows with thicknesses of 4-10 m. A process for exsolution of augite from a host pigeonite on (100) has been related to its low-calcium content.
Takeda, H.↗
Mark 1 diffractometer electronics
Electronic equipment for Mark 1 lunar X-ray diffractometer - power supply, logic, and data processing subsystems
X-RAY DIFFRACTION↗
The ternary system tantalum-hafnium-carbon at 2050 deg c
Isothermal cross section of tantalum-hafnium- carbon at high temperatures constructed from X-ray diffraction, chemical analysis, and metallographic and microhardness data
ISOTHERMAL LAYER↗
Fluid flow effects on crystalline perfection
Optimum solidification parameters for the production of highly perfect copper crystals by Czochralski growth are sought along with the documentation of crystal imperfections under various growth conditions. X-ray techniques which do not in their application produce defects and which allow the characterization of imperfections in single crystals are chosen to assess crystal perfection. The X-ray techniques employed ranged from ordinary Laue photography through Borrmann topography to double-crystal scanning diffractometry, thus allowing crystals with a wide variation in perfection to be studied. As a set of controllable solidification parameters, the rotation of the seed and of the melt and the diameter of the bottleneck are chosen. X-ray diffraction topographs are analyzed along with the data obtained from rocking curve measurements. Tables of growth conditions and quantitative data of rocking curve widths are presented.
Kuriyama, M.↗
Microprobe and oxygen fugacity study of armalcolite
The stability of synthetic armalcolite was determined as a function of oxygen fugacity with particular regard to the oxidation state of iron and titanium. The equilibrium pseudobrookite (armalcolite) composition was measured at 1200 C under various conditions of oxidation typical of the lunar environment. These data, when compared with published descriptions of mare basalts, provide information about the conditions of crystallization of armalcolite-bearing lunar rocks. Some information about the crystal chemistry of armalcolite was obtained from X-ray diffraction and electron microprobe analyses of synthetic armalcolite and Zr-armalcolite. Further data were gathered from a comparison of the Mossbauer spectra of a phase pure stoichiometric armalcolite and one containing appreciable amounts of trivalent titanium.
Friel, J. J.↗
Silica reinforcement and char reactions in the Apollo heat shield.
Reactions of the silica reinforcement fiber and ablation char of the Apollo heat shield have been investigated by laboratory tests in an arc image furnace (at temperature levels up to 5000 R, pressures up to 0.7 atm, and heat flux similar to reentry) and by an actual reentry test. Microchemical analyses and X-ray diffraction studies have been made to determine the presence of SiC formation in the char. Experimental data and analytical predictions of thermal and density profiles have been compared for the ablation of virgin heat shield and precharred materials to determine the effects of SiC formation on ablation performance. In all analyses, general agreement was found between chemical composition and the thermal predictions for laboratory tests and reentry materials. In all ablated materials, SiC was formed in the front surface of the char. The highest SiC content found was 58% by weight and found in a high-pressure environment. The SiC formed was found to act as a heat sink in the ablation process and can lower the front surface temperature by 300 R.
Cagliostro, D. E.↗
Ternary compound thin film solar cells
A group of ternary compound semiconductor (I-III-VI2) thin films for future applications in photovoltaic devices is proposed. The consideration of these materials (CuInSe2, CuInTe2 and especially CuInS2) for long range device development is emphasized. Much of the activity to date has been concerned with the growth and properties of CuInX2 films. X-ray and electron diffraction analyses, Hall mobility and coefficient, resistivity and carrier concentration variations with substrate and film temperature as well as grain size data have been determined. Both p- and n-type films of CuInS2 and CuInSe2 have been produced. Single and double source deposition techniques have been utilized. Some data have been recorded for annealed films.
Kazmerski, L. L.↗
Interaction of hydrogen chloride with alumina
The influence of outgas conditions and temperature on the adsorptive properties of two aluminas Alon-c and Al6sG were studied using adsorption isotherm measurements. Alon-C and Al6SG were characterized using X-ray powder diffraction, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and BET nitrogen surface areas. Some of these techniques were applied to two other aluminas but no isotherm data was obtained. Isotherm data and techniques applied to each alumina are summarized in tabular form.
Bailey, R. R.↗
A study of phase transitions in lead difluoride by use of polychromatic X-ray diffraction
A polychromatic X-ray diffraction technique was used to obtain patterns of alpha-PbF2 and beta-PbF2. The results obtained at room temperature and 314 C at 1 atm, and at room temperature at 5.5 kbar, are in good agreement with published data. The advantages of the technique for high-temperature and high-pressure work are discussed.
Mahajan, V. K.↗
Beta-FeOOH, akaganeite, in lunar rocks
Experiments were conducted to determine the nature of the alteration process in lunar rocks. Mixtures of 10 wt.% Fe + 10 wt.% FeCl2 + 80 wt.% basalt (terrestrial) were pelletized and allowed to set for 48 hrs at 25 C, at 40% and at 100% relative humidity. The end products were examined by reflected-light microscopy and by X-ray diffraction. The degree of reaction appears to depend upon the amount of FeCl2, the availability of water and the Ni content of the metallic Fe. The experiments showed the extremely rapid rate at which the oxyhydration can occur in air and that the product is beta-FeOOH. The data from the FeOOH mineral in rock 66095 were compared with those obtained from synthetic beta-FeOOH and found to be identical. The 'rust' in the Apollo 16 rocks could result from oxyhydration of the samples, caused by water vapor contamination, all or part of which occurred in the Apollo spacecraft and/or upon return to earth. The akageneite (beta-FeOOH) in lunar rocks could be entirely of terrestrial origin as originally suggested by Taylor et al. (1973).
Taylor, L. A.↗
X-ray diffraction identification of minerals in lunar regolith returned by Luna 16 automatic station
The methods of powder and monocrystal X-ray diffraction served in identifying the mineral composition of gross samples of regolith from different levels of the drill core and about 80 individual regolith particles returned by the Luna 16 station. It was established that the Sea of Fertility regolith includes pyroxenes of the augite-pigeonite series, anorthites, ilmenite, olivines, spinels, alpha cristobalite, iron particles, glass, and several as yet unidentified particles. Crystallographic and roentgenometric data are given for all the lunar minerals found.
Makarov, Y. S.↗
Evaluation of zirconia, thoria and zirconium diboride for advanced resistojet use
A literature survey was conducted to collect material properties data on all advanced high temperature materials. Three of these, Y2O3-stabilized ZrO2, ThO2, and ZrB2 with additives of C and SiC were selected for further study. Stabilized ZrO2 and ThO2 were found to have higher temperature oxidation resistance than any metal and great potential for use in advanced biowaste resistojets. ZrO2 has a lower electrical resistivity and sublimation and a higher creep endurance strength. ZrO2 and ThO2 tubular heat exchangers, electrically heated indirectly, were evaluated in short tests to about 1900 K in flowing CO2. ZrO2 was subjected to N2, H2, H2O and vacuum as well. X-ray diffraction and fluorescence analyses were made. The metal-to-ceramic seal technology for ZrO2 and ThO2 was developed using chemical vapor deposition of tantalum for metallizing and 82 Au - 18 Ni filler braze.
Page, R. J.↗