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Boese, R. W.

Publications and source records attributed to Boese, R. W..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Net thermal radiation in the atmosphere of Venus

Estimates of the true atmospheric net fluxes at the four Pioneer Venus entry sites are presently obtained through corrections of measured values that are relatively small for the case of the clouds, but generally large deeper in the atmosphere. The correction procedure for both the small and large probe fluxes used model results near 14 km to establish the size of the correction. The thermal net fluxes obtained imply that the contribution of mode 3 particles to the IR opacity of the middle and lower clouds is smaller than indicated by the Pioneer Venus cloud particle spectrometer measurements, and the day probe results favor a reduction of only about 50 percent. The fluxes at all sites imply that a yet-undetermined source of considerable opacity is present in the upper cloud. Beneath the clouds, the thermal net fluxes generally increase with increasing latitude.

Revercomb, H. E.↗
NASA NTRS1985

Thermal net flux measurements on the Pioneer Venus entry probes

Corrected thermal net (upward minus downward flux) radiation data from four Pioneer Venus probes at latitudes of 4 deg and 60 deg N, and 27 deg and 31 deg S, are presented. Comparisons of these fluxes with radiative transfer calculations were interpreted in terms of cloud properties and the global distribution of water vapor in the lower atmosphere of Venus. The presence of an as yet undetected source of IR opacity is implied by the fluxes in the upper cloud range. It was also shown that beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and a decrease of the water vapor mixing ratios toward the equator.

Revercomb, H. E.↗
NASA NTRS1985

Net Thermal Radiation in the Atmosphere of Venus

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60 deg N, 31 deg S, 27 deg S, and 4 deg N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found. The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested, but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2-5 x 10(exp -5) near 60 deg, 2-5 x 10(exp -4) near 30 deg, and greater than 5 x 10(exp -4) near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.

Sromovsky, L. A.↗
NASA NTRS1985

Net Thermal Radiation in the Atmosphere of Venus

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60 deg. N, 31 deg. S, 27 deg. S, and 4 deg. N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus 52, 279-300). The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O.B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1964. Icarus 37, 143-160), but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds a( high latitudes and water vapor mixing ratios of about 2-5 x 10(exp -5) near 6 deg., 2-5 x 10(exp -11) near 30 deg., and less than 5 x 10(exp -4 ) near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.

Revercomb, H. E.↗
NASA NTRS1982

Gaseous infrared absorption in the lower atmosphere of Venus

Possibly important sources of infrared opacity in the Venusian atmosphere was identified. It is shown that which is the major atmospheric constituent comprising about 97 percent of the atmosphere, is the dominant infrared opacity source. Not shown is N2 which comprises about 3 percent of the atmosphere. The mixing ratio of water vapor varies considerably with altitude but falls in the range of about 20 to 200 parts per million (ppm). The mixing ratio of SO2 falls in the range of 100-200 ppm. This number is about 5000 times larger than estimates obtained earlier via Earth-based observations. The abundance of some of the other minor constituents is also shown.

Chackerian, C., Jr.↗
NASA NTRS1981

Intensity of the hydrogen peroxide v6/b/ band around 1266 cm

Laboratory spectra of the V6(b) band of H2O2 at 1266/cm have been obtained at a resolution of 0.06/cm and at temperatures ranging from 278 to 294 K. A total band intensity of 375 + or - 17 per sq cm per amagat is determined from the spectra. Special techniques to handle the H2O2 samples in a way that minimizes abundance determination errors are discussed.

Valero, F. P. J.↗
NASA NTRS1981

The use of intermolecular potential functions in fitting pressure induced spectra

An example is presented which demonstrates the importance of using physically realistic derivatives of the intermolecular potential when fitting pressure-induced spectra. The use of nonrealistic derivatives may mask second-order temperature effects in the theory. As the temperature decreases, the intermolecular potential may have an important angular dependence.

Goorvitch, D.↗
NASA NTRS1981

Investigation of the 2-0 pressure-induced vibrational absorption spectrum of hydrogen at temperatures below ambient

A theoretical fit has been made to our laboratory measurements of the 2-0 collisionally induced H2 absorption band for temperatures of 122 and 273.3 K and at a density of 20 amagats. A Lennard-Jones 6-12 intermolecular potential and a Birnbaum-Cohen line profile have been used. The fit resulted in a chi-square of 0.2%. Line widths have also been derived as a function of temperature. The lifetimes of the states have been calculated.

Silvaggio, P. M.↗
NASA NTRS1981

Investigation of the 1-0 pressure-induced vibrational absorption spectrum of hydrogen at temperatures below ambient

A theoretical fit has been made to laboratory measurements of the 1-0 collisionally induced H2 absorption band over a temperature range of 100-273 K and for densities up to 22 amagats. Both the Birnbaum-Cohen and the MacTaggert-Hunt line shape profiles were used. In addition, an intermolecular potential of either a Lennard-Jones 6-12 or a Morse-spline-van der Waals has been used for each line shape. The best fit resulted in a chi-square of 5%. Line widths have also been derived as a function of temperature. The lifetimes of the states were calculated.

Goorvitch, D.↗
NASA NTRS1981

Temperature dependence of HNO3 absorption in the 11.3-micron region

Laboratory spectra have been obtained for HNO3 with a Michelson-type Fourier transform interferometer using absorption cells with path lengths of 10.3, 25.5, and 49.8 cm at temperatures of 240, 248, 283, and 294 K. The measurements lead to a total band intensity value of 642 plus or minus 5% per sq cm amagat, which is a temperature independent value after the gas density correction has been made. However, the temperature dependence of the spectral absorption coefficients is apparent in the 885 kayser region.

Goldman, A.↗
NASA NTRS1980

Integrated band intensities of gaseous N/2/O/5/

Values for mid-IR integrated band intensities of gaseous N2O5 were determined at room temperature. The absorptions studied were at 1720, 1246, 743, and 557/cm. The integrated intensities were 2204, 581, 685, and 699/atm cm, respectively. Implications of these results for the stratospheric detection of N(2)O(5) are discussed.

Lovejoy, R. W.↗
NASA NTRS1980

Temperature dependence of intensities of the 8-12 micron bands of CFCl3

The absolute intensities of the 8-12 micron bands from Freon 11 (CFCl3) were measured at temperatures of 294 and 216 K. Intensities of the bands centered at 798, 847, 934, and 1082 per cm are all observed to depend on temperature. The temperature dependence for the 847 and 1082 per cm fundamental regions is attributed to underlying hot bands; for the nu2 + nu5 combination band (934 per cm), the observed temperature dependence is in close agreement with theoretical prediction. The implication of these results on atmospheric IR remote-sensing is briefly discussed.

Nanes, R.↗
NASA NTRS1980

Band model calculations for CFCl3 in the 8-12 micron region

A Goody random band model with a Voigt line profile is used to calculate the band absorption of CFCl3 at various pressures at room and stratospheric (216 K) temperatures. Absorption coefficients and line spacings are computed.

Silvaggio, P. M.↗
NASA NTRS1980

The infrared radiometer on the sounder probe of the Pioneer Venus mission

The functional aspects of the Large Probe Infrared Radiometer Instrument are presented taking into account the experiment's objective to measure the net thermal flux as the Venus Probe descended into the planet's atmosphere, as well as to detect water vapor, cloud layers and their infrared opacity. The optical elements, including the detectors are described and a brief review of the instrument's calibration is given.

Boese, R. W.↗
NASA NTRS1979

Infrared methane spectra between 1120 per cm and 1800 per cm - A new atlas

A new atlas of CH4 lines in the 1120-1800-per cm region has been generated, based on laboratory spectra taken with a Nicolet interferometer at 0.06-per cm resolution with 635-cm path length at pressures of 0.98 torr, 4.86 torr, and 19.97 torr. A compilation of line positions and line intensities includes 1339 CH4 lines, several hundred of which have not been previously observed.

Blatherwick, R. D.↗