Intensities and half-widths at different temperatures for the 201/III/ - 000 band of CO2 at 4854 per cm
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Engineering topics
Publications and source records attributed to Boese, R. W..
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During the descent to the surface of Venus, the large probe infrared radiometer measured the net thermal radiative flux in several spectral bandpasses. Preliminary analysis has permitted us to estimate (1) the infrared extinction coefficient profile attributable to aerosols, with respect to their visible profile, in the upper atmosphere of Venus and (2) the water vapor mixing ratio below the clouds. An indication of the composition of a multicomponent cloud is seen in the data from the spectral bandpass from 6 to 7 micrometers.
Because of the controversy over the value of the band strength for the nu-4 fundamental of CH4, equivalent widths of the R(0), R(1), and P(11, 11, F1) lines have been measured to compare with opposing views. The present measurements are consistent with the band strength of Ko and Varanasi (1977), who, on the basis of high-resolution line-strength measurements, propose an integrated band strength of 145 kaysers/(cm-am).
An atlas of 1339 methane absorption lines in the range 1120 to 1800 reciprocal centimeters, including the nu(4) and nu(2) bands, is presented. Laboratory spectra were obtained by a Nicolet Fourier transform Michelson interferometer with a resolution of approximately 0.06 reciprocal cm and a path length of 6.35 m of 0.98, 4.86 and 19.97 torr. Observed spectra are also compared with spectral intensities calculated line-by-line on the basis of tabulated intensities of the observed spectral lines.
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The LIR (large probe infrared radiometer) instrument has been developed for the NASA Ames Research Center for use in the 1978 Venus Atmospheric Probe Mission. The mission objectives are to determine the nature and composition of the clouds, the composition and structure of the atmosphere, and the atmospheric circulation pattern of the planet Venus. The LIR is a six-channel (3-50 micron) internally calibrated radiometer which measures the radiance difference at plus or minus 45 deg to the horizontal as viewed through a single diamond window in the spacecraft. The LIR optical system consists of a unique arrangement of hollow light pipes which optically couple a six element detector/filter array to the spacecraft window while mechanically and thermally isolating the array from the window's harsh thermal environment. A single rotating section with a 45 deg bend and containing a collimator alternately views up and down through director/extender pipes located adjacent to the diamond window. Light is transferred from the rotating section to a fixed section containing a diamond diffuser to scramble the light. This minimizes asymmetries and improves channel field of view overlap.
Line intensities for the P sub P and P sub Q branches of the (2-O) vibrational band of the magnetic dipole electronic transition for the oxygen red system at 6280 A were measured, and the sum of the R sub R and R sub Q branch intensities was taken. A large number of repetitive spectral scans were required for accuracy, because of low absorption values even at optical path lengths from 300 to 600 m. A total of 557 individual measurements of P-branch lines yielded an intensity value for the P-branches, and equivalent widths for 24 spectral scans yielded an intensity value for the R-branch. R-branch to P-branch intensity ratios were taken for the A-band, B-band, and gamma-band (respectively, O-O at 7620 A, 1-O at 6880 A, and 2-O at 6280 A). Intensities for some rotational lines are found, and effects of combined rotation-vibration interaction are probed.
A complete atlas of the 5 nu-1 absorption band of NH3 is presented together with measurements of the total band intensity, line intensities, and self-broadening coefficients. The spectrum, which is displayed in the interval from 6418 to 6550 A, was obtained photoelectrically at a pressure of 0.061 atm, and many more lines were seen in this spectrum than in a previous one obtained at a pressure of 0.39 atm. The band intensity is used to derive the NH3 abundance in the atmospheres of Jupiter and Saturn, and the abundances in a single vertical path are found to be about 10 m amagat for Jupiter and 2 m amagat for Saturn. These results are shown to be in agreement with previous results obtained from higher resolution photographic spectra.
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Comments on Hunt's (1972) conclusion that the phase variation of lines in the 7820- and 7883-A CO2 bands is due to the presence of two scattering layers in the Venusian atmosphere. It is shown that the increase of equivalent width with phase between 0 and 90 deg noted by Hunt in the data by Gray Young et al. (1971) does not necessarily require a two-layer model of scattering in the Venusian atmosphere and that this increase may be due to the strong backward lobe in the Venusian cloud phase function. Hunt, in a reply, notes that Regas et al. incorrectly use in their analysis Hansen's (1969) data which are for a homogeneous planetary atmosphere, while Hunt used an inhomogeneous model of the Venusian atmosphere. In addition, further evidence to support Hunt's claim for a multilayered structure of the upper Venusian clouds is presented.
The synthetic-spectrum technique was used in the analysis. The synthetic spectra were constructed with a model which takes into account both isotropic scattering and the inhomogeneity in the Venus atmosphere. The Potter-Hansen correction factor was used to correct for anisotropic scattering. The synthetic spectra obtained are, therefore, the first which contain all the essential physics of line formation. The results confirm Potter's conclusion that the Venus cloud tops resemble terrestrial cirrus or stratus clouds in their scattering properties.
Atmospheric oxygen A band individual rotational lines intensities and half widths measurements
Ammonia red and green bands measured line positions, strengths and half widths applied to Jupiter atmospheric pressure determination
Martian carbon dioxide abundance from spectral scan measurements using solar telescope
Carbon dioxide tetrad band line intensity and widths quantitative measurements, considering agreement with Boltzmann distribution