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Chen, Cheng

Publications and source records attributed to Chen, Cheng.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Influence of Clay Wettability Alteration on Relative Permeability

Abstract Understanding the wettability of porous materials is important to model fluid flow in the subsurface. One of the critical factors that influences wetting in real reservoirs is the composition of geologic materials. The wetting properties for clay minerals can have a particularly strong impact on flow and transport. In this work, we analyze the chemical composition of a Mt. Simon sandstone core to resolve the microscopic structure of clay regions and assess how alterations to the local wetting properties influence multiphase transport based on core flooding experiments and relative permeability simulations. We show that whichever fluid has greater affinity toward clay minerals will tend to accumulate within these high surface area regions, leading to dramatic shifts in the relative permeability. This work establishes the essential importance of the mineral composition and associated wetting properties in the modeling of flow and transport in reservoir‐scale systems.

Fan, Ming↗
DOE OSTI2020

The electrolyte comprising more robust water and superhalides transforms Zn-metal anode reversibly and dendrite-free

A great challenge for all aqueous batteries, including Zn-metal batteries, is the parasitic hydrogen evolution reaction on the low-potential anode. Herein, we report the formula of a highly concentrated aqueous electrolyte that mitigates hydrogen evolution by transforming water molecules more inert. The electrolyte comprises primarily ZnCl 2 and LiCl as an additive, both of which are inexpensive salts. The O–H covalent bonds in water get strengthened in a chemical environment that has fewer hydrogen bonding interactions and a greater number of Zn–Cl superhalides, as suggested by integrated characterization and simulation. As a result, the average Coulombic efficiency of zinc-metal anode is raised to an unprecedented >99.7% at 1 mA cm –2 . In the new electrolyte, the plating/stripping processes leave the zinc-metal anode dendrite-free, and the zinc-metal anode delivers stable plating/stripping cycles for 4000 hours with an areal capacity of 4 mAh cm –2 at 2 mA cm –2 . Furthermore, the high Coulombic efficiency of zinc-metal anode in the ZnCl 2 -LiCl mixture electrolyte is demonstrated in full cells with a limited anode. The V 2 O 5 ·H 2 O| |Zn full cell with an N/P mass ratio of 1.2 delivers a stable life of more than 2500 cycles, and the LiMn 2 O 4 | |Zn hybrid cell with an N/P mass ratio of 0.6 exhibits 1500 cycles in its stable life.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Electronic structure of the Si-containing topological Dirac semimetal CaAl 2 Si 2

There has been an upsurge in the discovery of topological quantum materials, where various topological insulators and semimetals have been theoretically predicted and experimentally observed. However, very few of them contain silicon, the most widely used element in the electronics industry. Recently, ternary compound CaA l 2 S i 2 has been predicted to be a topological Dirac semimetal, hosting Lorentz-symmetry-violating quasiparticles with a strongly tilted conical band dispersion. In this work, by using high-resolution angle-resolved photoemission spectroscopy, we investigated the comprehensive electronic structure of CaA l 2 S i 2 . A pair of topological Dirac crossings is observed along the k z direction, in good agreement with the ab initio calculations, confirming the topological Dirac semimetal nature of the compound. Our study expands the topological material family on Si-containing compounds, which have great application potential in realizing low-cost, nontoxic electronic devices with topological quantum states.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Zero-energy bound states in the high-temperature superconductors at the two-dimensional limit

Majorana zero modes (MZMs) that obey the non-Abelian statistics have been intensively investigated for potential applications in topological quantum computing. The prevailing signals in tunneling experiments “fingerprinting” the existence of MZMs are the zero-energy bound states (ZEBSs). However, nearly all of the previously reported ZEBSs showing signatures of the MZMs are observed in difficult-to-fabricate heterostructures at very low temperatures and additionally require applied magnetic field. Here, by using in situ scanning tunneling spectroscopy, we detect the ZEBSs upon the interstitial Fe adatoms deposited on two different high-temperature superconducting one-unit-cell iron chalcogenides on SrTiO 3 (001). The spectroscopic results resemble the phenomenological characteristics of the MZMs inside the vortex cores of topological superconductors. Our experimental findings may extend the MZM explorations in connate topological superconductors toward an applicable temperature regime and down to the two-dimensional (2D) limit.

Science & Technology - Other Topics↗
DOE OSTI2019

Comprehensive study of the interactions between the critical dimensionless numbers associated with multiphase flow in 3D porous media

Multiphase flow in porous media is of signifcant interest in many engineering applications, such as geologic carbon sequestration, enhanced oil recovery, and groundwater contamination and remediation. In order to advance the fundamental understanding of multiphase flow in complex three-dimensional (3D) porous media, the interactions between the critical dimensionless numbers, including the contact angle, viscosity ratio, and capillary (Ca) number, were explored using X-ray micro-computed tomography (micro-CT) scanning and lattice Boltzmann (LB) modeling. In this study, the 3D pore structure information was extracted from micro-CT images and then used as interior boundary conditions of flow modeling in a pore-scale LB simulator to simulate multiphase flow within the pore space. A Berea sandstone sample was scanned and then two-phase flow LB simulations were performed based on the micro-CT images. The LB-simulated water/CO 2 distributions agreed well with the micro-CT scanned images. Simulation findings showed that a decreasing contact angle causes a decrease in wetting-fluid relative permeability and an increase in non-wetting fluid relative permeability. A rising Ca number increases both wetting and non-wetting fluid relative permeabilities. An increasing viscosity ratio (the ratio of non-wetting fluid viscosity to wetting fluid viscosity) facilitates the increase of non-wetting fluid relative permeability and mitigates the reduction of wetting fluid relative permeability, when the contact angle decreases continuously. The primary novel finding of this study is that the viscosity ratio affects the rate of change of the relative permeability curves for both phases when the contact angle changes continuously. To date, we believe it is the first time that comprehensive interactions between these dimensionless numbers are demonstrated in a sandstone sample based on real 3D structures. We also investigated the role of the changes of flow direction and sample location on relative permeability curves. Simulation results showed that the change in non-wetting fluid relative permeability was larger when the flow direction was switched from vertical to horizontal, which indicated that there was stronger anisotropy in larger pore networks that were primarily occupied by the non-wetting fluid.

42 ENGINEERING↗
DOE OSTI2019

ARC3 Activation by PARC6 Promotes FtsZ-Ring Remodeling at the Chloroplast Division Site

Chloroplast division is initiated by assembly of the stromal Z ring, composed of cytoskeletal Filamenting temperature-sensitive Z (FtsZ) proteins. Midplastid Z-ring positioning is governed by the chloroplast Min (Minicell) system, which inhibits Z-ring assembly everywhere except the division site. The central Min-system player is the FtsZ-assembly inhibitor ACCUMULATION AND REPLICATION OF CHLOROPLASTS3 (ARC3). Here, we report Arabidopsis (Arabidopsis thaliana) chloroplasts contain two pools of ARC3: one distributed throughout the stroma, which presumably fully inhibits Z-ring assembly at nondivision sites, and the other localized to a midplastid ring-like structure. We show that ARC3 is recruited to the middle of the plastid by the inner envelope membrane protein PARALOG OF ARC6 (PARC6). ARC3 bears a C-terminal Membrane Occupation and Recognition Nexus (MORN) domain; previous yeast two-hybrid experiments with full-length and MORN-truncated ARC3 showed the MORN domain mediates ARC3-PARC6 interaction but prevents ARC3-FtsZ interaction. Using yeast three-hybrid experiments, we demonstrate that the MORN-dependent ARC3-PARC6 interaction enables full-length ARC3 to bind FtsZ. The resulting PARC6/ARC3/FtsZ complex enhances the dynamics of Z rings reconstituted in a heterologous system. In conclusion, our findings lead to a model whereby activation of midplastid-localized ARC3 by PARC6 facilitates Z-ring remodeling during chloroplast division by promoting Z-ring dynamics and reveal a novel function for MORN domains in regulating protein–protein interactions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

Late Delivery of Nitrogen to the Earth

Atmospheric nitrogen may be a necessary ingredient for the habitability of a planet as its presence helps to prevent water loss from a planet. The present-day nitrogen isotopic ratio, {sup 15}N/{sup 14}N, in the Earth’s atmosphere is a combination of the primitive Earth’s ratio and the ratio that might have been delivered in comets and asteroids. Asteroids have a nitrogen isotopic ratio that is close to the Earth’s. This indicates either a similar formation environment to the Earth or that the main source of nitrogen was delivery by asteroids. However, according to geological records, the Earth’s atmosphere could have been enriched in {sup 15}N during the Archean era. Comets have a higher {sup 15}N/{sup 14}N ratio than the current atmosphere of the Earth, and we find that about 5% ∼ 10% of nitrogen in the atmosphere of the Earth may have been delivered by comets to explain the current atmosphere of the Earth or the enriched {sup 15}N atmosphere of the Earth. We model the evolution of the radii of the snow lines of molecular nitrogen and ammonia in a protoplanetary disk and find that both have radii that put them farther from the Sun than the main asteroid belt. With an analytic secular resonance model and N-body simulations we find that the ν {sub 8} apsidal precession secular resonance with Neptune, which is located in the Kuiper Belt, is a likely origin for the nitrogen-delivering comets that impact the Earth.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Microwave-assistant hydrothermal synthesis of SnO2@ZnO hierarchical nanostructures enhanced photocatalytic performance under visible light irradiation

Highlights: • A photocatalyst of SnO{sub 2}@ZnO HNSs is prepared via a microwave-assistant hydrothermal method. • Enhanced photodegradation of methylene blue under the visible light irradiation has been observed. • The defect in photocatalyst is the main photocatalytic mechanism under the visible light irradiation. • The superoxide radical is the main photoactive species. - Abstract: In this paper, for the first time, SnO{sub 2}@ZnO hierarchical nanostructures (HNSs) were synthesized by a simple two-step microwave-assistant hydrothermal method. Systematical characterization of the SnO{sub 2}@ZnO HNSs revealed that the rutile SnO{sub 2} nanowires (NWs) were uniformly and tightly grown on the entire surface of each ZnO nanoflowers (NFs). The photocatalytic performance of the SnO{sub 2}@ZnO HNSs showed a remarkably enhanced photocatalytic performance under visible light irradiation (400 nm≤λ ≤ 800 nm). The photoluminescence (PL) spectrum results indicated that the defect related energy level is the main mechanism of the photocatalytic performance under the visible light irradiation. The unique morphology and heterojunction structures in SnO{sub 2}@ZnO HNSs were the core enhanced mechanism in photodegradation process. The advantage endowed with the microwave-assistant hydrothermal method can result in the efficient spatial charge separation between ZnO nanorods (NRs) and SnO{sub 2} NWs and reduce the charge recombination along the heterojunction, which makes SnO{sub 2}@ZnO HNSs a highly promising for photocatalytic applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗