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Chung, Serena H.

Publications and source records attributed to Chung, Serena H..

Chapter 22 - Pathways Toward Sustainable Development

Model-based scenario analysis can help in identifying ways to achieve the environmental targets of the Sustainable Development Goals (SDGs) and related multilateral environmental agreements (MEAs) (well established). Target-seeking scenarios provide insight into the required level of effort, promising measures, and possible synergies and trade-offs between these measures and a range of targets. The usefulness of scenarios can be illustrated by the successful use of such scenarios in the literature on climate policy. Scenarios can be used to explore different pathways for achieving long-term targets and provide insights into the costs and benefits of these pathways. There are important interrelations (synergies and trade-offs) between the achievement of the various SDGs and related MEAs.. This means that strategies that aim to achieve sets of targets will have to take account for these interrelations. At the moment, scenarios that explore the fulfilment of a large set of SDG targets simultaneously are mostly lacking. An assessment of possible pathways must therefore rely on more narrowly focused scenarios in the literature. This does lead to a higher level of uncertainty and some clear knowledge gaps. {22.2}

Van Vuuren, Detlef↗

Chapter 21 - Future Developments Without Targeted Policies

Together with other tools, model-based scenario analysis provides a useful method to explore whether environment related targets of the Sustainable Development Goals (SDGs) and related Multilateral Environmental Agreements (MEAs) are going to be achieved (well established). Assessing whether current trends are leading to fulfilment of the selected targets outlined in Chapter 20 is complex: it requires insights into the interactions of different trends and systems, inertia and cross-scale relationships. A combination of qualitative storylines and quantitative scenario tools can help to explore possible futures trends, while taking the many complexities into account. While scenarios can never be forecasts, because surprises may occur, they can inform decision makers of the likely implications of current trends. {21.2}

Lucas, Paul↗

Modelling bidirectional fluxes of methanol and acetaldehyde with the FORCAsT canopy exchange model

Here, the FORCAsT canopy exchange model was used to investigate the underlying mechanisms governing foliage emissions of methanol and acetaldehyde, two short chain oxygenated volatile organic compounds ubiquitous in the troposphere and known to have strong biogenic sources, at a northern mid-latitude forest site. The explicit representation of the vegetation canopy within the model allowed us to test the hypothesis that stomatal conductance regulates emissions of these compounds to an extent that its influence is observable at the ecosystem scale, a process not currently considered in regional- or global-scale atmospheric chemistry models. Here, we found that FORCAsT could only reproduce the magnitude and diurnal profiles of methanol and acetaldehyde fluxes measured at the top of the forest canopy at Harvard Forest if light-dependent emissions were introduced to the model. With the inclusion of such emissions, FORCAsT was able to successfully simulate the observed bidirectional exchange of methanol and acetaldehyde. Although we found evidence that stomatal conductance influences methanol fluxes and concentrations at scales beyond the leaf level, particularly at dawn and dusk, we were able to adequately capture ecosystem exchange without the addition of stomatal control to the standard parameterisations of foliage emissions, suggesting that ecosystem fluxes can be well enough represented by the emissions models currently used.

99 GENERAL AND MISCELLANEOUS↗

Climate Response of Direct Radiative Forcing of Anthropogenic Black Carbon

The equilibrium climate effect of direct radiative forcing of anthropogenic black carbon (BC) is examined by 100-year simulations in the Goddard Institute for Space Studies General Circulation Model II-prime coupled to a mixed-layer ocean model. Anthropogenic BC is predicted to raise globally and annually averaged equilibrium surface air temperature by 0.20 K if BC is assumed to be externally mixed. The predicted increase is significantly greater in the Northern Hemisphere (0.29 K) than in the Southern Hemisphere (0.11 K). If BC is assumed to be internally mixed with the present day level of sulfate aerosol, the predicted annual mean surface temperature increase rises to 0.37 K globally, 0.54 K for the Northern Hemisphere, and 0.20 K for the Southern Hemisphere. The climate sensitivity of BC direct radiative forcing is calculated to be 0.6 K W (sup -1) square meters, which is about 70% of that of CO2, independent of the assumption of BC mixing state. The largest surface temperature response occurs over the northern high latitudes during winter and early spring. In the tropics and midlatitudes, the largest temperature increase is predicted to occur in the upper troposphere. Direct radiative forcing of anthropogenic BC is also predicted to lead to a change of precipitation patterns in the tropics; precipitation is predicted to increase between 0 and 20 N and decrease between 0 and 20 S, shifting the intertropical convergence zone northward. If BC is assumed to be internally mixed with sulfate instead of externally mixed, the change in precipitation pattern is enhanced. The change in precipitation pattern is not predicted to alter the global burden of BC significantly because the change occurs predominantly in regions removed from BC sources.

Chung, Serena H.↗

Electron Tomography of Nanoparticle Clusters: Implications for Atmospheric Lifetimes and Radiative Forcing of Soot

Nanoparticles are ubiquitous in nature. Their large surface areas and consequent chemical reactivity typically result in their aggregation into clusters. Their chemical and physical properties depend on cluster shapes, which are commonly complex and unknown. This is the first application of electron tomography with a transmission electron microscope to quantitatively determine the three-dimensional (3D) shapes, volumes, and surface areas of nanoparticle clusters. We use soot (black carbon, BC) nanoparticles as an example because it is a major contributor to environmental degradation and global climate change. To the extent that our samples are representative, we find that quantitative measurements of soot surface areas and volumes derived from electron tomograms differ from geometrically derived values by, respectively, almost one and two orders of magnitude. Global sensitivity studies suggest that the global burden and direct radiative forcing of fractal BC are only about 60% of the value if it is assumed that BC has a spherical shape.

vanPoppel, Laura H.↗