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England, C.

Publications and source records attributed to England, C..

Minimizing Launch Mass for ISRU Processes

The University of Dayton and the Jet Propulsion Laboratory are developing a methodology for estimating the Earth launch mass (ELM) of processes for In-Situ Resource Utilization (ISRU) with a focus on lunar resource recovery. ISRU may be enabling for both an extended presence on the Moon, and for large sample return missions and for a human presence on Mars. To accomplish these exploration goals, the resources recovered by ISRU must offset the ELM for the recovery process. An appropriate figure of merit is the cost of the exploration mission, which is closely related to ELM. For a given production rate and resource concentration, the lowest ELM - and the best ISRU process - is achieved by minimizing capital equipment for both the ISRU process and energy production. ISRU processes incur Carnot limitations and second law losses (irreversibilities) that ultimately determine production rate, material utilization and energy efficiencies. Heat transfer, chemical reaction, and mechanical operations affect the ELM in ways that are best understood by examining the process's detailed energetics. Schemes for chemical and thermal processing that do not incorporate an understanding of second law losses will be incompletely understood. Our team is developing a methodology that will aid design and selection of ISRU processes by identifying the impact of thermodynamic losses on ELM. The methodology includes mechanical, thermal and chemical operations, and, when completed, will provide a procedure and rationale for optimizing their design and minimizing their cost. The technique for optimizing ISRU with respect to ELM draws from work of England and Funk that relates the cost of endothermic processes to their second law efficiencies. Our team joins their approach for recovering resources by chemical processing with analysis of thermal and mechanical operations in space. Commercial firms provide cost inputs for ELM and planetary landing. Additional information is included in the original extended abstract.

England, C.↗

Extraction of Oxygen from the Martian Atmosphere

A mechanical process was designed for direct extraction of molecular oxygen from the martian atmosphere based on liquefaction of the majority component, CO2, followed by separation of the lower-boiling components. The atmospheric gases are compressed from about 0.007 bar to 13 bar and then cooled to liquefy most of the CO2. The uncondensed gases are further compressed to 30 bar or more, and then cooled again to recover water as ice and to remove much of the remaining CO2. The final gaseous products consisting mostly of nitrogen, oxygen, and carbon monoxide are liquefied and purified by cryogenic distillation. The liquefied CO2 is expanded back to the low-pressure atmosphere with the addition of heat to recover a majority of the compression energy and to produce the needed mechanical work. Energy for the process is needed primarily as heat to drive the CO2-based expansion power system. When properly configured, the extraction process can be a net producer of electricity. The conceptual design, termed 'MARRS' for Mars Atmosphere Resource Recovery System, was based on the NASA/JSC Mars Reference Mission (MRM) requirement for oxygen. This mission requires both liquid oxygen for propellant, and gaseous oxygen as a component of air for the mission crew. With single redundancy both for propellant and crew air, the oxygen requirement for the MRM is estimated at 5.8 kg/hr. The process thermal power needed is about 120 kW, which can be provided at 300-500 C. A lower-cost nuclear reactor made largely of stainless steel could serve as the heat source. The chief development needed for MARRS is an efficient atmospheric compression technology, all other steps being derived from conventional chemical engineering separations. The conceptual design describes an exceptionally low-mass compression system that can be made from ultra-lightweight and deployable structures. This system adapts to the rapidly changing martian environment to supply the atmospheric resource to MARRS at constant conditions.

England, C.↗

NEMS for space and terrestrial applications

Nanoscale electromechanical systems (NEMS) techniques were used to manufacture a membrane used to supply singly charged un-fractured ions for mass spectrometry. The innovative nanostructure, developed at the Jet Propulsion Laboratory (JPL), is a major advance over micromachined 'volcano' field ionization devices and filaments or other energy-intensive devices, achieving nearly 100% ionization of gases and vapors without appreciable fracture.

Nanoscale electromechanical systems NEMS soft ioni↗

Martian Surface Boundary Layer Characterization: Enabling Environmental Data for Science, Engineering and Human Exploration

For human or large robotic exploration of Mars, engineering devices such as power sources will be utilized that interact closely with the Martian environment. Heat sources for power production, for example, will use the low ambient temperature for efficient heat rejection. The Martian ambient, however, is highly variable, and will have a first order influence on the efficiency and operation of all large-scale equipment. Diurnal changes in temperature, for example, can vary the theoretical efficiency of power production by 15% and affect the choice of equipment, working fluids, and operating parameters. As part of the Mars Exploration program, missions must acquire the environmental data needed for design, operation and maintenance of engineering equipment including the transportation devices. The information should focus on the variability of the environment, and on the differences among locations including latitudes, altitudes, and seasons. This paper outlines some of the WHY's, WHAT's and WHERE's of the needed data, as well as some examples of how this data will be used. Environmental data for engineering design should be considered a priority in Mars Exploration planning. The Mars Thermal Environment Radiator Characterization (MTERC), and Dust Accumulation and Removal Technology (DART) experiments planned for early Mars landers are examples of information needed for even small robotic missions. Large missions will require proportionately more accurate data that encompass larger samples of the Martian surface conditions. In achieving this goal, the Mars Exploration program will also acquire primary data needed for understanding Martian weather, surface evolution, and ground-atmosphere interrelationships.

England, C.↗

Isothermal separation processes

The isothermal processes of membrane separation, supercritical extraction and chromatography were examined using availability analysis. The general approach was to derive equations that identified where energy is consumed in these processes and how they compare with conventional separation methods. These separation methods are characterized by pure work inputs, chiefly in the form of a pressure drop which supplies the required energy. Equations were derived for the energy requirement in terms of regular solution theory. This approach is believed to accurately predict the work of separation in terms of the heat of solution and the entropy of mixing. It can form the basis of a convenient calculation method for optimizing membrane and solvent properties for particular applications. Calculations were made on the energy requirements for a membrane process separating air into its components.

England, C.↗

A New Use for High-Sulfur Coal

New process recovers some of economic value of high-sulfur coal. Although high-sulfur content is undesirable in most coal-utilization schemes (such as simple burning), proposed process prefers high-sulfur coal to produce electrical power or hydrogen. Potential exists for widespread application in energy industry.

Lawson, D. D.↗

Superconductivity, cohesive energy density, and electron-atom ratio in metals

It is shown that superconductivity above 8 K occurs in alloys and metallic compounds within relatively narrow regions of cohesive energy density with a sharp peak which includes Nb3Ge, SiV3, Nb3Ga, and NbN. When cross-correlated with the electron-atom ratio, high-temperature superconductivity can be observed in only a few regions. This suggests a search for superconductors with high-transition temperatures and critical fields within these regions.

England, C.↗

Reduced product yield in chemical processes by second law effects

An analysis of second law effects in chemical processes, where product yield is explicitly related to the individual irreversibilities within the process to indicate a maximum theoretical yield, is presented. Examples are given that indicate differences between first and second law approaches toward process efficiency and process yield. This analysis also expresses production capacity in terms of the heating value of a product. As a result, it is particularly convenient in analyzing fuel conversion plants and their potential for improvement. Relationships are also given for the effects of irreversibilities on requirements for process heat and for feedstocks.

England, C.↗

Continuous extrusion of coal

A feeding method for use with bituminous coals that exhibit plasticity at elevated temperatures is described and demonstrated on a small screw extruder previously used to extrude polyethylene. A metered feed of coal heated to a temperature just below that of incipient caking (approximately 450 C) is used. Modifications to the extruder consisting of ceramic band heaters, auxiliary cooling coils on the thrust bearing and special quick opening dies are detailed. Coals successfully extruded include high volatile A bituminous coals, high volatile B bituminous coals, a high volatile C bituminous coal and a coal with high ash content. The computer program, EXTRUD, used to simulate the extruder is described. Predicted power consumption exhibits 30% scatter, which is explained by the sensitivity of the coal friction coefficient to temperature profiles. Detailed analysis reveals some discrepancies in the program that need to be resolved.

England, C.↗

New method of feeding coal - Continuous extrusion of fully plastic coal

Continuous feeding of coal in a compressing screw extruder is described as a method of introducing coal into pressurized systems. The method utilizes the property of many bituminous coals of softening at temperatures from 350 to 400 C. Coal is then fed much in the manner of common thermoplastics, using screw extruders. Preliminary results show that coals can be extruded at rates of about 3.3 kg/MJ, similar to those for plastics.

Ryason, P. R.↗

Coal extrusion in the plastic state

Continuous feeding of coal in a compressing screw extruder is described as a method of introducing coal into pressurized systems. The method utilizes the property of many bituminous coals of softening at temperatures from 350 to 425 C. Coal is then fed, much in the manner of common thermoplastics, using screw extruders. Data on the viscosity and extruder parameters for extrusion of Illinois No. 6 coal are presented.

England, C.↗

Acid/alkali bromide secondary battery

Secondary electrochemical battery has been developed which has high energy/ weight density. Battery is rechargeable and works on reaction between hydrogen and bromine.

England, C.↗

Hydrogen production

The state of hydrogen production technology is evaluated. Specific areas discussed include: hydrogen production fossil fuels; coal gasification processes; electrolysis of water; thermochemical production of hydrogen; production of hydrogen by solar energy; and biological production of hydrogen. Supply options are considered along with costs of hydrogen production.

England, C.↗

Hydrogen-Bromine Secondary Battery

A secondary battery is described utilizing hydrogen and halogen as primary reactants. It comprises inert anode and cathode initially contacting an aqueous solution of an acid and an alkali metal bromide. The hydrogen generated during charging of the cell is stored as gas, while the bromine becomes dissolved predominantly in the lower layers of the acid electrolyte. Preferred components are phosphoric acid and lithium bromide.

England, C.↗

Flame stability in combusting turbulent jets

A simplified theoretical model for turbulent methane/air flames from a subscale power plant burner is developed and applied to predict the stability of flames as a function of (1) ambient atmosphere temperature and composition, (2) initial preheat temperature, and (3) percentage of external product gas recirculation. The flame model equates the rate at which mass is supplied per unit volume to the rate it is chemically reacted per unit volume using a one-step reaction and a perfectly stirred reactor (PSR). The model contains a free parameter which is evaluated by comparing the theoretical results to experimental results available in the literature. The stability results show that premixed, turbulent flames are stable over a wide equivalence ratio range if the ambient gas is air; however, if combustion products are entrained, the stability is sharply reduced.

Nelson, H. F.↗

Sampling nitric oxide from combustion gases.

Experimental study of several sampling tube and probe material compositions and designs aimed at preventing nitric oxide reduction when sampling nitric oxide from combustion gases. A 250,000 Btu/h furnace fired with technical grade methane was used for testing the sampling probes over a wide range of air-fuel mixtures. The results obtained include the finding that the use of stainless steel in probes creates inaccuracies in near-stoichiometric and fuel-rich sampling in hydrocarbon flames. For very fuel-rich flames, water cooling is needed even in quartz probes to prevent significant reduction of nitric oxide.-

England, C.↗

Fastener provides for bolt misalignment and quick release of flange

Fastener enables two large flanges to be bolted together without close alignment between the bolt and bolt-hole diameters, and provides for a quick release of one of the flanges under emergency conditions. It contains a nut that is retained by a square head in a recess in one side of the removable flange and by a collar and snap ring on the other side of the flange.

England, C.↗