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Gordley, L. L.

Publications and source records attributed to Gordley, L. L..

At least 19 records

On the Quality of the Nimbus 7 LIMS Version 6 Water Vapor Profiles and Distributions

This report describes the quality of the Nimbus 7 Limb Infrared Monitor of the Stratosphere (LIMS) water vapor (H2O) profiles of 1978/79 that were processed with a Version 6 (V6) algorithm and archived in 2002. The V6 profiles incorporate a better knowledge of the instrument attitude for the LIMS measurements along its orbits, leading to improvements for its temperature profiles and for the registration of its water vapor radiances with pressure. As a result, the LIMS V6 zonal-mean distributions of H2O exhibit better hemispheric symmetry than was the case from the original Version 5 (V5) dataset that was archived in 1982. Estimates of the precision and accuracy of the V6 H2O profiles are developed and provided. Individual profiles have a precision of order 5% and an estimated accuracy of about 19% at 3 hPa, 14% at 10 hPa, and 26% at 50 hPa. Profile segments within about 2 km of the tropopause are often affected by emissions from clouds that appear in the finite field-of-view of the detector for the LIMS H2O channel. Zonally-averaged distributions of the LIMS V6 H2O are compared with those from the more recent Microwave Limb Sounder (MLS) satellite experiment for November, February, and May of 2004/2005. The patterns and values of their respective distributions are similar in many respects. Effects of a strengthened Brewer-Dobson circulation are indicated in the MLS distributions of the recent decade versus those of LIMS from 1978/79. A tropical tape recorder signal is present in the 7-month time series of LIMS V6 H2O with lowest values in February 1979, and the estimated, annually-averaged "entry-level" H2O is 3.5 to 3.8 ppmv. It is judged that this historic LIMS water vapor dataset is of good quality for studies of the near global-scale chemistry and transport for pressure levels from 3 hPa to about 70 to 100 hPa.

Remsberg, E. E.↗

Errors in Sounding of the Atmosphere Using Broadband Emission Radiometry (SABER) Kinetic Temperature Caused by Non-Local Thermodynamic Equilibrium Model Parameters

The vast set of near global and continuous atmospheric measurements made by the SABER instrument since 2002, including daytime and nighttime kinetic temperature (T(sub k)) from 20 to 105 km, is available to the scientific community. The temperature is retrieved from SABER measurements of the atmospheric 15 micron CO2 limb emission. This emission separates from local thermodynamic equilibrium (LTE) conditions in the rarefied mesosphere and thermosphere, making it necessary to consider the CO2 vibrational state non-LTE populations in the retrieval algorithm above 70 km. Those populations depend on kinetic parameters describing the rate at which energy exchange between atmospheric molecules take place, but some of these collisional rates are not well known. We consider current uncertainties in the rates of quenching of CO2 (v2 ) by N2 , O2 and O, and the CO2 (v2 ) vibrational-vibrational exchange to estimate their impact on SABER T(sub k) for different atmospheric conditions. The T(sub k) is more sensitive to the uncertainty in the latter two and their effects depend on altitude. The T(sub k) combined systematic error due to non-LTE kinetic parameters does not exceed +/- 1.5 K below 95 km and +/- 4-5 K at 100 km for most latitudes and seasons (except for polar summer) if the Tk profile does not have pronounced vertical structure. The error is +/- 3 K at 80 km, +/- 6 K at 84 km and +/- 18 K at 100 km under the less favourable polar summer conditions. For strong temperature inversion layers, the errors reach +/- 3 K at 82 km and +/- 8 K at 90 km. This particularly affects tide amplitude estimates, with errors of up to +/- 3 K.

Garcia-Comas, Maya↗

Assessment of the Quality of the Version 1.07 Temperature-Versus-Pressure Profiles of the Middle Atmosphere from TIMED/SABER

The quality of the retrieved temperature-versus-pressure (or T(p)) profiles is described for the middle atmosphere for the publicly available Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) Version 1.07 (V1.07) data set. The primary sources of systematic error for the SABER results below about 70 km are (1) errors in the measured radiances, (2) biases in the forward model, and (3) uncertainties in the corrections for ozone and in the determination of the reference pressure for the retrieved profiles. Comparisons with other correlative data sets indicate that SABER T(p) is too high by 1-3 K in the lower stratosphere but then too low by 1 K near the stratopause and by 2 K in the middle mesosphere. There is little difference between the local thermodynamic equilibrium (LTE) algorithm results below about 70 km from V1.07 and V1.06, but there are substantial improvements/differences for the non-LTE results of V1.07 for the upper mesosphere and lower thermosphere (UMLT) region. In particular, the V1.07 algorithm uses monthly, diurnally averaged CO2 profiles versus latitude from the Whole Atmosphere Community Climate Model. This change has improved the consistency of the character of the tides in its kinetic temperature (T(sub k)). The T(sub k) profiles agree with UMLT values obtained from ground-based measurements of column-averaged OH and O2 emissions and of the Na lidar returns, at least within their mutual uncertainties. SABER T(sub k) values obtained near the mesopause with its daytime algorithm also agree well with the falling sphere climatology at high northern latitudes in summer. It is concluded that the SABER data set can be the basis for improved, diurnal-to-interannual-scale temperatures for the middle atmosphere and especially for its UMLT region.

Remsberg, E. E.↗

Mesospheric H2O Concentrations Retrieved from SABER/TIMED Measurements

The SABER instrument on board the TIMED Satellite is a limb scanning infrared radiometer designed to measure temperature and minor constituent vertical profiles and energetics parameters in the mesosphere and lower thermosphere (MLT). The H2O concentrations are retrieved from 6.3 micron band radiances. The populations of H2O(v2) vibrational levels are in non-Local Thermodynamic Equilibrium (non-LTE) above approximately 55 km altitude and the interpretation of 6.3 micron radiance requires utilizing non-LTE H2O model that includes various energy exchange processes in the system of H2O vibrational levels coupled with O2, N2, and CO2 vibrational levels. We incorporated these processes including kinetics of O2/O3 photolysis products to our research non-LTE H2O model and applied it for the development and optimization of SABER operational model. The latter has been validated using simultaneous SCISAT1/ACE occultation measurements. This helped us to estimate CO2(020)-O2(X,v=I), O2(X,v=I)- H2O(010), and O2(X,v=1) O rates at mesopause temperatures that is critical for an adequate interpretation of non-LTE H2O radiances in the MLT. The first distributions of seasonal and meridional H2O concentrations retrieved from SABER 6.3 micron radiances applying an updated non-LTE H2O model are demonstrated and discussed.

Feofilov, A. G.↗

An overview of the Halogen Occultation Experiment (HALOE) and preliminary results

The Halogen Occultation Experiment (HALOE) experiment has observed vertical profiles and pressure versus latitude cross sections of temperature HCl, HF, CH4, H2O, NO, NO2, O3, and aerosols over the range from 80 deg S to 80 deg N. An in-orbit precision of better than 0.3 ppbv has been demonstrated for HCl, HF, NO, NO2 and less than 0.6 ppmv for the other channels. Comparisons with correlative measurements at this early stage are encouraging. Nitric oxide has been observed over the range from the upper troposphere to 130-km. Latitudinal cross sections of the long-lived tracers CH4 and HF show clear indications of the effect of the general circulation.

Russell, J. M., III↗

Description of data on the Nimbus 7 LIMS map archive tape: Ozone and nitric acid

The Nimbus 7 Limb Infrared Monitor of the Stratosphere (LIMS) data set has been processed into a Fourier coefficient representation with a Kalman filter algorithm applied to profile data at individual latitudes and pressure levels. The algorithm produces synoptic data at noon Greenwich Mean Time (GMT) from the asynoptic orbital profiles. This form of the data set is easy to use and is appropriate for time series analysis and further data manipulation and display. Ozone and nitric acid results are grouped together in this report because the LIMS vertical field of views (FOV's) and analysis characteristics for these species are similar. A comparison of the orbital input data with mixing ratios derived from Kalman filter coefficients indicates errors in mixing ratio of generally less than 5 percent, with 15 percent being a maximum error. The high quality of the mapped data was indicated by coherence of both the phases and the amplitudes of waves with latitude and pressure. Examples of the mapped fields are presented, and details are given concerning the importance of diurnal variations, the removal of polar stratospheric cloud signatures, and the interpretation of bias effects in the data near the tops of profiles.

Remsberg, E. E.↗

Observations of the diurnal variation of nitrogen dioxide in the stratosphere

Observations of NO2 from the limb infrared monitor of the stratosphere (LIMS) experiment in high-latitude summer are presented. Appropriate selection of latitude and days during the month of May yields NO2 observations obtained during the afternoon and evening at solar zenith angles ranging from about 35-110 deg. These data show that the NO2 abundances in the stratosphere become strongly dependent on the solar zenith angle for angles exceeding about 80 deg. Model calculations and other observations suggest that from about 80-95 deg this dependence probably reflects variations in the propagation of the visible radiation that photodissociates NO2. The data obtained at zenith angles greater than about 95 deg provide clear evidence for the night decay of NO2 to form N2O5, and the observed decay rate is shown to be consistent with present theory.

Solomon, S.↗

Transport of ozone in the middle stratosphere - Evidence for planetary wave breaking

Data from the Nimbus 7 Limb Infrared Monitor of the Stratosphere (LIMS) for the period October 25, 1978-May 28, 1979 are used in a descriptive study of ozone variations in the middle stratosphere. It is shown that the ozone distribution is strongly influenced by irreversible deformation associated with large amplitude planetary-scale waves. This process, which has been described by McIntyre and Palmer as planetary wave breaking, takes place throughout the 3-30 mb layer, and poleward transport of ozone within this layer occurs in narrow tongues drawn on the tropics and subtropics in association with major and minor warming events. These events complement the zonal mean diabatic circulation in producing significant changes in the total column amount of ozone.

Leovy, C. B.↗

Global lower mesospheric water vapor revealed by LIMS observations

The Limb Infrared Monitor of the Stratospheric water vapor channel data analysis has been extended from the 1. mb level (about 48 km) to the .3 mb level (about 60 km) through a radiance averaging procedure and better understanding of systematic errors. The data show H2O mixing ratio peaks near the .5 mb level varying from 4 to 7 ppmv with latitude and season. Above this level the mixing ratio drops off quickly with altitude, but, due to experimental uncertainties, at an uncertain rate. The stratospheric results are virtually the same as determined from the archived LIMS results with a tropical hygropause and enhanced H2O concentration in the lower levels at high winter latitudes.

Gordley, L. L.↗

Implications of the stratospheric water vapor distribution as determined from the Nimbus 7 LIMS experiment

The LIMS experiment on Nimbus 7 has provided new results on the stratospheric water vapor distribution. The data show (1) a latitudinal gradient with mixing ratios that increase by a factor of 2 from equator to + or - 60 degrees at 50 mb, (2) most of the time there is a fairly uniform mixing ratio of 5 ppmv at high latitudes, but more variation exists during winter, (3) a well-developed hygropause at low to midlatitudes of the lower stratosphere, (4) a source region of water vapor in the upper stratospehere to lower mesosphere that is consistent with methane oxidation chemistry, at least within the uncertainties of the data, (5) an apparent zonal mean H2O distribution that is consistent with the circulation proposed by Brewer in 1949, and (6) a zonal mean distribution in the lower stratosphere that is consistent with the idea of quasi-isentropic transport by eddies in the meridional direction. Limits to the use of the data in the refinement of our understanding of the stratospheric water vapor budget are noted.

Remsberg, E. E.↗

The variability of stratospheric and mesospheric NO2 in the polar winter night observed by LIMS

The LIMS experiment sounded the upper atmosphere from late October 1978 to late May 1979 and provided vertical profiles of atmospheric temperature, 03, H2O, HNO3, and NO2. Radiance averaging was used before retrieval to measure the altitude distribution of NO2 over the altitude range from the lower stratosphere into the mesosphere. Observations in the polar winter night region northward of about 70 deg N reveal NO2 levels near 175 ppbv at about 70 km, and they show a significant longitudinal variability (factor of 4 to 7). A definite temporal trend exists, showing a buildup of mesospheric and stratospheric NO2 during the polar night and a subsequent slowing of the increase of decline after sunlight returns, depending on altitude. The data represent the first experimental evidence that the thermosphere is an NO(x) source for the mesosphere and stratosphere.

Russell, M. J., III↗

Validation of nitrogen dioxide results measured by the limb infrared monitor of the stratosphere (LIMS) experiment on NIMBUS 7

The validation of results from the nitrogen dioxide channel and the quality of the data are examined in connection with the LIMS experiment which ran from late October 1978 to late May 1979. Factors studied include: channel characteristics, experiment errors due to instrument and spacecraft effects, predicted and measured precision, predicted accuracy, and comparisons with correlative measurements made in a series of balloon underflights. Features such as profile shape and slope of the mixing ratio altitude distribution are in good agreement. The LIMS data also fall within the range of previous mixing ratio measurements and are consistent with model estimates. The calculated on-orbit precision is about 0.3 ppbv and the estimated accuracy from simulations is about 2 ppbv over the 3-10-mbar range. Accuracy is less at higher and lower pressure levels. These results provide the first day-night set of nitrogen dioxide measurements from space.

Russell, J. M., III↗

Validation of water vapor results measured by the Limb Infrared Monitor of the Stratosphere experiment on Nimbus 7

In the LIMS experiment using thermal IR limb scanning to sound the composition and structure of the upper atmosphere, one of the LIMS channels was spectrally centered at 6.9 micrometers to measure the vertical profile and global distribution of stratospheric water vapor. This channel's characteristics, the data from it, and the steps taken to validate results are described. The mean difference between the LIMS measurements and data from 13 balloon underflights is about 0.6 ppmv with LIMS mixing ratios biased high; this difference is of about the same order as estimated LIMS accuracy and less than the sum of the errors for LIMS and the balloon techniques. In-orbit precision is 0.2-0.3 ppmv and accuracy is estimated at 20-30 percent from 50 mbar to the stratopause. An unexplained diurnal variation exists in the vertical profile data which is largest at the 1-mbar level and virtually nonexistent at 10 mbar; day values are higher than night. More confidence is placed in zonal mean distributions averaged over several days than in single profiles. A zonal mean pressure-latitude cross section is described for January 5-9, 1979.

Russell, J. M., III↗

Spectroscopy and transmittances for the LIMS experiment

The Limb Infrared Monitor of the Stratosphere (LIMS) instrument on the Nimbus 7 spacecraft sensed limb emission profiles for 7 months, starting in October 1979. Vertical temperature profiles are inferred from measurements in two CO2 channels, and constituent profiles are obtained form the O3, HNO3, NO2, and water vapor channels. The line parameters used to calculate transmittances in the retrieval algorithm are presented. Their adequacy for LIMS and for other applications are assessed, and recommendations for future investigations are outlined.

Drayson, S. R.↗

Validation of temperature retrievals obtained by the Limb Infrared Monitor of the Stratosphere (LIMS) experiment on Nimbus 7

An outline is given of LIMS temperature determinations (as a function of pressure) from measurements in two channels covering portions of the 15-micrometer band of carbon dioxide. The known sources of error from the radiometer and data reduction are used to estimate the systematic and random errors expected of the results. Observational determinations of the complete end-to-end precision are obtained by computing the standard deviation of six sequential temperature retrievals in regions where the atmosphere is horizontally uniform. This yields values of 0.2 to 0.6 K, in reasonable agreement with the estimates. A correction for horizontal gradients in the atmosphere leads to a large reduction in the differences between the stratospheric temperatures determined on the ascending and descending portions of the orbit. The temperatures agree in the mean with radiosondes and rocketsondes to within 1-2 K in most regions below 1 mbar. Several interesting, previously unseen features included cold regions in the mid-latitude mesosphere and wavelike vertical variations in the tropics.

Gille, J. C.↗

The validation of Nimbus 7 LIMS measurements of ozone

Approximately seven and one half months of stratospheric ozone profiles have been processed from the LIMS (Limb Infrared Monitor of the Stratosphere) experiment on the Nimbus 7 satellite. Data profiles cover the stratosphere and mesosphere from 100 to 0.1 mbar and from 84 degrees N to 64 degrees S latitude. Topics covered include the ozone channel characteristics, precision, systematic uncertainties, and comparisons with data from balloon and rocket underflights, Umkehr soundings, and Dobson measurements. Comparisons with Dobson total ozone are made by integrating combined LIMS plus balloon profiles. The estimated on-orbit precision is 0.02-0.16 ppmv. Simulations of the experiment indicate potential systematic uncertainties ranging from 15 percent in the 1-mbar region to an upper limit of 40 percent at 100 mbar and 0.1 mbar. Results are well within the uncertainties for the correlative sensors themselves. LIMS detects significant vertical structure in the ozone profile even below the ozone mixing ratio peak. Several other comparisons showing good agreement are noted.

Remsberg, E. E.↗

Sensitivity of ozone retrievals in limb-viewing experiments to errors in line-width parameters

The variance of atmospheric ozone concentration profiles retrieved in i.r. limb-viewing experiments is examined over the range of published ozone halfwidth values. Simulated retrievals are performed for a typical satellite-based high-resolution absorption experiment and a broad-band emission experiment. The results indicate that, for limb-viewing experiments, inaccurate collision-broadened linewidth values can lead to significant errors in retrieved profiles for broad-band radiometric data or for isolated strong lines in high-resolution spectra.

Smith, M. A. H.↗