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Engineering topics

Gupta, A.

Publications and source records attributed to Gupta, A..

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Double-beam optical method and apparatus for measuring thermal diffusivity and other molecular dynamic processes in utilizing the transient thermal lens effect

A sample material was irradiated by relatively high power, short pulses from a dye laser. Energy from the pulses was absorbed by the sample material, thereby forming a thermal lens in the area of absorption. The pulse repetition rate was chosen so that the thermal lens is substantially dissipated by the time the next pulse reaches the sample material. A probe light beam, which in a specific embodiment is a relatively low power, continuous wave (cw) laser beam, irradiated the thermal lens formed in the sample material. The intensity characteristics of the probe light beam subsequent to irradiation of the thermal lens is related to changes in the refractive index of the sample material as the thermal lens is formed and dissipated.

Moacanin, J.↗
NASA NTRS1981

Development of a weatherable acrylic elastomer for solar cell encapsulation

Poly-n-butylacrylate (PnBA) will be discussed as a potential candidate to be used in solar cell encapsulation. A new process has been developed in which PnBA can be readily cross-linked from a solvent-free syrup by a thermal process to give a highly flexible transparent film which does not creep significantly at temperature of up to 90 C. This process can be automated without the use of high cost capital equipment. Photodegradation of PnBA has also been modeled as a function of wavelengths and intensities. Its photostability will be discussed.

Liang, R.↗
NASA NTRS1980

Thermal diffusivity measurements using a pulsed dual-beam thermal lens technique

A novel pulsed dual-beam thermal lens technique for the determination of thermal diffusivity of liquids and solids was developed. In this technique a transient thermal lens is formed in the test specimen by using a dye laser pulse as a heating source and the thermal lens decay is monitored by means of a CW He-Ne laser. The technique is fast and contactless and avoids some of the major difficulties of conventional methods. Thermal diffusivities for water and a polycarbonate plastic were measured and found to be in agreement with literature values. Considerable simplification and minimization of certain errors was achieved by use of a reference material.

Gupta, M. C.↗
NASA NTRS1980

UV actinometer film

Cumulative UV radiation can be measured by low-cost polymer film that is unaffacted by visible light. Useful for virtually any surface, film can help paint and plastics manufacturers determine how well their products stand up against UV radiation. Actinometer film uses photochemically sensitive compound that changes its chemical composition in response to solar radiation. Extent of chemical conversion depends on length exposure and can be measured by examining film sample with spectrophotometer. Film can be exposed from several seconds up to month.

Coulbert, C. D.↗
NASA NTRS1980

Changes in "thermal lens" measure diffusivity

In an extension of "thermal lens" effect to new applications and better resolution, two laser beams combine to rapidly measure thermal diffusivity and other molecular dynamic properties. New double-beam technique handles very small samples unlike classical techniques for measuring diffusivity. It can be used for measurements on samples undergoing stress, making it applicable to data collection for structural engineering.

Gupta, A.↗
NASA NTRS1980

Development of failure model for nickel cadmium cells

The development of a method for the life prediction of nickel cadmium cells is discussed. The approach described involves acquiring an understanding of the mechanisms of degradation and failure and at the same time developing nondestructive evaluation techniques for the nickel cadmium cells. The development of a statistical failure model which will describe the mechanisms of degradation and failure is outlined.

Gupta, A.↗
NASA NTRS1979

An analytical approach to evaluation of space radiation effects on materials for long-life missions

An analytical model was developed which quantifies effects on organic composite matrix materials of high energy electrons and of UV as well as interactions between the two radiations. Literature data on polyethylene were used to construct a degradation kinetics scheme corresponding to an Earth orbit at L=3. Analysis of the model showed that steady state concentrations of radicals put limits on accelerated test conditions. These conclusions were validated by an experimental study on polymethylmethacrylate using UV laser excitation. Relationships for balancing electron and UV radiations to equal acceleration factors are derived. Pulse radiolysis using an electron-beam along with time-resolved spectroscopy is shown to be able to separate primary form secondary reactions. Implications of these reactions to changes in engineering material properties are indicated. The use of mechanistic studies is discussed in the context of general test strategies for evaluating materials for space applications.

Moacanin, J.↗
NASA NTRS1979

Reactor for simulation and acceleration of solar ultraviolet damage

An environmental test chamber providing acceleration of UV radiation and precise temperature control (+ or -)1 C was designed, constructed and tested. This chamber allows acceleration of solar ultraviolet up to 30 suns while maintaining temperature of the absorbing surface at 30 C - 60 C. This test chamber utilizes a filtered medium pressure mercury arc as the source of radiation, and a combination of selenium radiometer and silicon radiometer to monitor solar ultraviolet (295-340 nm) and total radiant power output, respectively. Details of design and construction and operational procedures are presented along with typical test data.

Laue, E.↗
NASA NTRS1979

Effects of space environment on composites: An analytical study of critical experimental parameters

A generalized methodology currently employed at JPL, was used to develop an analytical model for effects of high-energy electrons and interactions between electron and ultraviolet effects. Chemical kinetic concepts were applied in defining quantifiable parameters; the need for determining short-lived transient species and their concentration was demonstrated. The results demonstrates a systematic and cost-effective means of addressing the issues and show qualitative and quantitative, applicable relationships between space radiation and simulation parameters. An equally important result is identification of critical initial experiments necessary to further clarify the relationships. Topics discussed include facility and test design; rastered vs. diffuse continuous e-beam; valid acceleration level; simultaneous vs. sequential exposure to different types of radiation; and interruption of test continuity.

Gupta, A.↗
NASA NTRS1979

Physical/chemical modeling for photovoltaic module life prediction

The paper presents a generalized methodology for identification and evaluation of potential degradation and failure of terrestrial photovoltaic encapsulation. Failure progression modeling and an interaction matrix are utilized to complement the conventional approach to failure degradation mode identification. Comparison of the predicted performance based on these models can produce: (1) constraints on system or component design, materials or operating conditions, (2) qualification (predicted satisfactory function), and (3) uncertainty. The approach has been applied to an investigation of an unexpected delamination failure; it is being used to evaluate thermomechanical interactions in photovoltaic modules and to study corrosion of contacts and interconnects.

Moacanin, J.↗
NASA NTRS1978

Solid state photochemistry of polycarbonates

The quantum yield of photoFries rearrangement in a polycarbonate film has been analyzed as a function of temperature and humidity on the basis of previously reported (Koyler and Mann, 1977) experimental data. Results indicate that in the homogeneous amorphous phase, photoFries rearrangement is a concerted process proceeding either from the pi star reversed arrow n singlet, in which case it must be subject to considerable self quenching, or from a triplet, presumably the first triplet since the lifetime of higher triplets is expected to be very short in the solid phase. If the parent excited state is the first triplet, chain scission is possibly an independent process, probably occurring from the pi star reversed arrow n singlet. Evidence of chain scission on photodegradation in the solid state includes loss of C-O and C-C bond intensities revealed in the Fourier transform infrared spectra, gel permeation chromotography elution profiles of degraded film samples dissolved in CHCl3, and a decrease in tensile strength and T sub g as photodegradation proceeds. Chain scission is apparently inhibited as photoFries products accumulate.

Gupta, A.↗
NASA NTRS1978

Actinometric measurement of solar ultraviolet and development of a weighted solar UV integral

An actinometer has been developed to measure outdoor irradiance in the range 295-400 nm. Actinometric measurements of radiation are based on determination of photochemical reaction rates for reactions of known quantum efficiency. Actinometers have the advantage of providing irradiance data over surfaces of difficult accessibility; in addition, actinometrically determined irradiance data are wavelength weighted and therefore provide a useful means of assessing the degradation rates of polymers employed in solar energy systems.

Gupta, A.↗
NASA NTRS1977

Catalysts for low-energy aldehyde processes

Photochemical reaction of dicobalt octacarbonyl with polymeric support systems results in formation of polymer bonded metal catalyst. Catalyst is used in hydroformylation (addition of carbon dioxide and hydrogen) of olefins to yield aldehydes.

Gupta, A.↗