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Killinger, D. K.

Publications and source records attributed to Killinger, D. K..

At least 19 records

Tunable Infrared Lasers: Preparing for Expanded use in Environmental Monitoring

The literature on the use of tunable infrared lasers, for atmospheric trace gas detection and monitoring is about 25 years of age. However, this field, whith its myriad of potential application areas, has always been driven by the available laser technology. As new or improved laser devices become available, with characteristics which lend themselves to operation in compact, nearly autonomous instruments, their application to atmospheric science and environmental measurements expands.

tunable infrared lasers↗

Lidar technology measurements and technology: Report of panel

Lidar is ready to make an important contribution to tropospheric chemistry research with a variety of spaceborne measurements that complement the measurements from passive instruments. Lidar can now be considered for near-term and far-term space missions dealing with a number of scientifically important issues in tropospheric chemistry. The evolution in the lidar missions from space are addressed and details of these missions are given. The laser availability for space missions based upon the technical data is assessed.

Browell, Edward V.↗

Laser remote sensing of atmospheric ammonia using a CO2 lidar system

A CO2 differential-absorption lidar system has been used for the remote sensing of ammonia in the atmosphere. For CO2 lidar returns backscattered from topographic targets at ranges up to 2.7 km, the path-averaged sensitivity of the DIAL system was 5 ppb of NH3. Concentrations of atmospheric ammonia were found to vary during the day from undetectable levels (less than 5 ppb) to as high as 20 ppb, depending on temperature and humidity conditions.

Force, A. P.↗

Frequency tuning characteristics of a Q-switched Co:MgF2 laser

A tunable Q-switched Co:MgF2 laser has been developed for atmospheric remote sensing applications. Frequency tuning is provided by a quartz etalon and a specially designed three-element birefringent filter covering the whole gain bandwidth of the Co:MgF2 laser. The laser has good temporal and spectral characteristics, with an emission linewidth of approximately 3 GHz (0.1 per cm).

Lovold, S.↗

Error reduction in laser remote sensing - Combined effects of cross correlation and signal averaging

A systematic analysis is presented of the extent to which the accuracy of a differential-absorption lidar (DIAL) measurement may be improved by using the combined effects of signal averaging and temporal cross correlation. Previous studies which considered these effects separately are extended by incorporating both effects into a single analytical framework. In addition, experimental results involving lidar returns from a diffusely reflecting target using a dual-CO2 laser DIAL system with both heterodyne and direct detection are presented. These results are shown to be in good agreement with the theoretical analysis and help establish the limits of accuracy achievable under various experimental conditions.

Menyuk, N.↗

Assessment of relative error sources in IR DIAL measurement accuracy

An assessment is made of the role the various error sources play in limiting the accuracy of infrared differential absorption lidar measurements used for the remote sensing of atmospheric species. An overview is presented of the relative contribution of each error source including the inadequate knowledge of the absorption coefficient, differential spectral reflectance, and background interference as well as measurement errors arising from signal fluctuations.

Menyuk, N.↗

Experimental comparison of heterodyne and direct detection for pulsed differential absorption CO2 lidar

A pulsed dual-wavelength dual-CO2-laser differential-absorption lidar (DIAL) system has been developed which permits simultaneous heterodyne and direct detection of the same lidar returns. This system has been used to make an experimental comparison of the SNRs and statistical and temporal characteristics of the DIAL returns from several topographic targets. These results were found to be in general agreement with theory and were used to quantify the relative merits of the two detection techniques. The measured parameter values were applied to an analytical treatment to predict system trade-offs for the remote sensing of atmospheric species, with application to both path-averaged and range-resolved measurements.

Killinger, D. K.↗

Signal averaging limitations in heterodyne- and direct-detection laser remote sensing measurements

The improvement in measurement uncertainty brought about by the averaging of increasing numbers of pulse return signals in both heterodyne- and direct-detection lidar systems is investigated. A theoretical analysis is presented which shows the standard deviation of the mean measurement to decrease as the inverse square root of the number of measurements, except in the presence of temporal correlation. Experimental measurements based on a dual-hybrid-TEA CO2 laser differential absorption lidar system are reported which demonstrate that the actual reduction in the standard deviation of the mean in both heterodyne- and direct-detection systems is much slower than the inverse square-root dependence predicted for uncorrelated signals, but is in agreement with predictions in the event of temporal correlation. Results thus favor the use of direct detection at relatively short range where the lower limit of the standard deviation of the mean is about 2 percent, but advantages of heterodyne detection at longer ranges are noted.

Menyuk, N.↗

Limitations of laser transmission measurements due to correlated atmospheric effects

An evaluation is made of results of recent experimental work concerning the effects that atmospherically induced fluctuations and temporal correlations have on the accuracy of atmospheric laser transmission experiments. These experiments directly measured the limitations of signal averaging as a means to the reduction of the standard deviation of laser signals which are backscattered from either a specular or a diffusely reflecting target, by means of both heterodyne and direct detection systems. These limitations are shown to agree with a theory in which the observed, atmospherically induced temporal correlation is taken into account.

Menyuk, N.↗

Limitations of signal averaging due to temporal correlation in laser remote-sensing measurements

Laser remote sensing involves the measurement of laser-beam transmission through the atmosphere and is subject to uncertainties caused by strong fluctuations due primarily to speckle, glint, and atmospheric-turbulence effects. These uncertainties are generally reduced by taking average values of increasing numbers of measurements. An experiment was carried out to directly measure the effect of signal averaging on back-scattered laser return signals from a diffusely reflecting target using a direct-detection differential-absorption lidar (DIAL) system. The improvement in accuracy obtained by averaging over increasing numbers of data points was found to be smaller than that predicted for independent measurements. The experimental results are shown to be in excellent agreement with a theoretical analysis which considers the effect of temporal correlation. The analysis indicates that small but long-term temporal correlation severely limits the improvement available through signal averaging.

Menyuk, N.↗

Remote probing of the atmosphere using a CO2 DIAL system

An overview of our laser remote sensing effort is presented. Using both fundamental and frequency-doubled CO2 laser radiation in a differential absorption LIDAR (DIAL) system, background concentrations of CO, NO, and C2H4 in the atmosphere as well as increases due to localized emission sources have been measured. These species have been detected using the backscattered laser radiation from topographic targets at ranges to 2.7 km with a sensitivity of plus or minus 10 ppb. In addition, using a dual-laser DIAL system, the effect of induced correlation of the LIDAR returns due to atmospheric turbulence has been investigated. These results have been used to help quantify the accuracy of the DIAL measurements and are shown to be consistent with theory.

Killinger, D. K.↗

Effect of turbulence-induced correlation on laser remote sensing errors

Using a 10.6-micron dual-laser differential-absorption laser remote sensing system, the short- and long-term temporal correlation of the returns from topographic targets and retroreflectors are measured in order to investigate the effect of atmospheric turbulence on laser remote sensing measurement errors. The results quantify the improvement obtained through use of a dual-laser system compared to that of a single-laser system and are in good agreement with those predicted by a theory which considers the effect of partial temporal correlation on the resultant measurement error.

Killinger, D. K.↗

Temporal correlation measurements of pulsed dual CO2 lidar returns

A pulsed dual-laser direct-detection differential-absorption lidar DIAL system, operating near 10.6 microns, is used to measure the temporal correlation and statistical properties of backscattered returns from specular and diffuse topographic targets. Results show that atmospheric-turbulence fluctuations can effectively be frozen for pulse separation times on the order of 1-3 msec or less. The diffuse target returns, however, yielded a much lower correlation than that obtained with the specular targets; this being due to uncorrelated system noise effects and different statistics for the two types of target returns.

Menyuk, N.↗

Rotational dependence in the linewidth of the ultraviolet transitions of OH

The homogeneously broadened linewidth of OH due to collisions with water molecules was found to decrease with increasing rotational excitation, and tended to level off to a constant value. This observed dependence is a manifestation of the rotational distribution of the water molecule through rotational transitions in near resonance with those of the OH. The constant value at high rotational excitation reflects the nonresonant contributions to the homogeneous linewidth similar to those due to nonpolar molecules.

Wang, C. C.↗

Effect of rotational excitation on the band oscillator strength of OH

In the study described, a single-frequency tunable CW dye laser was used to obtain accurate absorption measurements of the band oscillator strength for various rotational-electronic lines in some transitions of OH. The band oscillator strength is shown to decrease linearly with the energy of rotational excitation. This decrease is attributed exclusively to the lengthening of the internuclear distance due to rotation.

Wang, C. C.↗

Direct measurements of the Gibbs free energy of OH using a CW tunable laser

The paper describes an absorption measurement for determining the Gibbs free energy of OH generated in a mixture of water and oxygen vapor. These measurements afford a direct verification of the accuracy of thermochemical data of H2O at high temperatures and pressures. The results indicate that values for the heat capacity of H2O obtained through numerical computations are correct within an experimental uncertainty of 0.15 cal/mole K.

Killinger, D. K.↗

Absorption measurements of OH using a CW tunable laser

Absorption of OH was measured using a CW tunable laser. Results indicate that this technique, when combined with frequency modulation, promises a sensitivity of 100,000 molecules/cu cm for OH monitoring in the atmosphere.

Killinger, D. K.↗