Simultaneous determination of rotational and translational temperatures of OH/2 Pi/ in a gas discharge
A simultaneous determination of the rotational and translational temperatures of OH(2 Pi) in a water-vapor discharge is reported. These temperatures were determined by measuring the strength and line shape of the absorption lines in the 2 Pi (v = 0) - 2 Sigma(+) (v = 0) transitions of OH using a CW tunable laser. It was found that the rotational distribution was thermalized, but the corresponding rotational temperature was much lower than the translational temperature. Possible implications of these results are discussed.