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Larimer, Curtis J.

Publications and source records attributed to Larimer, Curtis J..

Scale up, Field Testing, and Optimization of Nontoxic, Durable, Economical Coatings for Control of Invasive mussels at Hydropower Facilities (Final Report for CRADA 527)

In this effort, Pacific Northwest National Laboratory (PNNL) demonstrated the technical maturation of a durable, economical, and nontoxic coating (Superhydrophobic Lubricant Infused Composite, SLIC) that prevents invasive mussels and other unwanted organisms from growing on hydropower and marine structures. The physical characteristics of SLIC were measured using a variety of industry standard methods, just as a commercially available paint would, to show that it can rival other antifouling paints on the market not just in antifouling efficacy, but in structural integrity. SLIC also underwent extensive field testing in diverse field sites across the US to demonstrate that it is effective in varying environments. Engagement with industrial partners showed there is continued interest and need for a cost-effective, durable antifouling coating such as SLIC.

13 HYDRO ENERGY↗

Enhancing Lifetime and Reducing Costs for Fish Diversion Netting Structures (Final Report)

In this effort Pacific Northwest National Laboratory (PNNL) developed and demonstrated an anti-fouling coating that is effective on fish diversion structures. The coating was based on a previously developed superhydrophobic lubricant infused composite (SLIC) coating but modified for application to flexible substrates. We showed that the new reformulated coating – FlexiSLIC – can be applied to flexible fibrous structures to significantly reduce biofouling of netting and anchor lines, to enable longer operational lifetimes, reduced costs, and more reliable operations. The coating developed in this effort was tested on relevant fish diversion structural netting and rope materials (e.g. nylon, Dyneema, polypropylene) to reduce biofouling. Engagement with industry in the development and demonstration further supported progress toward commercialization of the materials.

36 MATERIALS SCIENCE↗

Methods and systems of characterizing and counting microbiological colonies

Described herein are methods, systems, and non-transitory computer-readable media to non-destructively acquire three-dimensional profiles of cellular microbiological samples growing on the surface of a solid growth medium. Acquisitions can be performed by an optical microscope that includes a vertical scanning interferometer. The three-dimensional profiles can enable measurement of sample parameters of microcolonies, which can be made of microbial colony forming units. The methods and systems enable early and rapid detection and quantification of microbes.

Larimer, Curtis J.↗

Classification of Ultrasonic Weld Quality using Acoustic Signatures Acquired During Manufacture

Ultrasonic welding is a process is based on generating a solid-state bond between two metals by applying moderate pressure and high intensity sound waves (20-70 kHz frequencies) at their interface. During the solid-state process numerous material, surface, instrument, and environmental factors contribute to bond formation, strength, and durability. The inherent difficulty of measuring and controlling each of these factors has, to date, made predicting bond quality elusive. In this work, a Sonics model MWB20 ultrasonic spot welder with integral base, was used to produce a variety of welds of different metal foils under varying weld conditions. Acoustic measurements were recorded throughout the measurement process. Subsequent analysis of the signals using metrics that approximate the energy dispersed during the weld proved to successfully predict weld quality. Two metrics based on normalized energy differential and Renyi entropy were developed into Python and C++ scripts for direct analysis of weld acoustic data.

36 MATERIALS SCIENCE↗

Enhancing Lifetime and Reducing Costs for Fish Diversion Netting Structures (Abstract)

This effort will focus on technology transfer and commercialization of antifouling coatings with an enthusiastic and engaged industrial team. Environmental requirements and operational demands call for a nontoxic coating/paint to prevent fouling on fish passage guidance netting at hydropower facilities. For example, one netting customer estimated the capital cost for compliance at $\$12$ million to $\$15$ million. This project will build partnerships between PNNL and private companies to optimize, demonstrate, mature, and commercialize a novel PNNL-developed technology that addresses this critical coating need of the hydropower industry. This effort will support modification of existing coatings for application to flexible netting structures. Industrial partners include commercial coating development specialist (Lorama), hydrophobic material manufacturer and paint developer (Dry Surface Technologies), aquatic applications specialists (Prometheus Innovations and River Connectivity Systems), and hydropower netting producer (Pacific Netting Products). Engagement with the U.S. Army Corps of Engineers (USACE) and Bureau of Reclamation (BOR), two hydropower operators, throughout the project will provide expertise and field test sites that will provide crucial proof of real-world performance data (additional details provided in Teaming section). Taylor Shellfish Farms will provide organisms and fouling expertise as well as a perspective of potential broader impacts for the blue economy. Sample netting will demonstrate performance in a range of environments for key hydropower applications. PNNL will work with industrial partners to overcome commercialization barriers as well as resolving any manufacturing or regulatory issues. This Phase 1 effort is focused on technology optimization for application to fish passage guidance netting and technology validation as verified by independent testing (through USACE, BOR, Taylor Shellfish and Prometheus Innovations). Through this effort, SLIC will be demonstrated for netting applications at technology readiness level (TRL) 5. The field test data will allow optimization of SLIC formulation and performance which is key to enabling technology transfer of a mature proven technology to industry and production of a viable commercial product specifically focused for hydropower needs.

13 HYDRO ENERGY↗

Electric Vehicles at Scale - Phase II - Distribution Systems Analysis

The use of electric vehicles (EVs) in the United States has grown significantly during the last decade, posing benefits to the environment but also potential challenges to our grid. To better understand this scenario , the Department of Energy (DOE) asked Pacific Northwest National Laboratory (PNNL) to perform an authoritative study of the impacts of EVs at scale on the electric grid. The Phase I study focused on the bulk power electricity impacts . This EV-at-scale Phase II work addresses key questions of interest to DOE related to the impacts of EV in the distribution systems: 1. When (which year), where, and how many EVs will be adopted and how will they be charged? 2. Given some prospective answers to the above question, what would be the EV hosting capability of a distribution system circuit? 3. How could the hosting capability be expanded to accommodate more EVs and what would be the potential measures and cost? This report documents the methodologies developed as part of this project and provides EV adoption modeling examples using distribution system circuit data provided by industry partner, Southern California Edison (SCE).

24 POWER TRANSMISSION AND DISTRIBUTION↗

Durable Super-Repellant Materials for Stretchable and Flexible Personal Protective Equipment

The goal of this report is to summarize findings from development of new flexible protective coatings with superhydrophobic properties. For many practical applications, the durability of such coatings must far exceed what it currently possible. We aimed to develop coatings that can be integrated into personal protective equipment to provide an additional barrier that can shed and reduce the spread of infectious liquids. The COVID-19 pandemic has revealed the importance of PPE for frontline healthcare workers. Developing durable protective coatings could have both immediate impacts during the pandemic and long-term benefits in multiple industries.

36 MATERIALS SCIENCE↗

Reinforced composites with repellent and slippery properties

Compositions and processes are disclosed for forming hydrophobic coatings and lubricant-infused surface coatings. Coatings may be applied to various substrates without prior chemical or temperature treatment of the substrates and over large and irregular surfaces. Coatings are self-healing, antifouling, and have enhanced lifetimes.

Larimer, Curtis J.↗

Optical coherence tomography imaging of plant root growth in soil

Complex interactions between roots and soil provide the nutrients and physical support required for robust plant growth. Yet, visualizing the root-soil interface is challenged by soil’s opaque scattering characteristics. In this paper, we describe methods for using optical coherence tomography (OCT) to provide non-destructive 3D and cross-sectional root imaging not available with traditional bright field microscopy. OCT is regularly used for bioimaging, especially in ophthalmology where it can detect retinal abnormalities. Prior use of OCT in plant biology has focused on surface defects of above ground tissues, predominantly in food crops. Our results show OCT is also viable for detailed, in situ study of living plant roots.

59 BASIC BIOLOGICAL SCIENCES↗