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Lee, Y. S.

Publications and source records attributed to Lee, Y. S..

15 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Enhanced charge density wave with mobile superconducting vortices in La 1.885 Sr 0.115 CuO 4

Superconductivity in the cuprates is found to be intertwined with charge and spin density waves. Determining the interactions between the different types of order is crucial for understanding these important materials. Here, we elucidate the role of the charge density wave (CDW) in the prototypical cuprate La 1.885 Sr 0.115 CuO 4 , by studying the effects of large magnetic fields (H) up to 24 Tesla. At low temperatures (T), the observed CDW peaks reveal two distinct regions in the material: a majority phase with short-range CDW coexisting with superconductivity, and a minority phase with longer-range CDW coexisting with static spin density wave (SDW). With increasing magnetic field, the CDW first grows smoothly in a manner similar to the SDW. However, at high fields we discover a sudden increase in the CDW amplitude upon entering the vortex-liquid state. Our results signify strong coupling of the CDW to mobile superconducting vortices and link enhanced CDW amplitude with local superconducting pairing across the H -T phase diagram.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Direct visualization and control of antiferromagnetic domains and spin reorientation in a parent cuprate

Here, we report magnetic optical second-harmonic generation (SHG) polarimetry and imaging on Sr 2 Cu 3 O 4 Cl 2 , which allows direct visualization of the mesoscopic antiferromagnetic (AFM) structure of a parent cuprate. Temperature- and magnetic-field-dependent SHG reveals large domains with 90° relative orientations that are stabilized by a combination of uniaxial magnetic anisotropy and the Earth's magnetic field. Below a temperature T R ~ 97 K, we observe an unusual 90° spin reorientation transition, possibly driven by competing magnetic anisotropies of the two copper sublattices, which swaps the AFM domain states while preserving the domain structure. This allows deterministic switching of the AFM states by thermal or laser heating. Near T R , the domain walls become exceptionally responsive to an applied magnetic field, with the Earth's field sufficient to completely expel them from the crystal. Our findings unlock opportunities to study the mesoscopic AFM behavior of parent cuprates and explore their potential for AFM technologies.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Observation of two types of charge-density-wave orders in superconducting La 2-x Sr x CuO 4

The discovery of charge- and spin-density-wave (CDW/SDW) orders in superconducting cuprates has altered our perspective on the nature of high-temperature superconductivity (SC). However, it has proven difficult to fully elucidate the relationship between the density wave orders and SC. Here, using resonant soft X-ray scattering, we study the archetypal cuprate La 2-x Sr x CuO 4 (LSCO) over a broad doping range. We reveal the existence of two types of CDW orders in LSCO, namely CDW stripe order and CDW short-range order (SRO). While the CDW-SRO is suppressed by SC, it is partially transformed into the CDW stripe order with developing SDW stripe order near the superconducting T c. These findings indicate that the stripe orders and SC are inhomogeneously distributed in the superconducting CuO 2 planes of LSCO. This further suggests a new perspective on the putative pair-density-wave order that coexists with SC, SDW, and CDW orders.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Three-dimensional collective charge excitations in electron-doped copper oxide superconductors

High-temperature copper oxide superconductors consist of stacked CuO 2 planes, with electronic band structures and magnetic excitations that are primarily two-dimensional1,2, but with superconducting coherence that is three-dimensional. This dichotomy highlights the importance of out-of-plane charge dynamics, which has been found to be incoherent in the normal state within the limited range of momenta accessible by optics. Here in this study, we use resonant inelastic X-ray scattering to explore the charge dynamics across all three dimensions of the Brillouin zone. Polarization analysis of recently discovered collective excitations (modes) in electron-doped copper oxides reveals their charge origin, that is, without mixing with magnetic components. The excitations disperse along both the in-plane and out-of-plane directions, revealing its three-dimensional nature. The periodicity of the out-of-plane dispersion corresponds to the distance between neighbouring CuO 2 planes rather than to the crystallographic c-axis lattice constant, suggesting that the interplane Coulomb interaction is responsible for the coherent out-of-plane charge dynamics. The observed properties are hallmarks of the long-sought ‘acoustic plasmon’, which is a branch of distinct charge collective modes predicted for layered systems and argued to play a substantial part in mediating high-temperature superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Asymmetric Cracking in Mar-M247 Alloy Builds During Electron Beam Powder Bed Fusion Additive Manufacturing

In the electron beam powder bed fusion (EB-PBF) process, a substantial number of high-gamma prime Ni-based superalloys are considered as non-printable due to a high propensity to form cracks. In this research, we focused on computational modeling framework to predict solidification-related cracking phenomena in EB-PBF processes. The cracking analysis was performed on cylindrical overhang structures where the cracks are observed only on one side of the part. Comprehensive microstructural characterization correlated the cracking tendency to low-melting point liquid-film formation along columnar grain boundaries with high misorientation angles due to partitioning of alloying elements. Uncoupled numerical thermal and mechanical models were used to rationalize the relationship between process parameters, build geometry, and cracking. The simulations showed asymmetric temperature distributions and associated asymmetric tensile thermal stresses over a cross section due to differences in section modulus and periodic changes in beam scanning directions. Here, the results provide a potential pathway based on spatially varying beam scanning strategies to reduce the cracking tendency during additive manufacturing of complex geometries on the overhang structure in high-gamma prime nickel-based superalloys.

36 MATERIALS SCIENCE↗
DOE OSTI2018

La 139 and Cu 63 NMR investigation of charge order in La 2 CuO 4 + y ( T c = 42 K)

Here, we report 139 La and 63 Cu NMR investigation of the successive charge order, spin order, and superconducting transitions in superoxygenated La 2 CuO 4+y single crystal with stage-4 excess oxygen order at T stage ≃290 K. We show that the stage-4 order induces tilting of CuO 6 octahedra below T stage , which in turn causes 139 La NMR line broadening. The structural distortion continues to develop far below Tstage, and completes at T charge ≃60 K, where charge order sets in. This sequence is reminiscent of the the charge-order transition in Nd codoped La 1.88 Sr 0.12 CuO 4 that sets in once the low-temperature tetragonal phase is established. We also show that the paramagnetic 63 Cu NMR signals are progressively wiped out below T charge due to enhanced low-frequency spin fluctuations in charge-ordered domains, but the residual 63 Cu NMR signals continue to exhibit the characteristics expected for optimally doped superconducting CuO 2 planes. This indicates that charge order in La 2 CuO 4+y does not take place uniformly in space. In addition, unlike the typical second-order magnetic phase transitions, low-frequency Cu spin fluctuations as probed by 139 La nuclear spin-lattice relaxation rate do not exhibit critical divergence at T spin (≃T c ) =42 K. These findings, including the spatially inhomogeneous nature of the charge-ordered state, are qualitatively similar to the case of La 1.885 Sr 0.115 CuO 4 , but both charge and spin order take place more sharply in the present case.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2018

Dynamic simulation of powder packing structure for powder bed additive manufacturing

Here, powder packing structure is a critical parameter of powder bed-based additive manufacturing (AM). Experimental characterization of powder is typically limited to measuring bulk properties, whereas many numerical models of AM powder packing are based on geometrical consideration without accounting for particle-to-particle interactions. In the present paper, the powder packing dynamics is simulated using a discrete element method (DEM)-based model that solves the mechanical contact forces and moments between individual particles. As DEM uses explicit time integration, a main challenge in modeling dynamics of metallic powder packing is the need for extremely fine time increment size (e.g., in the order of 1 ns for a 10-μm-diameter particle). The effect of mass scaling, employed for speeding up the calculation, on the simulation results is examined in a test case of powder particles packed inside a box container. The calculated packing density for two different particle size distributions is validated against independent literature data for laser powder bed AM with AISI 316L stainless steel powder. The sensitivity of key input parameters (e.g., friction coefficient) is further evaluated in this test case. The powder packing model is then applied to a practical situation of binder jet AM involving rolling of multiple layers of IN718 powder particles onto a powder bed, for which the calculated packing density is also validated with independent literature data.

42 ENGINEERING↗
DOE OSTI2018

La 139 NMR investigation of the charge and spin order in a La 1.885 Sr 0.115 CuO 4 single crystal

139 La NMR is suited for investigations into magnetic properties of La 2 CuO 4 -based cuprates in the vicinity of their magnetic instabilities, owing to the modest hyperfine interactions between 139 La nuclear spins and Cu electron spins. We report comprehensive 139 La NMR measurements on a single-crystal sample of high-T c superconductor La 1.885 Sr 0.115 CuO 4 in a broad temperature range across the charge and spin order transitions (T charge ≃ 80 K, T neutron spin ≃ T c = 30 K). From the high-precision measurements of the linewidth for the nuclear spin I z = + 1 / 2 to -1/2 central transition, we show that paramagnetic line broadening sets in precisely at T charge due to enhanced spin correlations within the CuO 2 planes. Additional paramagnetic line broadening ensues below ~35 K, signaling that Cu spins in some segments of CuO 2 planes are on the verge of three-dimensional magnetic order. A static hyperfine magnetic field arising from ordered Cu moments along the ab plane, however, begins to develop only below T$μSR\atop{spin}$ = 15 – 20 K, where earlier muon spin rotation measurements detected Larmor precession for a small volume fraction (~20 % ) of the sample. Based on the measurement of 139 La nuclear-spin-lattice relaxation rate 1/T 1 , we also show that charge order triggers enhancement of low-frequency Cu spin fluctuations inhomogeneously; a growing fraction of 139 La sites is affected by enhanced low-frequency spin fluctuations toward the eventual magnetic order, whereas a diminishing fraction continues to exhibit a behavior analogous to the optimally superconducting phase even below T charge . In conclusion, these 139 La NMR results corroborate our recent 63 Cu NMR observation that a very broad, anomalous winglike signal gradually emerges below T charge , whereas the normally behaving, narrower main peak is gradually wiped out [T. Imai et al., Phys. Rev. B 96, 224508 (2017)]. Furthermore, we show that the enhancement of low-energy spin excitations in the low-temperature regime below Tneutron spin (≃ Tc) depends strongly on the magnitude and orientation of the applied magnetic field.

42 ENGINEERING↗
DOE OSTI2017

Revisiting Cu 63 NMR evidence for charge order in superconducting La 1.885 Sr 0.115 CuO 4

Here, the presence of charge and spin stripe order in the La 2 CuO 4 -based family of superconductors continues to lead to new insight on the unusual ground-state properties of high- T c cuprates. Soon after the discovery of charge stripe order at T charge ≃65 K in Nd 3+ co-doped La 1.48 Nd 0.4 Sr 0.12 CuO 4 ( T c ≃6 K), Hunt et al. demonstrated that La 1.48 Nd 0.4 Sr 0.12 CuO 4 and superconducting La 2–x Sr x CuO 4 with x~1/8( T c ≃30 K) share nearly identical NMR anomalies near Tcharge of the former. Their inevitable conclusion that La 1.885 Sr 0.115 CuO 4 also undergoes charge order at a comparable temperature became controversial, because diffraction measurements at the time were unable to detect Bragg peaks associated with charge order. Recent advances in x-ray diffraction techniques finally led to definitive confirmations of the charge order Bragg peaks in La 1.885 Sr 0.115 CuO 4 with an onset at as high as T charge ≃80 K. Meanwhile, improved instrumental technology has enabled routine NMR measurements that were not feasible two decades ago. Motivated by these new developments, we revisit the charge order transition of a La 1.885 Sr 0.115 CuO 4 single crystal based on 63 Cu NMR techniques. We demonstrate that 63 Cu NMR properties of the nuclear spin I z =–1/2 to +1/2 central transition below T charge exhibit unprecedentedly strong dependence on the measurement time scale set by the separation time τ between the 90° and 180° radio-frequency pulses; a new kind of anomalous, very broad winglike 63Cu NMR signals gradually emerge below T charge only for extremely short τ≲4μs, while the spectral weight I Normal of the normal NMR signals is progressively wiped out. The NMR linewidth and relaxation rates depend strongly on τ below T charge , and their enhancement in the charge ordered state indicates that charge order turns on strong but inhomogeneous growth of Cu spin-spin correlations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Epigenetic regulation of RNA polymerase III transcription in early breast tumorigenesis

RNA polymerase III (Pol III) transcribes medium-sized non-coding RNAs (collectively termed Pol III genes). Emerging diverse roles of Pol III genes suggest that individual Pol III genes are exquisitely regulated by transcription and epigenetic factors. Here we report global Pol III expression/methylation profiles and molecular mechanisms of Pol III regulation that have not been as extensively studied, using nc886 as a representative Pol III gene. In a human mammary epithelial cell system that recapitulates early breast tumorigenesis, the fraction of actively transcribed Pol III genes increases reaching a plateau during immortalization. Hypermethylation of Pol III genes inhibits Pol III binding to DNA via inducing repressed chromatin and is a determinant for the Pol III repertoire. Finally, when Pol III genes are hypo-methylated, MYC amplifies their transcription, regardless of its recognition DNA motif. Thus, Pol III expression during tumorigenesis is delineated by methylation and magnified by MYC.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1988

Cost-effective intersatellite link applications to the fixed satellite services

Potential cost-effective applications of intersatellite links (ISLs) to domestic, regional, and global fixed satellite services are presented, addressing traffic forecast and service demands for the year 2001. To determine the cost advantages and other systems benefits of ISLs, selected satellite network architectures were derived for ISL and corresponding non-ISL systems. The cost analysis was performed using payload sizing based on state-of-the-art ISL technology, both optical and microwave.

Lee, Y. S.↗
NASA NTRS1976

Optimal insensitive-controller synthesis

Proof of two theorems is included in report: local sufficiency condition for existence of insensitive controllers in the case of sufficiently small parameter variations; and necessary condition for optimal controller corresponding to point in boundary of domain of admissible parameter variations to be optimal insensitive controller.

Harvey, C. A.↗