Engineering topics

Naumann, R. J.

Publications and source records attributed to Naumann, R. J..

At least 19 records

NASA NTRS2009

Spacelab Science Results Study

Beginning with OSTA-1 in November 1981 and ending with Neurolab in March 1998, a total of 36 Shuttle missions carried various Spacelab components such as the Spacelab module, pallet, instrument pointing system, or mission peculiar experiment support structure. The experiments carried out during these flights included astrophysics, solar physics, plasma physics, atmospheric science, Earth observations, and a wide range of microgravity experiments in life sciences, biotechnology, materials science, and fluid physics which includes combustion and critical point phenomena. In all, some 764 experiments were conducted by investigators from the U.S., Europe, and Japan. The purpose of this Spacelab Science Results Study is to document the contributions made in each of the major research areas by giving a brief synopsis of the more significant experiments and an extensive list of the publications that were produced. We have also endeavored to show how these results impacted the existing body of knowledge, where they have spawned new fields, and if appropriate, where the knowledge they produced has been applied.

Naumann, R. J.↗

NASA NTRS2002

Reduction of Convection in Closed Tube Vapor Transport Experiments

The primary objective of this effort was to develop a method for suppressing convective flows during the growth of mercurous chloride crystals by vapor transport in closed tubes to levels approaching those obtained in the microgravity environment. Mercurous chloride was chosen because it is a technologically interesting acoustical optical material whose optical properties are believed to be affected by convective flows. Since the Grashof number scales as the cube of the smallest dimension in the flow system, reduction of the size scale can be extremely effective in reducing unwanted convective flows. However, since materials of practical interest must be grown at least on the cm scale, reduction of the overall growth system is not feasible. But if the region just above the growing crystal could be restricted to a few mm, considerable reduction in flow velocity would result. By suspending an effusive barrier in the growth ampoule just above the growth interface, it should be possible to reduce the convective velocity in this vicinity to levels approaching flows in microgravity. If successful, this growth technique will offer a screening test for proposed space experiments that involve vapor transport to see if reduction of convection will result in improved material and will set a new standard against which the improvements obtained in microgravity may be judged. In addition, it may provide an improved method for preparing materials on Earth whose growth is affected adversely by convection. If the properties of this material can be improved there is a potential commercial interest from Brimrose Inc., who has agreed to fabricate and test devices from the crystals we have grown. This report describes the development of the growth facility, the purification processes developed for preparing the starting material, and the results from growth experiments with and without the effusive baffle. Mercurous chloride turned out to be a more difficult material to deal with than originally anticipated. At growth temperatures, it is extremely sensitive to practically any impurity which causes it to form oxychlorides and/or to decompose into elemental mercury and bichloride of mercury. We were unable to find a suitable method for protecting the magnetic material used to suspend the effusion barrier from the attack of mercurous chloride vapor. Although we were successful in growing single crystals of mercurous chloride without the effusion baffle, they exhibited severe microcracking which we attribute to wall-induced thermal stresses. This leads us to believe that uncontrolled convection may not be the most important problem in the development of this material and a new growth process was attempted that eliminates the wall-induced stress. Unfortunately, the grant ran out before this new method could be adequately tested.

Naumann, R. J.↗

NASA NTRS1994

Protein crystal growth in microgravity: Temperature induced large scale crystallization of insulin

One of the major stumbling blocks that prevents rapid structure determination using x-ray crystallography is macro-molecular crystal growth. There are many examples where crystallization takes longer than structure determination. In some cases, it is impossible to grow useful crystals on earth. Recent experiments conducted in conjuction with NASA on various Space Shuttle missions have demonstrated that protein crystals often grow larger and display better internal molecular order than their earth-grown counterparts. This paper reports results from three Shuttle flights using the Protein Crystallization Facility (PCF). The PCF hardware produced large, high-quality insulin crystals by using a temperature change as the sole means to affect protein solubility and thus, crystallization. The facility consists of cylinders/containers with volumes of 500, 200, 100, and 50 ml. Data from the three Shuttle flights demonstrated that larger, higher resolution crystals (as evidenced by x-ray diffraction data) were obtained from the microgravity experiments when compared to earth-grown crystals.

Long, Marianna M.↗

NASA NTRS1986

Making Highly Pure Glass Rods

Proposed quasi-containerless method for making glass rods or fibers minimizes contact between processing equipment and product. Method allows greater range of product sizes and shapes than achieved in experiments on containerless processing. Molten zone established in polycrystalline rod. Furnace sections separated, and glass rod solidifies between them. Clamp supports solid glass as it grows in length. Pulling clamp rapidly away from melt draws glass fiber. Fiber diameter controlled by adjustment of pulling rate.

Naumann, R. J.↗

NASA NTRS1986

Theory of Ostwald ripening in a two-component system

When a two-component system is cooled below the minimum temperature for its stability, it separates into two or more immiscible phases. The initial nucleation produces grains (if solid) or droplets (if liquid) of one of the phases dispersed in the other. The dynamics by which these nuclei proceed toward equilibrium is called Ostwald ripening. The dynamics of growth of the droplets depends upon the following factors: (1) The solubility of the droplet depends upon its radius and the interfacial energy between it and the surrounding (continuous) phase. There is a critical radius determined by the supersaturation in the continuous phase. Droplets with radii smaller than critical dissolve, while droplets with radii larger grow. (2) The droplets concentrate one component and reject the other. The rate at which this occurs is assumed to be determined by the interdiffusion of the two components in the continuous phase. (3) The Ostwald ripening is constrained by conservation of mass; e.g., the amount of materials in the droplet phase plus the remaining supersaturation in the continuous phase must equal the supersaturation available at the start. (4) There is a distribution of droplet sizes associated with a mean droplet radius, which grows continuously with time. This distribution function satisfies a continuity equation, which is solved asymptotically by a similarity transformation method.

Baird, J. K.↗

NASA NTRS1986

Exploiting the Vacuum of Space

Molecular-beam epitaxy and other processes tested with minimal contamination. Vacuum experimental facility for outer space creates vacuums higher than those available in terrestrial vacuum chambers. Facility minimizes contamination of work from walls and allows rapid removal of gases and heat generated by experimental processes. Used for processes such as molecular-beam epitaxy (growing semiconductor superlattices), metal/organic chemical vapor deposition, coating mirrors and other optical components, and ultrapurification.

Naumann, R. J.↗

NASA NTRS1986

Containerless glass fiber processing

An acoustic levitation furnace system is described that was developed for testing the feasibility of containerless fiber pulling experiments. It is possible to levitate very dense materials such as platinum at room temperature. Levitation at elevated temperatures is much more difficult. Samples of dense heavy metal fluoride glass were levitated at 300 C. It is therefore possible that containerless fiber pulling experiments could be performed. Fiber pulling from the melt at 650 C is not possible at unit gravity but could be possible at reduced gravities. The Acoustic Levitation Furnace is described, including engineering parameters and processing information. It is illustrated that a shaped reflector greatly increases the levitation force aiding the levitation of more dense materials.

Ethridge, E. C.↗

NASA NTRS1986

Containerless high purity pulling process and apparatus for glass fiber

Apparatus and method for pulling optical glass fibers in a containerless environment is disclosed which includes a single axis acoustical levitation furnace in which a specimen is levitated and melted. A reflector unit is carried in the interior of the furnace and includes a reflector disposed centrally about the acoustical axis of the levitator. The reflector unit includes a circular shroud of insulation and a copper sleeve inserted in the unit which is hollow at for receiving a cooling medium. A fiber pulling bore is formed centrally in the reflector unit surrounded by cooling jacket to enhance solidification and formation of a fiber. A starting fiber strand is introduced into the melt and pulled outwardly through bore whereby the specimen fiber is started and formed as pulled therethrough. In order to replenish the melt and thus enable a continous process, a movable secondary reflector is provided which captures a supplemental specimen pellet and by movement of the reflector transfers it to the melt.

Naumann, R. J.↗

NASA NTRS1986

Materials sciences in space

A summary is presented of recent theoretical and experimental examinations of materials processing methods in microgravity conditions. The discussion covers Skylab and Spacelab flights, rocket and parabolic flights, and drop tube experiments. Attention is given to crystal growth, fluid physics, metallurgical and electrophoresis experiments.

Feuerbacher, B.↗

NASA NTRS1986

Historical development

The history of the U.S. Microgravity Science and Applications program is summarized, noting significant discoveries in the first decade of the program. The experiments were performed to understand the behavior of liquid propellants (and other fluids), liquid melt zones, and containerless liquid suspension systems in microgravity. Investigations were carried out with a drop tower, on KC-135 and solid rocket flights, and during Apollo, Skylab and Apollo-Soyuz missions.

Naumann, R. J.↗

NASA NTRS1986

Containerless processing technology

Ground- and space-based containerless processing levitation devices are described. Experiments performed in the MSFC drop tube, the JPL drag-free drop facilities, a single-axis tuned cavity acoustic levitator furnace on TEXUS-I, and a three-axis acoustic levitator and furnace on the STS-11 mission are discussed. Neither acoustic interference nor aerodynamic levitation trials have yielded promising results in sounding rocket and STS based experiments. An electrostatic levitator has furnished a high degree of positioning control with multiple objects in a terrestrial laboratory.

Naumann, R. J.↗

NASA NTRS1985

Space shuttle molecular and wake vacuum measurements

The wake environment of the space shuttle is analyzed to determine whether it is feasible to perform ultrahigh vacuum experiments in or near the payload bay with the shuttle oriented such that the payload bay faces the antivelocity direction. Several mechanisms were considered by which molecules could approach the payload bay from this direction and their relative contributions to the wake environment are estimated. These mechanisms include ambient atmospheric molecules that have velocities in excess of the orbital velocity which can overtake the shuttle, ambient atmospheric molecules that are backscattered by collisions with the shuttle induced atmosphere, and self scattering from the induced atmosphere. These estimates are compared with the measurements made with the collimated mass spectrometer which was part of the Induced Environment Contamination Monitor flown on several of the early shuttle flights. Although the collimated mass spectrometer was not designed for this purpose and the instrument background for the species for which the collimator is effective is above the expected levels, upper limits can be established for these species in the wake environment which are consistent with the analysis. There was considerably more helium and argon observed in the wake direction than was predicted, however. Possible origins of these gases are discussed.

Naumann, R. J.↗

NASA NTRS1985

Containerless Manufacture of Glass Optical Fibers

Contamination and crystallization reduced in proposed process. Solid optical fiber drawn from an acoustically levitated lump of molten glass. New material added in solid form, melted and then moved into main body of molten glass. Single axis acoustic levitation furnances levitate glass melts at temperature up to about 700 degrees C. Processing in unit limited to low-melting temperature glasses.

Naumann, R. J.↗

NASA NTRS1984

One-dimensional thermal modeling of vertical Bridgman-type crystal growth

Articles by Naumann (1982) and Jasinski et al. (1983) examined the axial temperature distribution of the charge during vertical Bridgman-type crystal growth. A comparison of their results demonstrates that Naumann's model is applicable for K (ratio of crucible to charge thermal conductivity) equal to or greater than 1 or for small Biot numbers. The Jasinski model provides a correction for larger Biot numbers and is also applicable for small values of K.

Jasinski, T.↗

NASA NTRS1983

Homogeneous nucleation kinetics

Homogeneous nucleation kinetics are rederived in a manner fundamentally similar to the approach of classical nucleation theory with the following modifications and improvements. First, the cluster is a parent phase cluster and does not require energization to the parent state. Second, the thermodynamic potential used to describe phase stability is a continuous function along the pathway of phase decomposition. Third, the kinetics of clustering corresponds directly to the diffusional flux of monomers through the cluster distribution and are formally similar to classical theory with the resulting kinetic equation modified by two terms in the preexponential factor. These terms correct for the influence of a supersaturation dependent clustering within the parent phase and for the influence of an asymmetrical cluster concentration as a function of cluster size at the critical cluster size. Fourth, the supersaturation dependence of the nucleation rate is of the same form as that given by classical nucleation theory. This supersaturation dependence must however be interpreted in terms of a size dependent surface tension. Finally, there are two scaling laws which describe supersaturation to either constant nucleation rate or to the thermodynamically determined physical spinodal.

Rasmussen, D. H.↗

NASA NTRS1983

Effect of variable thermal conductivity on isotherms in Bridgman growth

A change in thermal conductivity associated with melting or solidification can have a profound influence on the isotherms near the solidification interface if the material is being directionally solidified in an ampoule whose walls carry a substantial portion of the heat. This analysis was prompted by a recent discovery that the thermal conductivity of Hg(1-x)CD(x)Te increased dramatically as the material is heated above the solidus curve. An illustrative example is shown in which the sample is approximated as an infinite cylinder with constant but diffferent thermal properties in the solid and melt. The boundary conditions are fixed on the surface by a conductive ampoule in a two-zone Bridgman furnace with an adiabatic region separating the two zones. The effect of the adiabatic zone in this case is to intensify the curvature of the interface rather than to lessen it.

Naumann, R. J.↗

NASA NTRS1982

Materials Processing in Space

A report describes investigations of materials processing in low-gravity environment. Ultimately, research could lead to new commercially-applicable materials and processes and to an understanding of constraints imposed by gravity. NASA-supported work is carried out in 46 academic, industrial, and Government laboratories, and covers a number of areas. An overview is given of objective and current state of development for over 100 tasks.

Naumann, R. J.↗

NASA NTRS1982

An analytical approach to thermal modeling of Bridgman-type crystal growth. I - One-dimensional analysis

A relatively simple one-dimensional thermal model of the Bridgman growth process has been developed which is applicable to the growth of small diameter samples with conductivities similar to those of metallic alloys. The heat flow in a translating rod is analyzed in a way that is applicable to Biot numbers less than unity. The model accommodates an adiabatic zone, different heat transfer coefficients in the hot and cold zones, and changes in sample material properties associated with phase change. The analysis is applied to several simplified cases. The effect of the rod's motion is studied in a three-zone furnace for a rod sufficiently long that end effects can be neglected; end effects are then investigated for a motionless rod. Finally, the addition of a fourth zone, an independently controlled booster heater between the main heater and the adiabatic zone, is evaluated for its ability to increase the gradient in the sample at the melt interface and to control the position of the interface.

Naumann, R. J.↗