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Odukomaiya, Adewale

Publications and source records attributed to Odukomaiya, Adewale.

5 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Open-cycle thermochemical energy storage for building space heating: Practical system configurations and effective energy density

Salt-hydrate thermochemical materials (TCM) are promising candidates for energy storage systems for building space heating due to their high theoretical energy density and the need for low regeneration temperature. However, water vapor is required to drive the hydration process of the TCM reactor, which poses a challenge during winter when water vapor is typically scarce. Using indoor air directly lowers the building's humidity to an unconformable level in practice, while the cold outdoor air contains limited moisture. Here we consider different integration strategies for open-cycle TCM reactors in buildings and develop a model to simulate their thermal performance across diverse buildings and climates, specifically for building space heating. The potential energy densities and the levelized cost of storage of the TCM reactor are evaluated in practical scenarios to demonstrate the load-shifting potential of TCM systems for heating applications. We use a strontium chloride (SrCl 2 )-based composite as the baseline and explore the impact of various reactor and material changes to the energy density and levelized cost of storage.

25 ENERGY STORAGE↗
DOE OSTI2024

Thermal battery cost scaling analysis: minimizing the cost per kW h

Thermal and cost-scaling analyses provide the tools to optimize the geometry of thermal batteries based on cost. Figures-of-merit comprised of storage material properties are derived as the quantities that should be maximized when different components dominate cost.

25 ENERGY STORAGE↗
DOE OSTI2024

Enabling thermal energy storage in structural cementitious composites with a novel phase change material microcapsule featuring an inorganic shell and a bio-inspired silica coating

Phase change material (PCM) microcapsules offer a promising approach for integrating PCM into building materials for efficient thermal energy storage. Here, this study presents the development of a novel PCM microcapsule specifically designed for incorporation into cementitious materials. The microcapsule consists of a low-cost PCM core derived from vegetable oil by-products and a durable inorganic shell made from cenosphere, a hollow fly ash generated from coal burning power plants. A novel process is developed to apply a silica coating to these cenosphere-based PCM microcapsules (CPCM), resulting in bioinspired-silica-coated CPCM microcapsules (BCPCM). This coating process draws inspiration from marine microorganism-based silica production and utilizes low-cost sodium silicate as a precursor, enabling eco-friendly and cost-effective manufacturing at ambient temperature and mild pH conditions. The morphology, chemical stability, and thermal properties of the BCPCM along with its thermo-mechanical performance in cementitious composites were comprehensively analyzed. Experimental results demonstrate successful silica deposition on BCPCM, leading to enhanced latent heat properties of the produced BCPCM. With the silica coating, BCPCM exhibits a 50 °C delay in thermal decomposition compared to CPCM, enhancing fire resistance and preventing premature PCM leakage of the microcapsule. The bioinspired silica coating effectively restores over 10% of the strength loss for each percent increase in CPCM incorporated into the mortar. The thermal performance experiments reveal that increasing the BCPCM content reduces temperature peaks and rates of temperature increase, indicating an improved capacity for thermal energy storage. This new PCM microcapsule provides a cost-effective solution to integrate thermal energy storage to cementitious material, as evidenced that over 30% of aggregates (in volume) can be replaced by the microcapsule without a drastic loss of strength.

25 ENERGY STORAGE↗
DOE OSTI2023

The impact of non-ideal phase change properties on phase change thermal energy storage device performance

Phase change materials have been known to improve the performance of energy storage devices by shifting or reducing thermal/electrical loads. While an ideal phase change material is one that undergoes a sharp, reversible phase transition, real phase change materials do not exhibit this behavior and often have one or more non-idealities – glide, hysteresis, supercooling – associated with them. Experimental and modeling techniques to characterize these non-ideal properties are reasonably well understood, however, their impact on the performance of a thermal energy storage system is not fully understood. Herein, we analyze the performance of a heat exchanger with a phase change material as a function of the different non-idealities, for a heating and a cooling application. We focus on the impact of these non-ideal behaviors on different modes of operation of the thermal energy storage device, which will serve as a useful guide to researchers on the relative importance of the non-ideal properties, along with the necessary accuracy required during an experimental characterization.

25 ENERGY STORAGE↗