Engineering topics
Publications and source records attributed to Prinz, M..
We report mineral-chemical and Secondary Ion Mass Spectrometry (SIMS) oxygen-isotopic studies of forsteritic olivine grains from various Unequilibrated Ordinary Chondrites (UOCs). Our studies provide additional evidence for a genetic link between ordinary and carbonaceous chondrites and between various lithologies in these meteorites.
Kaidun is a remarkable chondrite breccia fall containing lithic clasts that span a wide range of chondrite groups including C and E chondrites, as well as having clasts with characteristics not yet found in existing chondrite samples. The dominant lithology in Kaidun appears to be CR chondritic, consonant with recent O isotope data. The carbonates in Kaidun are presented as one mineralogical basis for comparing it to the other hydrated chondrites and to better understand its relative alteration history. The four polished thin sections of Kaidun studied contained a variety of lithologies that we classified into four groups -- CR, E, CM-like, and dark inclusions (DIs). DIs contain sulfide and magnetite morphologies that superficially resemble CI chondrites, and some of the previously reported CI lithologies in Kaidun may be what we term DIs. Carbonates were found in all lithologies studied. Carbonates in Kaidun are similar in composition to those in CR chondrites. Some of the DIs in Kaidun, previously characterized as CI, have carbonates similar to those in CR chondrites and are unlike those in CI or CM chondrites. Most carbonates in Kaidun and CR chondrites are calcites, some of which formed at temperatures above 250 C. Dolomite is less common and some may be metastable. Alteration temperatures in the Renazzo CR chondrite were estimated to be approximately 300 C, based on O isotope fractionation between phyllosilicates and magnetite. Temperatures of up to 450 C were proposed for the alteration of a CR-like dark inclusion in Kaidun, based on the presence of hydrothermal pentlandite veins. The alteration temperatures for Kaidun and the other CR chondrites are considerably higher than those suggested for CI or CM parent bodies.
Chondrules can be divided into two broad textural types: porphyritic and nonporphyritic. Porphyritic chondrules are the most common in most chondrites and range texturally from olivine-rich (PO) to intermediate (POP) to pyroxene-rich (PP). Barred olivine (BO) chondrules can be considered a special case of porphyritic. Compositionally they can be divided into type I and II. Nonporphyritic are less abundant than porphyritic chondrules in most chondrites -- they make up approximately 125% of the chondrules in ordinary chondrites -- and range texturally from glassy (g) to cryptocrystalline (C) to radial pyroxene (RP). Compositionally nonporphyritic differ from porphyritic chondrules and within this group they are very similar to one another. Here we (1) review and contrast the characteristics of the nonporphyritic and porphyritic chondrules; (2) specify some of the problems associated with the origins of the textural and compositional differences between them; and (3) suggest a possible scenario for their origin, which may have important implications for the evolution of chondrules.
There is considerable evidence that chondrules formed by the melting of solid materials and, by default, the early solar nebula is the preferred location for chondrule formation. Agglomeratic olivine (AO) chondrules supply perhaps the most intriguing, direct evidence for chondrule formation from agglomeration of solids. We review the characteristics of AO chondrules and discuss their implications for understanding chondrule precursors and chondrule evolution.
The genetic relationships between the petrology, hydration reactions, and isotopic oxygen composition in the Belgica 7904 (B7904) carbonaceous chondrite, and the relationship between B7904 and the CM and CI chondrites were investigated by characterizing seven components separated from B7904. The seven specimens included two partially altered chondrules, two phylosilicate clasts, two olivine fragments, and one matrix sample. The results of the analyses and thermodynamic calculations suggest that CI chondrites may have been produced in a two-stage alteration process from materials similar to that of the B7904 matrix, by reactions with liquid water in their parent body. The common CM chondrites may have undergone aqueous alteration in the parent body, in addition to hydration in the nebula, resulting in two-stage alterations; the parent body may have been different from that of B7904.
LEW85332, originally described as a unique C3 chondrite, was shown to be a C2 chondrite with important linkages to the CR clan. An important petrologic aspect of LEW85332 is that it contains anhydrous chondrules and hydrated matrix, and new oxygen isotopic data on chondrules, matrix and whole rock are consistent with the petrology. Chondrules fall on the equilibrated chondrite line (ECL), with a slope near 1, which goes through ordinary chondrite chondrules. This contrasts with the CR chondrule line which has a lower slope due to hydrated components. LEW85332 chondrules define a new carbonaceous chondrite chondrule line, parallel to the anhydrous CV chondrule line (CCC), consistent with the well-established concept of two oxygen isotopic reservoirs. Matrix and whole rock fall on the CR line. The whole rock composition indicates that the chondrite is dominated by chondrules, and that most of them contain light oxygen similar to that of anhydrous olivine and pyroxene separates in the Renazzo and Al Rais CR chondrites.
Enstatite (En) chondrites record the most reducing conditions known in the early solar system. Their oxidation state may be the result of condensation in a nebular region having an enhanced C/O ratio, reduction of more oxidized materials in a reducing nebula, reduction during metamorphic reheating in a parent body, or a combination of these events. The presence of more oxidized Fe-rich silicates, two types of En (distinguished by red and blue CL), and the juxtaposition of FeO-rich pyroxenes (Fe-pyx) surrounded by blue En (enstatite) in the UEC's (unequilibrated enstatite chondrites) is intriguing and led to the examination of the question of enstatite chondrite formation. Previously, data was presented on the petrologic-geochemical characteristics of the Fe-pyx and coexisting red and blue En. Here minor and trace element abundances (determined by ion probe-SIMS) on these three types of pyroxenes are reported on in the following meteorites: Kota Kota and LEW87223 (EH3), MAC88136 (EL3), St. Marks (EH4), and Hvittis (EL6). More data are currently being collected.
The presence of dark lithic clasts within meteorites can provide information concerning asteroidal regolith processes, the extent of interactions between asteroids, and the relationship between meteorite types, micrometeorites, and interplanetary dust particles. Accordingly, we have been seeking and characterizing dark clasts found within carbonaceous chondrites, unequilibrated ordinary chondrites, howardites, and eucrites. We find that unequilibrated chondrites in this study contain fine-grained, anhydrous unequilibrated inclusions, while the howardites often contain inclusions from geochemically processed, hydrous asteroids (type 1 and 2 carbonaceous chondrites). Eucrites and howardities contain unusual clasts, not easily classified.
A stony meteorite found in Antarctica in 1985, recently identified as a type of chondrite, probably represents material from a previously unsampled region of the solar system. Scientists are currently debating how the object formed. Preliminary results on Allan Hills 85085 (ALH85085) were presented.
Results form the Antarctic sample, LEW 86010 indicate that it is an extremely interesting meteorite of clear igneous origin, and is probably closely related to ADOR. Several important questions await further detailed study. The most stringent test of the relationship to ADOR will come from the measurement of the oxygen isotopic composition. One possibility proposed is that LEW 86010 represents a partial or total melt of a mixture of material similar to the white Allende clasts and more ordinary chondritic meteorite material. Several lines of investigation will contribute to resolve this question. Further melting studies will be performed to determine whether LEW 86010 represents molten lava. In addition to test the connection with Allende, isotopic studies will look for anomalous isotopic compositions which are ubiquitous in Allende white inclusions. All of these studies will be performed on a tiny sample which weights only 5 grams, and is smaller than a marble, but which contains important clues to events which occurred during the birth of the solar system.
Trace element analyses using proton induced X-ray emission and synchrotron X-ray fluorescence have been made on metal and troilite from nine iron meteorites representing five geochemical groups. Nickel and copper distribution coefficients D (troilite/metal) vary by factors of 600 and 20, respectively, correlate positively with kamacite bandwidth and correlate negatively with bulk nickel content. Meteorites with bulk Ni of less than 10 percent have Cu-enriched troilite while those with Ni greater than 10 percent have Cu-depleted troilite. Since magmatic evolution and partial melting will produce Cu-enriched troilite only, the observation of Cu-depleted troilite in Ni-rich meteorites is evidence for subsolidus reequilibration, a process which reduces D(Cu) by transfer of Cu to exsolving metal. Elemental redistribution may have played an important role in establishing the present chemical trends in iron meteorites.
Previous studies of the newly classified polymict basaltic meteorites, the polymict eucrites (PE), are reviewed to synthesize their significance in extraterrestrial volcanism investigations. The PE breccias contain mafic clasts of euritic or basalt materials in different proportions than found in howardites. Comparisons are made of the eucrite suites in PEs, howardites, eucrites, cumulative eucrites and diogenites. The PEs and the howardites are found to be part of a continuum of basaltic achondrite polymict breccia. The basaltic clasts cooled rapidly at the surface of the PEs and are accompanied by larger-cooling deep crustal materials. Some PEs are regolith breccias that have been exposed to the solar wind, which affected the rare gas contents. It is suggested that the more-than-38 specimens found in Antarctica represent only six or eight different meteorites.
Mineralogical examination of thin sections of non-Antarctic and Antarctic HED (howardite, eucrite, diogenite) achondrites indicates that they contain a variety of lithic components. Some of these components occur both as monomict meteorites and as clasts in polymict meteorites, whereas others occur only as clasts in some polymict breccias. The components may be classified by the degree of homogenization of the pyroxene present. In order of increasing homogeneity these are: (1) Y-75011-type basalt clasts; (2) Pasamonte; (3) Y-790266-type clasts; (4) Stannern and Nuevo Laredo; (5) Juvinas and Haraiya; and (6) Ibitira. Type 1 has been least modified by post-igneous thermal annealing, while types 5 and 6 were thoroughly metamorphosed. Three types of cumulate eucrites are recognized and are believed to represent (a) cumulates from thick lava flows or layered intrusions; (b) lunar highlands type crust; and (c) differentiation products of diogenitic magmas.
Seven Yamato and six Allan Hills polymict eucrite specimens were compared by modal analysis. The analyses reveal differences of plagioclase and pyroxene content between the two groups. The Yamato suite has more 'pigeonitic' pyroxene and less plagioclase and low-calcium pyroxene than the Allan Hills suite. Variations within each suite are small and three sections of Allan Hills A78040 are more variable than the Allen Hills suite considered as a group. Modal data provides a basis for pairing polymict eucrite specimens when used together with mineralogical and petrographic criteria. Modal data furthermore confirms the presence of several rock types previously identified using pyroxene crystallography and hints at the presence of an augite-rich component.
The results of a study of the small achondrite found in 1974 near Brachina, Australia are presented and discussed. Trace element data for Brachina were found to be quite different from that for Chassigny. The major differences are higher FeO/MnO, Ge/Al, and K/La ratios, W depletion, high siderophile content, near-horizontal REE pattern at about 1 x chondrite level, high refractory/nonrefractory metal ratios (e.g., Ir/Au), and chalcophile element depletion. Brachina's 4.5 billion year age and oxygen isotropic signature within the eucritic field further suggest that it is not related to Chassigny or SNC meteorites, though it may be related to primitive meteorites, such as silicate inclusions in IAB irons and winonaites.
New interior samples of four Yamato polymict eucrites (Y74159, Y74450, Y75011, and Y75015) have been studied by electron microprobe, transmission electron microscope, and X-ray diffraction techniques, and compared with several samples of the Victoria Land polymict eucrites. These same samples have been analysed using Rb-Sr and Nd-Sm isotopic systematics. Several grains of inverted pigeonite, with blebby augite similar to those in Binda and Moama, have been identified in all four Yamato eucrites. Coarse-grained meso-stasis-rich subophitic basalts, which contain Mg-rich pigeonite (with Fe-rich olivine veinlets) zoned outward to a subcalcic ferroaugite rims, have also been found. These unique clasts were not found in ALH76005, 77302, 78040, 7858, and 78165 and EET eucrites. The tight grouping of Rb/Sr and Sm/Nd ratos, and similar modal compositions of the Yamato group indicate that they are most likely to be pieces from a single fall, and distinct from the ALH and EET groups. However, the Yamato, Allan Hills, and Elephant Moraine groups may sample a few distinct magmas or similar but different source regions on the same parent body.
Iron meteorites with oxygen-bearing phases can be classified in terms of their oxygen isotopic abundances. These iron meteorite classes are isotopically similar to various stony meteorite classes, which may indicate a common origin. The group IAB and IIICD irons may be related to the winonaites; group IIE irons may be related to H chondrites; group IVA irons may be related to L or LL chondrites.
The system of nomenclature for basaltic achondrite meteorites is discussed, and new classification criteria are proposed. Under the new system, all achondrites are divided intno the broad groupings 'monomict' and 'polymict' by the number of lithologies present. The monomicts are classified structurally as brecciated or unbreccciated and as eucrites, diogenites, or cumulate eucrites. The polymicts are classified using an arbitrary mineral-chemical standard based on the percentage content of diogenite (magnesium orthopyroxenite): diogenites have more than 90 percent, eucrites have less than 10 percent, and all other polymicts area howardites. Tables listing all known achondrites by classification are provided.