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R. Subramanian

Publications and source records attributed to R. Subramanian.

Low-Cost Sensor Performance Intercomparison, Correction Factor Development, and 2+ Years of Ambient PM2.5 Monitoring in Accra, Ghana

Particulate matter air pollution is a leading cause of global mortality, particularly in Asia and Africa. Addressing the high and wide-ranging air pollution levels requires ambient monitoring, but many low- and middle-income countries (LMICs) remain scarcely monitored. To address these data gaps, recent studies have utilized low-cost sensors. These sensors have varied performance, and little literature exists about sensor intercomparison in Africa. By colocating 2 QuantAQ Modulair-PM, 2 PurpleAir PA-II SD, and 16 Clarity Node-S Generation II monitors with a reference-grade Teledyne monitor in Accra, Ghana, we present the first intercomparisons of different brands of low-cost sensors in Africa, demonstrating that each type of low-cost sensor PM2.5 is strongly correlated with reference PM2.5, but biased high for ambient mixture of sources found in Accra. When compared to a reference monitor, the QuantAQ Modulair-PM has the lowest mean absolute error at 3.04 μg/m3, followed by PurpleAir PA-II (4.54 μg/m3) and Clarity Node-S (13.68 μg/m3). We also compare the usage of 4 statistical or machine learning models (Multiple Linear Regression, Random Forest, Gaussian Mixture Regression, and XGBoost) to correct low-cost sensors data, and find that XGBoost performs the best in testing (R2: 0.97, 0.94, 0.96; mean absolute error: 0.56, 0.80, and 0.68 μg/m3 for PurpleAir PA-II, Clarity Node-S, and Modulair-PM, respectively), but tree-based models do not perform well when correcting data outside the range of the colocation training. Therefore, we used Gaussian Mixture Regression to correct data from the network of 17 Clarity Node-S monitors deployed around Accra, Ghana, from 2018 to 2021. We find that the network daily average PM2.5 concentration in Accra is 23.4 μg/m3, which is 1.6 times the World Health Organization Daily PM2.5 guideline of 15 μg/m3. While this level is lower than those seen in some larger African cities (such as Kinshasa, Democratic Republic of the Congo), mitigation strategies should be developed soon to prevent further impairment to air quality as Accra, and Ghana as a whole, rapidly grow.

Humidity↗

Characterizing the Aging of Alphasense NO2 Sensors in Long-term Field Deployments

Low-cost NO2 sensors have been widely deployed for atmospheric sampling. While their initial performance has been characterized, few studies have examined their long-term degradation. This study focused on the performance of Alphasense low-cost NO2 sensors (NO2-B42F and NO2-B43F) over 4 years (2016–2020). A total of 29 NO2 sensors from 10 batches were collocated 78 times at two sites with reference instruments. Raw signals from “functional” NO2 sensors correlated linearly with reference NO2 concentrations. After long-term deployment, sensor raw signals started to deviate from reference NO2 concentrations due to sensor aging, an accumulated effect after sensor unpacking. Several sensors eventually became “non-functional” as sensor raw signals showed no correlation with reference NO2 concentrations. Sensor aging and non-functionality may be primarily caused by expiration of the ozone (O3) scrubber built into these sensors so that sensors responded to both ambient NO2 and O3. The influence of O3 on sensor response is quantified through the permutation importance method. Most of the sensors are non-functional after approximately 200–400 days of deployment, and no sensor was functional after 400 days of deployment. This result agrees well with the estimated lifetime of the built-in ozone scrubbers considering the ambient ozone concentration in the Pittsburgh area where these sensors were deployed. To ensure reliable data quality in long-term field deployments, we recommend collocating NO2 sensors with reference instruments regularly after 200–400 days of deployment to identify and replace non-functional sensors in a timely manner.

NO2sensors↗

From Low-Cost Sensors to High-Quality Data: A Review of Challenges and Summary of Best Practices for Effectively Using Low-Cost Particulate Matter Mass Sensors

Low-cost sensors for particulate matter mass (PM) enable spatially dense, high temporal resolution measurements of air quality that traditional reference monitoring cannot. Low-cost PM sensors are especially beneficial in low and middle-income countries where few, if any, reference grade measurements exist and in areas where the concentration fields of air pollutants have significant spatial gradients. Unfortunately, low-cost PM sensors also come with a number of challenges that must be addressed if their data products are to be used for anything more than a qualitative characterization of air quality. The various PM sensors used in low-cost monitors are all subject to biases and calibration dependencies, corrections for which range from relatively straightforward(e.g. meteorology, age of sensor) to complex (e.g. aerosol source, composition, refractive index). The methods for correcting and calibrating these biases and dependencies that have been used in the literature likewise range from simple linear and quadratic models to complex machine learning algorithms. Here we review the needs and challenges when trying to get high-quality data from low-cost sensors. We also present a set of best practices to follow to obtain high-quality data from these low-cost sensors.

low-cost sensors↗

First Measurements of Ambient PM2.5 in Kinshasa, Democratic Republic of Congo and Brazzaville, Republic of Congo Using Field-calibrated Low-cost Sensors

Estimates of air pollution mortality in sub-Saharan Africa are limited by a lack of surface observations of fine particulate matter (PM2.5). Despite being large metropolises, Kinshasa, Democratic Republic of the Congo (DRC), population 14.3 million, and Brazzaville, Republic of the Congo (ROC), population 2.4 million, have no reference air pollution monitors at the time of writing. Recently, a few reference monitors have been deployed in other parts of sub-Saharan Africa, including Kampala, Uganda. A low-cost PurpleAir PM2.5 monitor was collocated next to the Kampala US Embassy BAM-1020 (Met One Beta Attenuation Monitor) starting in August 2019. Raw PurpleAir data are strongly correlated with the BAM (r(exp 2) = 0.88), but have a mean absolute error of approximately 14 μg/cu.m. Two calibration models, multiple linear regression and a random forest approach, decrease mean absolute error (MAE) from 14.3 μg/cu.m to 3.4 µg/cu.m or less and improve the the r(exp 2) from 0.88 to 0.96. Given )the similarity in climate and emissions in Kampala, we apply the collocated field correction factors to four PurpleAir sensors in Kinshasa, DRC and one in neighboring Brazzaville, ROC deployed beginning April 2018. Annual average PM2.5 for 2019 in Kinshasa is estimated at 43.5 µg/cu.m, more than 4 times higher than WHO Interim Target 1 of 10 µg/cu.m. Surface PM2.5 and aerosol optical depth were each about 40% lower during the 2020 COVID19 lockdown period compared to the same time period in 2019, which cannot be explained by changes in meteorology or wildfire emissions alone. Our results highlight the need for clean air solutions implementation in the Congo.

Celeste McFarlane↗

Application of Low-Cost Fine Particulate Mass Monitors to Convert Satellite Aerosol Optical Depth Measurements to Surface Concentrations in North America and Africa

Low-cost particulate mass sensors provide opportunities to assess air quality at unprecedented spatial and temporal resolutions. Established traditional monitoring networks have limited spatial resolution and are simply absent in many major cities across sub-Saharan Africa (SSA). Satellites provide snapshots of regional air pollution but require ground-truthing. Low-cost monitors can supplement and extend data coverage from these sources worldwide, providing a better overall air quality picture. We investigate the utility of such a multi-source data integration approach using two case studies. First, in Pittsburgh, Pennsylvania, both traditional monitoring and dense low-cost sensor networks are compared with satellite aerosol optical depth (AOD) data from NASA's MODIS system, and a linear conversion factor is developed to convert AOD to surface fine particulate matter mass concentration (as PM2.5). With 10 or more ground monitors in Pittsburgh, there is a 2-fold reduction in surface PM2.5 estimation mean absolute error compared to using only a single ground monitor. Second, we assess the ability of combined regional-scale satellite retrievals and local-scale low-cost sensor measurements to improve surface PM2.5 estimation at several urban sites in SSA. In Rwanda, we find that combining local ground monitoring information with satellite data provides a 40 % improvement in surface PM2.5 estimation accuracy with respect to using low-cost ground monitoring data alone. A linear AOD-to-surface-PM2.5 conversion factor developed in Kigali, Rwanda, did not generalize well to other parts of SSA and varied seasonally for the same location, emphasizing the need for ongoing and localized ground-based monitoring, which can be facilitated by low-cost sensors. Overall, we find that combining ground-based low-cost sensor and satellite data, even without including additional meteorological or land use information, can improve and expand spatiotemporal air quality data coverage, especially in data-sparse regions.

AOD↗