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Robinson, M. S.

Publications and source records attributed to Robinson, M. S..

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Following excited-state chemical shifts in molecular ultrafast x-ray photoelectron spectroscopy

The conversion of photon energy into other energetic forms in molecules is accompanied by charge moving on ultrafast timescales. We directly observe the charge motion at a specific site in an electronically excited molecule using time-resolved x-ray photoelectron spectroscopy (TR-XPS). We extend the concept of static chemical shift from conventional XPS by the excited-state chemical shift (ESCS), which is connected to the charge in the framework of a potential model. This allows us to invert TR-XPS spectra to the dynamic charge at a specific atom. We demonstrate the power of TR-XPS by using sulphur 2p-core-electron-emission probing to study the UV-excited dynamics of 2-thiouracil. The method allows us to discover that a major part of the population relaxes to the molecular ground state within 220–250 fs. In addition, a 250-fs oscillation, visible in the kinetic energy of the TR-XPS, reveals a coherent exchange of population among electronic states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2020

The Role of Solar Wind Hydrogen in Space Weathering: Insights from Laboratory-Irradiated Northwest Africa 12008

Micrometeoroid impacts, solar wind plasma interactions, and regolith gardening drive the complicated and nuanced mechanism of space weathering (or optical maturation); a process by which a material’s optical properties are changed as a result of chemical and physical alterations at the surface of grains on airless bodies. Reddened slopes, attenuated absorption bands, and an overall reduction in albedo in the visible and near-IR wavelength ranges are primarily the result of native iron nanoparticle (npFe0) production within glassy rims that form from sputtering and vaporization. The sizes and abundance of these particles provide information about the relative surface exposure age of a particular grain. In addition, many studies have indicated that composition greatly affects the rate at which optical maturation occurs. Despite our understanding of how npFe0 affects optical signatures, the relative roles of micrometeoroid bombardment and solar wind interactions remains undetermined. To simulate the early effects of weathering by the solar wind and to determine thresholds for optical change with respect to a given mineral phase, we irradiated a fine-grained lunar basalt with 1 keV H+ to a fluence of 6.4 x 1016 H+ per sq.cm. Surface alterations within four phases have been evaluated using transmission electron microscopy (TEM). We found that for a given fluence of H+, the extent of damage acquired by each grain was dependent on its composition. No npFe(0) was produced in any of the phases evaluated in this study. These results are consistent with many previous studies conducted using ions of similar energy, but they also provide valuable information about the onset of space weathering and the role of the solar wind during the early stages of optical maturation.

Shusterman, M. L.↗
NASA NTRS2017

Young Lunar Volcanism: Irregular Mae Patches as Drained Lava Ponds and Inflated Flows

Irregular mare patches (IMPs) were previously proposed as sites of young lunar volcanism and/or endogenic activity [1-3], raising the possibility that volcanism on the Moon may not have ended approximately 1 Ga as determined from surface ages [4]. The wide-spread occurrence of more than 70 IMPs on the lunar nearside suggests a correlation with Th-rich PKT regions and a basaltic composition [1,2]. IMPs exhibit at least two types of deposit morphologies: (a) dome-like, steep-sided and smooth mounds and (b) low-relief ropy (LRR) to hummocky (LRH) materials (Fig. 1). Morphologic indicators such as steep (>40 deg) margin slopes across distances <10 m and crisp boundaries imply ages less than a few 100 Ma [e.g.,1-3]. The IMPs also have relatively few superposed craters >10 m in diameter, and young absolute model ages, which when combined with their superposition on young crater deposits like the continuous ejecta of Aristarchus crater, imply ages approximately 10 Ma to 100 Ma [1,2]. However, the mounds do not exhibit blocky crater morphologies, nor fracturing typical of young volcanic deposits, and the mound texture resembles that of mature regolith [e.g., 2,5], implying a much older age (approximately 3.5 Ga). These contrasting indicators have led to the proposal of widely varying formation mechanisms that range from ancient volcanism modified by recent tectonism [6] or outgassing [3,7], ancient volcanism of atypical materials [8], to Copernican-era volcanism [1,2].

Stopar, J. D.↗
NASA NTRS2017

Searching for Water Ice at the Lunar North Pole Using High-Resolution Images and Radar

Permanently shadowed regions (PSRs) at the lunar poles are potential reservoirs of frozen volatiles, and are therefore high-priority exploration targets. PSRs trap water and other volatiles because their annual maximum temperatures (40-100K) are lower than the sublimation temperatures of these species (i.e. H2O approx.104K). Previous studies using various remote sensing techniques have not been able to definitively characterize the distribution or abundance of ice in lunar PSRs. The purpose of this study is to search for signs of ice in PSRs using two complimentary remote sensing techniques: radar and visible images.

Mitchell, J. L.↗
NASA NTRS2017

Remote Sensing and Geologic Studies of Mare Australe: The North Australe Region

A key goal of the Lunar Reconnaissance Orbiter (LRO) mission is to investigate volcanic processes at different temporal and physical scales, with one emphasis being the characterization of ancient (meaning, greater than 3.9 Ga) volcanic units. One such ancient volcanic terrain is Mare Australe, a loosely-circular collection of mare basalts centered at approximately 38.9 deg S, 93 deg E (Fig. 1). Mare Australe is a complex, extensive, and poorly understood volcanic region.

Lawrence, S. J.↗
NASA NTRS2016

Revisiting the Field Geology of Taurus-Littrow

Integration of Apollo 17 field observations and photographs, sample investigations, Lunar Reconnaissance Orbiter Camera images, Chandrayaan-1 Moon Mineralogy Mapper (M(sup 3)) spectra, and Miniature Radio Frequency (Mini-RF) S-band radar images provides new insights into the geology of the valley of Taurus-Littrow on the Moon. Connecting the various remote observations to sample data enables a set of new conclusions to be drawn regarding the geological evolution of the valley. Structural considerations and published and recalculated Ar-40/Ar-39 analyses of samples from the North Massif and the Sculptured Hills indicate that the Crisium basin formed about 3.93 Ga; the Serenitatis basin about 3.82 Ga; and the Imbrium basin no earlier than 3.82 Ga and no later than the average of 3.72 Ga for 33 age dates from samples of the valley's mare basalts. Strong evidence continues to support the conclusion of others (Lucchitta, 1972; Spudis et al., 2011; Fassett et al., 2012) that the Sculptured Hills physiographic unit consists of Imbrium ejecta. Interpretation of M(sup 3) spectral data and Apollo 17 samples indicate that rock units of the Sculptured Hills consist of a largely coherent, Mg-suite pluton. LROC NAC stereo images and Mini-RF data indicate the presence of several exposed pyroclastic fissures across the Sculptured Hills. Rim boulders at Camelot Crater constitute nearly in situ wall rocks of that crater rather than ejecta and provide an opportunity for investigations of remanent magnetic field orientation at the time of the eruption of late mare basalt lavas in the valley. Paleomagnetic field orientation information also may be obtained relative to melt-breccia contacts in North Massif boulders that suggest original horizontal orientations. LROC images indicate the existence of two temporally separate light mantle avalanche deposits. The origin, potential flow mechanisms, and geology of the youngest avalanche from the South Massif have been clarified. The existence of two distinct light mantle avalanches raises doubt about the association of either light mantle avalanche with secondary impacts related to the Tycho impact event. Alternatively, the Lee-Lincoln thrust fault appears to have triggered the second light mantle avalanche between 70 and 110 Ma. A simple structural analysis shows that this thrust fault dips 20-25 degrees to the southwest where it crosses the North Massif and to the west where it crosses the valley floor. Mini-RF data reveal a line of reduced reflections roughly perpendicular to contours on the North Massif about 3 km to the east of the Lee-Lincoln fault. Although this line is possibly an older ancillary fault, LROC NAC stereo images indicate that it may be best explained as a pyroclastic fissure. A debris flow of dark, apparent pyroclastic ash lies below the southeast end of the potential fissure. Finally, young lunar impact glass sample 70019 has been precisely located within LROC NAC images and oriented for the first time using 60 mm (f.l.) sample documentation photographs. Sample 70019 can now be employed in lunar paleomagnetic field orientation studies.

Schmitt, H. H.↗
NASA NTRS2016

Defining Long-Duration Traverses of Lunar Volcanic Complexes with LROC NAC Images

A long-duration lunar rover [e.g., 1] would be ideal for investigating large volcanic complexes like the Marius Hills (MH) (approximately 300 x 330 km), where widely spaced sampling points are needed to explore the full geologic and compositional variability of the region. Over these distances, a rover would encounter varied surface morphologies (ranging from impact craters to rugged lava shields), each of which need to be considered during the rover design phase. Previous rovers including Apollo, Lunokhod, and most recently Yutu, successfully employed pre-mission orbital data for planning (at scales significantly coarser than that of the surface assets). LROC was specifically designed to provide mission-planning observations at scales useful for accurate rover traverse planning (crewed and robotic) [2]. After-the-fact analyses of the planning data can help improve predictions of future rover performance [e.g., 3-5].

Stopar, J. D.↗
NASA NTRS2016

Coordinates of Anthropogenic Features on the Moon

High-resolution images from the Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC) reveal the landing locations of recent and historic spacecraft and associated impact sites across the lunar surface. Using multiple images of each site acquired between 2009 and 2015, an improved Lunar Reconnaissance Orbiter (LRO) ephemeris, and a temperature-dependent camera orientation model, we derived accurate coordinates ( less than 12 meters) for each soft-landed spacecraft, rover, deployed scientific payload, and spacecraft impact crater that we have identified. Accurate coordinates enhance the scientific interpretations of data returned by the surface instruments and of returned samples of the Apollo and Luna sites. In addition, knowledge of the sizes and positions of craters formed as the result of impacting spacecraft provides key benchmarks into the relationship between energy and crater size, as well as calibration points for reanalyzing seismic measurements acquired during the Apollo program. We identified the impact craters for the three spacecraft that impacted the surface during the LRO mission by comparing before and after NAC images.

Moon↗
NASA NTRS2012

The Origin of Ina: Evidence for Inflated Lava Flows on the Moon

Ina is an enigmatic volcanic feature on the Moon known for its irregularly shaped mounds, the origin of which has been debated since the Apollo Missions. Three main units are observed on the floor of the depression (2.9 km across, < or =64 m deep) located at the summit of a low-shield volcano: irregularly shaped mounds up to 20 m tall, a lower unit 1 to 5 m in relief that surrounds the mounds, and blocky material. Analyses of Lunar Reconnaissance Orbiter Camera images and topography show that features in Ina are morphologically similar to terrestrial inflated lava flows. Comparison of these unusual lunar mounds and possible terrestrial analogs leads us to hypothesize that features in Ina were formed through lava flow inflation processes. While the source of the lava remains unclear, this new model suggests that as the mounds inflated, breakouts along their margins served as sources for surface flows that created the lower morphologic unit. Over time, mass wasting of both morphologic units has exposed fresh surfaces observed in the blocky unit. Ina is different than the terrestrial analogs presented in this study in that the lunar features formed within a depression, no vent sources are observed, and no cracks are observed on the mounds. However, lava flow inflation processes explain many of the morphologic relationships observed in Ina and are proposed to be analogous with inflated lava flows on Earth.

Garry, W. B.↗
NASA NTRS2011

Impact Melt in Small Lunar Highlands Craters

Impact-melt deposits are a typical characteristic of complex impact craters, occurring as thick pools on the crater floor, ponds on wall terraces, veneers on the walls, and flows outside and inside the rim. Studies of the distribution of impact melt suggested that such deposits are rare to absent in and around small (km to sub-km), simple impact craters. noted that the smallest lunar crater observed with impact melt was approximately 750 m in diameter. Similarly, theoretical models suggest that the amount of melt formed is a tiny fraction (<1%) of the total crater volume and thus significant deposits would not be expected for small lunar craters. LRO LROC images show that impact-melt deposits can be recognized associated with many simple craters to diameters down to approximately 200 m. The melt forms pools on the crater floor, veneer on the crater walls or ejecta outside the crater. Such melt deposits are relatively rare, and can be recognized only in some fresh craters. These observations indicate that identifiable quantities of impact melt can be produced in small impacts and the presence of such deposits shows that the material can be aggregated into recognizable deposits. Further, the present of such melt indicates that small craters could be reliably radiometrically dated helping to constrain the recent impact flux.

Plescia, J. B.↗
NASA NTRS2005

Comparison of Newly Acquired Lunar Spectra with the Titanium Abundance Maps Derived from Clementine

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) is one of seven science instruments onboard NASA's MESSENGER mission, currently en-route to the planet Mercury. One of MASCS s components, referred to as the Visible and Near Infrared Spectrograph (VIRS), will record reflectance spectra of the surface in order to characterize the mineralogy of the planet [1]. The lunar highlands and the average mercurian crust are proposed to be compositionally similar [i.e. 2]. In preparation to interpret VIRS reflectance spectra of Mercury to be first obtained in 2008, the Moon has been observed with an engineering model of the VIRS from a ground-based telescope. In this study, the ultraviolet and visible region of the spectrum is compared with titanium content in the lunar regolith.

Holsclaw, G. M.↗
NASA NTRS2005

Seismic Shaking Removal of Craters 0.2-0.5 km in Diameter on Asteroid 433 Eros

Impact cratering acts in a variety of ways to create a surprising range of scenery on small satellites and asteroids. The visible crater population is a self-modifying characteristic of these airless objects, and determining the various ways younger craters can add or subtract from the population is an important aspect of small body "geology." Asteroid 433 Eros, the most closely studied of any small body, has two aspects of its crater population that have attracted attention: a fall-off of crater densities below approx.100 m diameter relative to an expected equilibrium population [1] and regions of substantially lower large crater densities [2, 3, 4]. In this work we examine the global variation of the density of craters on Eros larger than 0.177 km, a size range above that involved in small crater depletion hypotheses [1, 5]. We counted all craters on Eros to a size range somewhat below 0.177 km diameter (and different from data used in [3]). The primary metric for this study is the number of craters between 0.177 and 1.0 km within a set radius of each grid point on the 2deg x 2deg shape model of Eros. This number can be expressed as an R-value [6], provided that it is remembered that the large bin size makes individual R values slightly different from those obtained in the usual root-2 bins.

Thomas, P. C.↗
NASA NTRS2003

A Near-Infrared (NIR) Global Multispectral Map of the Moon from Clementine

In May and June of 1994, the NASA/DoD Clementine Mission acquired global, 11- band, multispectral observations of the lunar surface using the ultraviolet-visible (UVVIS) and near-infrared (NIR) camera systems. The global 5-band UVVIS Digital Image Model (DIM) of the Moon at 100 m/pixel was released to the Planetary Data System (PDS) in 2000. The corresponding NIR DIM has been compiled by the U.S. Geological Survey for distribution to the lunar science community. The recently released NIR DIM has six spectral bands (1100, 1250, 1500, 2000, 2600, and 2780 nm) and is delivered in 996 quads at 100 m/pixel (303 pixels/degree). The NIR data were radiometrically corrected, geometrically controlled, and photometrically normalized to form seamless, uniformly illuminated mosaics of the lunar surface.

Eliason, E. M.↗
NASA NTRS2002

Lunar Topography and Basins Mapped Using a Clementine Stereo Digital Elevation Model

Planet-wide (1 km/pixel and 5 km/pixel) Digital Elevation Models (DEM) of the Moon have been produced using Clementine UVVIS (Ultraviolet-Visible) stereo. Six new basins have been discovered, two suspected basins have been confirmed, and the dimensions of existing basins better defined. Additional information is contained in the original extended abstract.

Cook, A. C.↗
NASA NTRS2001

The Porosity of Eros and Implications for Its Internal Structure

We estimate the porosity of Eros to be between 21-33%. Based on this porosity range and morphologic observations of the surface, we suggest that the asteroid is heavily fractured (but not a rubble pile). Additional information is contained in the original extended abstract.

Wilkison, S. L.↗
NASA NTRS2001

Digital Elevation Model Mosaic of Mercury

At CEPS (Center for Earth and Planetary Studies) work has been underway since 2000 to semi-automatically stereo match all Mariner 10 stereo pairs. The resulting matched image coordinates are converted into longitude, latitude, and height points and then combined to form a map projected Digital Elevation Model (DEM) mosaic of the planet's surface. Stereo images from Mariner 10 cover one quarter of the planet's surface, mostly in the southern hemisphere. Additional information is contained in the original extended abstract.

Cook, A. C.↗
NASA NTRS2001

Using Remotely Sensed Observations of Ancient Mare Deposits on the Moon as Possible Analogs to the Intercrater Plains on Mercury

Two commonly held models for the formation of the mercurian intercrater plains are: a global volcanic resurfacing event or basin-ejecta material. Although Mariner 10 images have provided morphologic and limited compositional information of the intercrater plains, the origin of these materials remains ambiguous. We examine whether Mariner 10 image at 355 (UV (ultraviolet)) and 575 nm (orange) can be used to distinguish between these models. Here we use Clementine image data (415 and 750 nm) for ancient lunar mare deposits to evaluate this suggestion. The inventorying of 'hidden' volcanic deposits is important to mercurian studies because they provide evidence of ancient volcanism, which yields clues to the thermal evolution of the planet. The greater abundance of intercrater plains on Mercury, relative to the intercrater plains observed within the lunar highlands, suggests that the resurfacing was comparably more intense. Mercury may represent an intermediate member of planet resurfacing; with the extremes being the Moon (approximately 17% resurfacing) and Venus (global resurfacing). Additional information is contained in the original extended abstract.

Gillis, J. J.↗