Engineering topics

Robinson, M. S.

Publications and source records attributed to Robinson, M. S..

26 records · Page 2

NASA NTRS1997

Experimental indication of a naphthalene-base molecular aggregate for the carrier of the 2175 angstroms interstellar extinction feature

Experiments where the simple polycyclic aromatic hydrocarbon (PAH) naphthalene (C10H8) is subjected to the energetic environment of a plasma have resulted in the synthesis of a molecular aggregate that has ultraviolet spectral characteristics that suggest it provides insight into the nature of the carrier of the 2175 angstroms interstellar extinction feature and may be a laboratory analog. Ultraviolet, visible, infrared, and mass spectroscopy, along with gas chromatography, indicate that it is a molecular aggregate in which an aromatic double ring ("naphthalene") structural base serves as the electron "box" chromophore that gives rise to the envelope of the 2175 angstroms feature. This chromophore can also provide the peak of the feature or function as a mantle in concert with another peak provider such as graphite. The molecular base/chromophore manifests itself both as a structural component of an alkyl-aromatic polymer and as a substructure of hydrogenated PAH species. Its spectral and molecular characteristics are consistent with what is generally expected for a complex molecular aggregate that has a role as an interstellar constituent.

NASA Discipline Exobiology↗

NASA NTRS1997

Inference of a 7.75 eV lower limit in the ultraviolet pumping of interstellar polycyclic aromatic hydrocarbon cations with resulting unidentified infrared emissions

The discrete infrared features known as the unidentified infrared (UIR) bands originating in starburst regions of other galaxies, and in H II regions and planetary nebulae within the Milky Way, are widely thought to be the result of ultraviolet pumped infrared fluorescence of polycyclic aromatic hydrocarbon (PAH) molecules and ions. These UIR emissions are estimated to account for 10%-30% of the total energy emitted by galaxies. Laboratory absorption spectra including the vacuum ultraviolet region, as described in this paper, show a weakening of the intensity of absorption features as the population of cations increases, suggesting that strong pi* <-- pi transitions are absent in the spectra of PAH cations. This implies a lower energy bound for ultraviolet photons that pump infrared emissions from such ions at 7.75 eV, an amount greater than previously thought. The implications include size and structure limitations on the PAH molecules and ions which are apparent constituents of the interstellar medium. Also, this might affect estimations of the population of early-type stars in regions of rapid star formation.

Non-NASA Center↗

NASA NTRS1995

Plasma processing of interstellar PAHs into solar system kerogen

Processes resulting in the formation of hydrocarbons of carbonaceous chondrites and the identity of the interstellar molecular precursors involved are an objective of investigations into the origin of the solar system and perhaps even life on earth. We have combined the resources and experience of an astronomer and physicists doing laboratory simulations with those of a chemical expert in the analysis of meteoritic hydrocarbons, in a project that investigated the conversion of polycyclic aromatic hydrocarbons (PAHs) formed in stellar atmospheres into alkanes found in meteorites. Plasma hydrogenation has been found in the University of Alabama at Birmingham Astrophysics Laboratory to produce from the precursor PAH naphthalene, a new material having an IR absorption spectrum (Lee, W. and Wdowiak, T.J., Astrophys. J. 417, L49-L51, 1993) remarkably similar to that obtained at Arizona State University of the benzene-methanol extract of the Murchison meteorite (Cronin, J.R. and Pizzarello, S., Geochim. Cosmochim. Acta 54, 2859-2868, 1990). There are astrophysical and meteoritic arguments for PAH species from extra-solar sources being incorporated into the solar nebula, where plasma hydrogenation is highly plausible. Conversion of PAHs into alkanes could also have occurred in the interstellar medium. The synthesis of laboratory analogs of meteoritic hydrocarbons through plasma hydrogenation of PAH species is underway, as is chemical analysis of those analogs. The objective is to clarify this heretofore uninvestigated process and to understand its role during the origin of the solar system as a mechanism of production of hydrocarbon species now found in meteorites. Results have been obtained in the form of time-of-flight spectroscopy and chemical analysis of the lab analog prepared from naphthalene.

NASA Discipline Exobiology↗

NASA NTRS1993

Galileo imaging results from the second Earth-Moon flyby: Lunar Maria and related units

The second flyby of the Earth-Moon System by Galileo occurred on December 7, 1992, on its trajectory toward Jupiter. The flyby took the spacecraft over the lunar north polar region from the dark farside and continued across the illuminated nearside. This provided the first opportunity to observe northern and northeastern limb regions with a modern, multispectral imaging system with high spatial resolution (up to 1.1 km/pixel). Scientific objectives included compositional assessment of previously uncharacterized mare regions, study of various light plains materials, and assessment of dark mantle deposits (DMD) and dark halo craters (DHC). Color composite images were prepared from ratios of Galileo SSI filter data (0.76/0.41 yields red; 0.76/0.99 yields green; 0.41/0.76 yields blue) and used for preliminary comparison of units. The 0.41/0.76 ratio has been empirically correlated to Ti content of mare soils (blue is relatively high, red is relatively low). The relative strengths of the ferrous one micron absorption in mafic minerals can be compared using the 0.76/0.99 ratio. In addition, relative ages of units analyzed spectrally were determined from crater statistics using Lunar Orbiter images following the techniques of Neukum et al. Mare deposits analyzed include Mare Humboldtianum, central and eastern Mare Frigoris, Mare Crisium and other deposits in the Crisium Basin, and isolated mare patches on the northeastern lunar limb. Preliminary results show a diversity of 0.41/0.76 micron signatures, implying a wide range of titanium contents. Some light plains units are similar to units found at the Apollo 16 site; others may be ancient mare materials. Dark mantle deposits (DMD) analyzed also are available.

Greeley, R.↗

NASA NTRS1993

Remote sensing studies of the northeastern portion of the lunar nearside

During the Galileo spacecraft encounter with the Earth-Moon system in December, 1992, a variety of spectral data and imagery were obtained for the eastern limb region as well as much of the lunar nearside. In order to support this encounter, we have been collecting near-infrared spectra and other remote sensing data for that portion of the northeastern nearside (NEM region) for which the highest resolution Galileo data were obtained. Analysis of spectra obtained for highlands units in the NEN region indicates that most surface units are dominated by anorthositic norite. To date, no pure anorthosites have been identified in the region. Several dark-haloed impact craters have exposed mare material from beneath highlands-rich surface units. Hence, ancient mare volcanism occurred in at least a portion of the NEN region. Endogenic dark-haloed craters in the region are the source of localized dark mantle deposits (LDMD) of pyroclastic origin and at least two compositional groups are present. The Galileo spacecraft obtained very high-resolution remote sensing data for the northeastern part of the nearside of the Moon. In order to prepare for and support this encounter, we have collected and analyzed a variety of spectral data for the NEN region. Numerous unanswered questions exist for this region. These include: (1) the composition and stratigraphy of the local highlands crust, (2) the nature and mode of formation of regional light plains, (3) the composition of localized pyroclastic deposits, and (4) the distribution of possible cryptomare in the region. The purpose of this paper is to present the preliminary results of our analyzes of remote sensing data of remote sensing data obtained for the NEN region.

Hawke, B. R.↗

NASA NTRS1993

Lunar multispectral mosaics from Galileo's second Earth-Moon flyby

Galileo's Solid-State Imaging (SSI) experiment acquired about 800 images of the Moon from the second Earth-Moon flyby (EM2) in December of 1992. Ten major sequences were acquired; each consists of mosaics of the entire or nearly entire visible and illuminated surface from each viewing geometry in at least six spectral filters (effective wavelengths for the Moon of 420, 564, 660, 756, 890, and 990 nm). The geometries of LUNMOS numbers 3, 4, 5, and 6 were designed to provide stereo data at the best possible resolutions. The purpose of this abstract is to describe the sequences, calibration, processing, and mosaicking, and to present a set of color products in a poster session.

Mcewen, A. S.↗

NASA NTRS1993

Chronology, eruption duration, and atmospheric contribution of Apollinaris Patera, Mars

Geologic mapping from Viking image data of the Martian volcano Apollinaris Patera allowed identification of 6 major events that shaped its current morphology. Derivation of new topographic data allowed accurate estimates of the volume of erupted products from which estimates of an eruption duration are presented for the edifice and its corresponding atmospheric water contribution. Topographic data were acquired using stereophotogrammetric (Viking picnos 603A42, 639A92) techniques in both profiling and contouring modes (1 km contour). The profiling mode results in a more precise measurement than the contouring mode, but is limited in its areal coverage. The contour data are used in a more general sense to provide synoptic coverage for the volcano. These new stereophotogrammetric measurements constrain the topography to an accuracy of approximately 800 m vertically and approximately 1000 m horizontally. Conversion of the derived contour map to a raster based digital elevation model (DEM) was done by a growing contours interpolation. An ambiguity arises in this volume calculation due to an uncertainty regarding the actual base of the volcano relative to the pre-existing topography. Thus, the volume estimate was bracketed by using the 100 m and the 750 m elevations, which generally correspond to the lower and upper portions of the circumferential basal scarp, respectively. The resulting volumes are 103,000 cu km and 97,000 cu km; therefore the total volume of Apollinaris Patera is estimated to be approximately 100,000 cu km.

Robinson, M. S.↗

NASA NTRS1991

New studies of Martian volcanoes

To investigate the morphology, topography, and evolution of volcanic constructs on Mars, researchers have been studying the volcanoes Olympus Mons, Tyrrhena Patera, and Apollinaris Patera. These studies relied upon the analysis of digital Viking orbiter images to measure the depth and slopes of the summit area of Olympus Mons, upon new Earth-based radar measurements for the analysis of the slopes of Tyrrhena Patera, and upon the color characteristics of the flanks of Apollinaris Patera for information regarding surface properties.

Mouginis-Mark, P. J.↗