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Rosalind May Armytage

Publications and source records attributed to Rosalind May Armytage.

HF Vapor Etching for Stardust Particle Extraction: A Progress Report

The Stardust mission captured thousands of particles from Jupiter-family comet 81P/Wild 2 using aluminum foil and silica aerogel collection media [1]. Most studies of Wild 2 material examine refractory terminal particles >1 μm in diameter which are extracted individually from the ends of tracks produced by the particle’s impact into the aerogel medium. A substantial (>65 %) mass fraction of the impactors is present as fine-grained (i.e. <1 μm) material in the ‘bulb’ and walls of the tracks, which may contain preserved organic material and presolar grains [2]. Few presolar grains have been identified in Stardust samples, which has been interpreted as owing to destruction upon impact into the foils and preferential sampling of terminal particles rather than a lack of presolar grains in Wild 2 samples [3-5]. By isolating the fine-grained material from these bulbs and performing microbeam and isotopic analyses (i.e., scanning electron microscopy and NanoSIMS), organic matter and presolar grains can be identified and constraints can be placed on the constituents of primitive outer solar system materials.

Stardust↗

Trace Element and Isotopic Evidence for Bennu's Primitive Provenance

The delivery of material from asteroid (101955) Bennu by NASA’s OSIRIS-REx mission provides the opportunity to investigate some of the most pristine material from the early Solar System [1]. Our team at Lawrence LivermoreNational Laboratory (LLNL) utilized the equivalent of 5.0 mg from Bennu sampleOREX-803015-100 to quantify the major and trace element contents and investigate major element isotopics (Ca, Ti, Cr, Fe, and Ni). Our 5.0 mg aliquot ofOREX-803015-100 was a subsample of dissolved homogenized material representing 20.66 mg [2]. A separate 5.0 mg aliquot was sent to ETH Zürich and is discussed in a companion abstract [3]. Before any chemical separation on our 5.0 mg aliquot, the equivalent of 0.5 mg was removed and analyzed for elemental abundances at LLNL using a ThermoScientific Element XR. Our data agree exceptionally well with those reported by[2], showing that Bennu is primitive and compositionally similar to CI chondrites, Ryugu [4], and the solar photosphere [5]. The remaining ~4.5 mg underwent purification procedures to chemically isolate and purify Ca, Ti, Cr, Fe, and Ni from one another and the sample matrix. Their isotopic compositions were measured on either the Triton TIMS (Ca) at JohnsonSpace Center in Houston, Neoma MC-ICPMS (Ti, Cr) at LLNL, or the Neptune MC-ICPMS (Fe, Ni) at LLNL. Results from the Ca, Ti, Cr, Fe, and Ni isotopic compositions suggest that Bennu is closely related to CI chondrites—consistent with conclusions from elemental composition [2] and oxygen isotopics [6]reported for Bennu. The major element isotope compositions that we will present demonstrate that Bennu likely formed in a similar region of the SolarSystem as CI chondrites and potentially at a similar time of Solar System evolution.

Greg Brennecka↗