Search NASA⌕ Search

Engineering topics

Rosner, D. E.

Publications and source records attributed to Rosner, D. E..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Onset conditions for gas phase reaction and nucleation in the CVD of transition metal oxides

A combined experimental/theoretical study is presented of the onset conditions for gas phase reaction and particle nucleation in hot substrate/cold gas CVD of transition metal oxides. Homogeneous reaction onset conditions are predicted using a simple high activation energy reacting gas film theory. Experimental tests of the basic theory are underway using an axisymmetric impinging jet CVD reactor. No vapor phase ignition has yet been observed in the TiCl4/O2 system under accessible operating conditions (below substrate temperature Tw = 1700 K). The goal of this research is to provide CVD reactor design and operation guidelines for achieving acceptable deposit microstructures at the maximum deposition rate while simultaneously avoiding homogeneous reaction/nucleation and diffusional limitations.

Collins, J.↗
NASA NTRS1991

Influence of mass diffusion on the stability of thermophoretic growth of a solid from the vapor phase

The stability of solid planar growth from a binary vapor phase with a condensing species dilute in a carrier gas is examined when the ratio of depositing to carrier species molecular mass is large and the main diffusive transport mechanism is thermal diffusion. It is shown that a deformation of the solid-gas interface induces a deformation of the gas phase isotherms that increases the thermal gradients and thereby the local mass deposition rate at the crests and reduces them at the valleys. The initial surface deformation is enhanced by the modified deposition rates in the absence of appreciable Fick/Brownian diffusion and interfacial energy effects.

Castillo, J. L.↗
NASA NTRS1987

Laboratory studies of binary salt CVD in combustion gas environments

A flash-evaporation technique is used to obtain vapor deposition characteristics for the binary alkali sulfates K2SO4 + Na2SO4 at 1 atm above 1100 K. The experimental equipment and techniques are described, and preliminary results are reported which indicate that this experimental technique meets most of the research requirements for studying multicomponent systems of current interest. The various deposition rate effects of introducing additives and the relevant inferences of condensate composition are presented, and the theoretical implications are discussed. It is concluded that alkali sulfate deposition and vaporization in combustion environments are inevitably influenced by chemical reactions such as hydroxide formation, and that solution nonideality is important even for homologous alkali-salt mixtures.

Liang, Baishen↗
NASA NTRS1986

Thermophoretically augmented mass transfer rates to solid walls across laminar boundary layers

Predictions of mass transfer (heavy vapor and small particle deposition) rates to solid walls, including the effects of thermal (Soret) diffusion ('thermophoresis' for small particles), are made by numerically solving the two-dimensional self-similar forced convection laminar boundary-layer equations with variable properties, covering the particle size range from vapor molecules up to the size threshold for inertial (dynamical nonequilibrium) effects. The effect of thermophoresis is predicted to be particularly important for submicron particle deposition on highly cooled solid surfaces, with corresponding enhancement factors at atmospheric conditions being over a thousand-fold at T(w)/T(e) equal to about 0.6. As a consequence of this mass transfer mechanism, the particle size dependence of the mass transfer coefficient to a cooled wall will be much weaker than for the corresponding case of isothermal capture by Brownian-convective diffusion.

Gokoglu, S. A.↗
NASA NTRS1985

Viscous dissipation effects on thermophoretically augmented aerosol particle transport across laminar boundary layers

The effect of viscous dissipation on mass transport across nonisothermal low-mass-loading laminar boundary layers of dusty gas is investigated theoretically by means of numerical simulations. The derivation of the model is outlined, and numerical results are presented in extensive graphs and characterized in detail. The dissipation effects are found to be significant, increasing total particle-deposition rates; the intensity of the effects depends on the ratio of wall temperature to mainstream static temperature.

Gokoglu, S. A.↗
NASA NTRS1985

Turbine airfoil deposition models and their hot corrosion implications

This research project deals with the prediction of single- and multi-component salt(-solution) deposition, flow and oxide dissolution and their effects on the lifetime of turbine blades. Goals include rationalizing and helping to predict corrosion patterns on operational gas turbine (GT) rotor blades and stator vanes, and ultimately providing some of the tools required to design laboratory simulators and future corrosion resistant high-performance engines. Necessary background developments are reviewed. Results and tentative conclusions for single species (Na sub 2 SO sub 4 (1)) condensation, binary salt-solution (Na sub 2 SO sub 4-K sub 2 SO sub 4) condensation, and burner-rig testing of alloy materials are outlined.

Rosner, D. E.↗
NASA NTRS1985

Polarization (ellipsometric) measurements of liquid condensate deposition and evaporation rates and dew points in flowing salt/ash-containing combustion gases

An application of an optical polarization technique in a combustion environment is demonstrated by following, in real-time, growth rates of boric oxide condensate on heated platinum ribbons exposed to seeded propane-air combustion gases. The results obtained agree with the results of earlier interference measurements and also with theoretical chemical vapor deposition predictions. In comparison with the interference method, the polarization technique places less stringent requirements on surface quality, which may justify the added optical components needed for such measurements.

Seshadri, K.↗
NASA NTRS1985

Transport-induced shifts in condensate dew-point and composition in multicomponent systems with chemical reaction

Partial heterogeneous condensation phenomena in multicomponent reacting systems are analyzed taking into consideration the chemical element transport phenomena. It is demonstrated that the dew-point surface temperature in chemically reactive systems is not a purely thermodynamic quantity, but is influenced by the multicomponent diffusion and Soret-mass diffusion phenomena. Several distinct dew-points are shown to exist in such systems and, as a result of transport constraints, the 'sharp' locus between two chemically distinct condensates is systematically moved to a difference mainstream composition.

Rosner, D. E.↗
NASA NTRS1985

Mass transfer across combustion gas thermal boundary layers - Power production and materials processing implications

The effects of Soret diffusion (for vapors) and thermophoresis (for particles) are illustrated using recent optical experiments and boundary layer computations. Mass transfer rate augmentations of up to a factor of 1000 were observed and predicted for submicron-particle capture by cooled solid surfaces, while mass transfer suppressions of more than 10 to the -10th-fold were predicted for 'overheated' surfaces. It is noted that the results obtained are of interest in connection with such technological applications as fly-ash capture in power generation equipment and glass droplet deposition in optical-waveguide manufacture.

Rosner, D. E.↗
NASA NTRS1984

Turbine Airfoil Deposition Models

Gas turbine failures associated with sea-salt ingestion and sulfur-containing fuel impurities have directed attention to alkali sulfate deposition and the associated hot corrosion of gas turbine (GT) blades under some GT operating conditions. These salt deposits form thin, molten films which undermine the protective metal oxide coating normally found on GT blades. The prediction of molten salt deposition, flow and oxide dissolution, and their effects on the lifetime of turbine blades are examined. Goals include rationalizing and helping to predict corrosion patterns on operational GT rotor blades and stators, and ultimately providing some of the tools required to design laboratory simulators and future corrosion-resistant high-performance engines. Necessary background developments are reviewed first, and then recent results and tentative conclusions are presented along with a brief account of the present research plans.

Rosner, D. E.↗
NASA NTRS1984

Comparisons of rational engineering correlations of thermophoretically-augmented particle mass transfer with STAN5-predictions for developing boundary layers

Modification of the code STAN5 to properly include thermophoretic mass transport, and examination of selected test cases developing boundary layers which include variable properties, viscous dissipation, transition to turbulence and transpiration cooling. Under conditions representative of current and projected GT operation, local application of St(M)/St(M),o correlations evidently provides accurate and economical engineering design predictions, especially for suspended particles characterized by Schmidt numbers outside of the heavy vapor range.

Gokoglu, S. A.↗
NASA NTRS1984

Correlation of thermophoretically-modified small particle diffusional deposition rates in forced convection systems with variable properties, transpiration cooling and/or viscous dissipation

A cooled object (heat exchanger tube or turbine blade) is considered to be immersed in a hot fluid stream containing trace amounts of suspended vapors and/or small particles. Numerical prediction calculations were done for self-similar laminar boundary layers and law-of-the-wall turbulent boundary layers. Correlations are presented for the effect of thermophoresis in the absence of transpiration cooling and viscous dissipation; the effect of real suction and blowing in the absence of thermophoresis; the effect of viscous dissipation on thermophoresis in the absence of transpiration cooling; and the combined effect of viscous dissipation and transpiration cooling on thermophoresis. The final correlation, St/St-sub-zero, is insensitive to particle properties, Euler number, and local mainstream temperature.

Gokoglu, S. A.↗
NASA NTRS1984

Experimental and theoretical deposition rates from salt-seeded combustion gases of a Mach 0.3 burner rig

Deposition rates on platinum-rhodium cylindrical collectors rotating in the cross streams of the combustion gases of a salt-seeded Mach 0.3 burner rig were determined. The collectors were internally air cooled so that their surface temperatures could be widely varied while they were exposed to constant combustion gas temperatures. The deposition rates were compared with those predicted by the chemically frozen boundary layer (CFBL) computer program, which is based on multicomponent vapor transport through the boundary layer. Excellent agreement was obtained between theory and experiment for the NaCl-seeded case, but the agreement lessened as the seed was changed to synthetic sea salt, NaNO3, and K2SO4, respectively, and was particularly poor in the case of Na2SO4. However, when inertial impaction was assumed to be the deposition mechanism for the Na2SO4 case, the predicted rates agreed well with the experimental rates. The former were calculated from a mean particle diameter that was derived from the measured intial droplet size distribution of the solution spray. Critical experiments showed that liquid phase deposits were blown off the smooth surface of the platinum-rhodium collectors by the aerodynamic shear forces of the high-velocity combustion gases but that rough or porous surfaces retained their liquid deposits.

Santoro, G. J.↗
NASA NTRS1984

Effect of particulate thermophoresis in reducing the fouling rate advantages of effusion-cooling

To predict small-particle diffusional mass transfer (deposition), including particle thermophoresis, transpiration cooling, and variable properties, the coupled ordinary differential equations governing self-similar laminar boundary layers are solved numerically. Under typical combustion turbine conditions, although diffusional deposition rates can be dramatically reduced by transpiration cooling (e.g., by some 5-decades for mainstream submicron particles corresponding to a Schmidt number of about 100 and a wall transpiration-cooled to Tw/Te = 0.8), actual deposition rate reductions will be smaller than previously expected (by about 1 decade for particles with Sc of about 100), owing to thermophoretic particle drift caused by the colder wall. Such microdroplets, small enough to behave like heavy molecules in combustion systems, are often important because they can cause adherence of the much larger ash particles which inertially impact on the same surface.

Gokoglu, S. A.↗
NASA NTRS1984

Boundary layer effects on particle impaction and capture

The inertial impaction and deposition of small particles on larger bodies with viscous boundary layers are considered theoretically, in a detailed comment on a paper by Menguturk et al. (1983). Topics addressed include cushion effects, the dimensionless groups corresponding to the diameter range (3-6 microns) examined by Menguturk et al. in a numerical example, analogous effects of particle-gas energy and mass exchange in boundary layers, and the combined effects of particle inertia and diffusion. It is argued that the inertial effects can be characterized in terms of a body, boundary-layer, or sublayer Stokes number. In a reply by Menguturk et al., the focus is on the application of the theoretical model to the erosion of blade surfaces in large gas turbines; the Stokes number is found to be of limited practical value in these cases, because the particle motion is not primarily normal to the blade surfaces.

Rosner, D. E.↗
NASA NTRS1984

Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

Gokoglu, S. A.↗
NASA NTRS1984

Comparisons of rational engineering correlations of thermophoretically-augmented particle mass transfer with STAN5-predictions for developing boundary layers

Modification of the code STAN5 to properly include thermophoretic mass transport, and examination of selected test cases developing boundary layers which include variable properties, viscous dissipation, transition to turbulence and transpiration cooling. Under conditions representative of current and projected GT operation, local application of St(M)/St(M),o correlations evidently provides accurate and economical engineering design predictions, especially for suspended particles characterized by Schmidt numbers outside of the heavy vapor range.

Gokoglu, S. A.↗