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Rosner, D. E.

Publications and source records attributed to Rosner, D. E..

At least 37 records · Page 2

Deposition of Na2SO4 from salt-seeded combustion gases of a high velocity burner rig

The mechanism of deposition of Na2SO4 was studied under controlled laboratory conditions and the results have been compared to a recently developed comprehensive theory of vapor deposition. Thus Na2SO4, NaCl, NaNO3 and simulated sea salt solutions were injected into the combustor of a nominal Mach 0.3 burner rig burning jet fuel at constant fuel/air ratios. The deposits formed on inert collectors, rotation in the cross flow of the combustion gases, were weighed and analyzed. Collector temperature was uniform and could be varied over a large range by internal air cooling. Deposition rates and dew point temperatures were determined. Supplemental testing included droplet size measurements of the atomized salt solutions. These tests along with thermodynamic and transport calculations were utilized in the interpretation of the deposition results.

Santoro, G. J.↗

Computer Program for the Calculation of Multicomponent Convective Diffusion Deposition Rates from Chemically Frozen Boundary Layer Theory

The computer program based on multicomponent chemically frozen boundary layer (CFBL) theory for calculating vapor and/or small particle deposition rates is documented. A specific application to perimter-averaged Na2SO4 deposition rate calculations on a cylindrical collector is demonstrated. The manual includes a typical program input and output for users.

Gokoglu, S. A.↗

Combustion system processes leading to corrosive deposits

Degradation of turbine engine hot gas path components by high temperature corrosion can usually be associated with deposits even though other factors may also play a significant role. The origins of the corrosive deposits are traceable to chemical reactions which take place during the combustion process. In the case of hot corrosion/sulfidation, sodium sulfate was established as the deposited corrosive agent even when none of this salt enters the engine directly. The sodium sulfate is formed during the combustion and deposition processes from compounds of sulfur contained in the fuel as low level impurities and sodium compounds, such as sodium chloride, ingested with intake air. In other turbine and power generation situations, corrosive and/or fouling deposits can result from such metals as potassium, iron, calcium, vanadium, magnesium, anad silicon. Previously announced in STAR as N81-23243

Stearns, C. A.↗

Use of a generalized Stokes number to determine the aerodynamic capture efficiency of non-Stokesian particles from a compressible gas flow

The aerodynamic capture efficiency of small but nondiffusing particles suspended in a high-speed stream flowing past a target is known to be influenced by parameters governing small particle inertia, departures from the Stokes drag law, and carrier fluid compressibility. By defining an effective Stokes number in terms of the actual (prevailing) particle stopping distance, local fluid viscosity, and inviscid fluid velocity gradient at the target nose, it is shown that these effects are well correlated in terms of a 'standard' (cylindrical collector, Stokes drag, incompressible flow, sq rt Re much greater than 1) capture efficiency curve. Thus, a correlation follows that simplifies aerosol capture calculations in the parameter range already included in previous numerical solutions, allows rational engineering predictions of deposition in situations not previously specifically calculated, and should facilitate the presentation of performance data for gas cleaning equipment and aerosol instruments.

Israel, R.↗

Aerodynamically-driven condensate layer thickness distributions on isothermal cylindrical surfaces

A simple yet rather general mathematical model is presented for predicting the distribution of condensate layer thickness when aerodynamic shear is the dominant mechanism of liquid flow along the surface. The Newtonian condensate film is treated using well-known thin-layer (lubrication theory) approximations, and condensate supply is taken to be the result of either convective diffusion or inertial impaction. Illustrative calculations for a circular cylinder in a crossflow at Re = 100,000 reveal the consequences of alternate condensate arrival mechanisms and the existence of thicker reverse-flow films behind the position of gas boundary-layer separation. The present formulation is readily generalized to include transient liquid layer flows on noncircular objects of variable surface temperature, as encountered in turbine-blade materials testing or operation.

Rosner, D. E.↗

Windward fraction of the total mass or heat transport for flow past a circular cylinder

The windward fraction of the total mass or heat transport for flow past a cylindrical aerodynamic object was estimated using the available experimental data for the angular distribution of the Nusselt transfer coefficient, Nu(theta, Re). The Re dependence of the windward surface fraction was calculated for the values of Re between 2 and 400,000. The results obtained from polar integrations of data from eight sources indicate that, for Reynolds numbers up to about 2000, more than 70 percent of the total transfer occurs on the windward surface. For the Re values above 100,000, the windward percentage is less than 50 percent.

Gokoglu, S.↗

Small particle transport across turbulent nonisothermal boundary layers

The interaction between turbulent diffusion, Brownian diffusion, and particle thermophoresis in the limit of vanishing particle inertial effects is quantitatively modeled for applications in gas turbines. The model is initiated with consideration of the particle phase mass conservation equation for a two-dimensional boundary layer, including the thermophoretic flux term directed toward the cold wall. A formalism of a turbulent flow near a flat plate in a heat transfer problem is adopted, and variable property effects are neglected. Attention is given to the limit of very large Schmidt numbers and the particle concentration depletion outside of the Brownian sublayer. It is concluded that, in the parameter range of interest, thermophoresis augments the high Schmidt number mass-transfer coefficient by a factor equal to the product of the outer sink and the thermophoretic suction.

Rosner, D. E.↗

Correlation and prediction of thermophoretic and inertial effects on particle deposition from non-isothermal turbulent boundary layers

The problem of small particle deposition which can cause hot stage corrosion and/or fouling in combustion turbines operating on fuels containing ash or inorganic salts is investigated. Two boundary layer transport phenomena are shown to assume importance in these cases: particle thermophoresis (migration down a temperature gradient) and particle inertia. Thermophoretic and eddy transport across turbulent boundary layers without and with particle inertia effects are quantitatively analyzed. The effects of streamwise blade curvature on particle transport across turbulent boundary layers are determined. It is shown that these phenomena destroy the analogy between mass and heat transfer or mass and momentum transfer. Also studied are the effects on particle deposition of distributed or localized wall blowing, surface roughness, and mainstream turbulence.

Rosner, D. E.↗

Rational engineering correlations of diffusional and inertial particle deposition behavior in non-isothermal forced convection environments

A multiparameter correlation approach to the study of particle deposition rates in engineering applications is discussed with reference to two specific examples, one dealing with thermophoretically augmented small particle convective diffusion and the other involving larger particle inertial impaction. The validity of the correlations proposed here is demonstrated through rigorous computations including all relevant phenomena and interactions. Such representations are shown to minimize apparent differences between various geometric, flow, and physicochemical parameters, allowing many apparently different physicochemical situations to be described in a unified way.

Rosner, D. E.↗

Combustion system processes leading to corrosive deposits

Degradation of turbine engine hot gas path components by high temperature corrosion can usually be associated with deposits even though other factors may also play a significant role. The origins of the corrosive deposits are traceable to chemical reactions which take place during the combustion process. In the case of hot corrosion/sulfidation, sodium sulfate was established as the deposited corrosive agent even when none of this salt enters the engine directly. The sodium sulfate is formed during the combustion and deposition processes from compounds of sulfur contained in the fuel as low level impurities and sodium compounds, such as sodium chloride, ingested with intake air. In other turbine and power generation situations, corrosive and/or fouling deposits can result from such metals as potassium, iron, calcium, vanadium, magnesium, and silicon.

Stearns, C. A.↗

Experimental and theoretical studies of the laws governing condensate deposition from combustion gases

A description is presented of the results of a research program directed at an improved understanding of condensate deposition rate phenomena in combustion systems. The conducted experiments make use of real-time optical laser reflectance-interference-polarization techniques in flame environments. The obtained new data and the results of previous gravimetric experiments are employed as a basis for the development of a comprehensive convective diffusion deposition theory, taking into account the assumption of a multicomponent vapor or multisize class particles 'source-free' boundary layer. The theory makes it possible to provide self-consistent salt/ash/soot deposition rate predictions over a wide variety of environmental conditions.

Rosner, D. E.↗

Thermal /Soret/ diffusion effects on interfacial mass transport rates

It is shown that thermal (Soret) diffusion significantly alters convective mass transport rates and important transition temperatures in highly nonisothermal flow systems involving the transport of 'heavy' species (vapors or particles). Introduction of the Soret transport term is shown to result in mass transfer effects similar to those of 'suction' and a homogeneous chemical 'sink'. It is pointed out that this analogy provides a simple method of correlating and predicting thermal diffusion effects in the abovementioned systems.

Rosner, D. E.↗

Experimental studies of the formation/deposition of sodium sulfate in/from combustion gases

An optical polarization (ellipsometric) technique was developed for measuring rapidly growing and evaporating transparent liquid condensate films (e.g., boric oxide) on solid surfaces exposed to combustion product gases. Results for the B2O3 deposition rate from BCl3-seeded propane/air flames are shown to agree well with the results of earlier interference measurements, and also with theoretical CVD predictions. Evaporation rates (from platinum ribbons into seeded propane air flames) are estimated using the polarization technique. It appears that, compared with the interference method, the polarization technique places less stringent requirements on surface quality, which may justify the added optical components needed for such measurements. It is concluded that the complementary optical methods of polarization (ellipsometry) and interference hold considerable promise for application to the rapid measurement of condensation and evaporation rates in high temperature (e.g., combustion product) environments.

Rosner, D. E.↗

A new approach to the correlation of boundary layer mass transfer rates with thermal diffusion and/or variable properties

A rational approach to the correlation of boundary layer mass transport rates, applicable to many commonly encountered laminar flow conditions with thermal diffusion and/or variable properties, is outlined. The correlation scheme builds upon already available constant property blowing/suction solutions by introducing appropriate correction factors to account for the additional ('pseudo' blowing and source) effects identified with variable properties and thermal diffusion. Applications of the scheme to the particular laminar boundary layer mass transfer problems considered herein (alkali and transition metal compound vapor transport) indicates satisfactory accuracy up to effective blowing factors equivalent to about one third of the 'blow off' value. As a useful by-product of the variable property correlation, we extend the heat-mass transfer analogy, for a wide range of Lewis numbers, to include variable property effects.

Srivastava, R.↗

Chemically frozen multicomponent boundary layer theory of salt and/or ash deposition rates from combustion gases

There is increased interest in, and concern about, deposition and corrosion phenomena in combustion systems containing inorganic condensible vapors and particles (salts, ash). To meet the need for a computationally tractable deposition rate theory general enough to embrace multielement/component situations of current and future gas turbine and magnetogasdynamic interest, a multicomponent chemically 'frozen' boundary layer (CFBL) deposition theory is presented and its applicability to the special case of Na2SO4 deposition from seeded laboratory burner combustion products is demonstrated. The coupled effects of Fick (concentration) diffusion and Soret (thermal) diffusion are included, along with explicit corrections for effects of variable properties and free stream turbulence. The present formulation is sufficiently general to include the transport of particles provided they are small enough to be formally treated as heavy molecules. Quantitative criteria developed to delineate the domain of validity of CFBL-rate theory suggest considerable practical promise for the present framework, which is characterized by relatively modest demands for new input information and computer time.

Rosner, D. E.↗

Theory of deposition of condensible impurities on surfaces immersed in combustion gases

The components resulting from the deposition of inorganic salts (e.g., Na2S04) and oxides present in the combustion products from gas turbine engines were investigated. Emphasis was placed on the effects of multicomponent vapor transport, thermophoretic transport of vapor and small particles to actively cooled surfaces, variable fluid properties within mass transfer boundary layers, and free stream turbulence.

Rosner, D. E.↗

Experimental studies of the formation/deposition of sodium sulfate in/from combustion gases

Interference in a reflected beam of monochromatic light from a linearly polarized helium-neon laser was used to determine the dew point and deposition rate of B2O3 on a heated platinum target. Preliminary results at different BCl3 seed levels, except for one flow velocity and equivalence ratio (.813) are presented and discussed. Alkali chloride reactions with atomic oxygen were also investigated. Readily detectable Na*(g) and K*(g) - atoms were observed in emission at 589 nm, 766nm, 796nm, respectively.

Rosner, D. E.↗

Experimental Studies of the Formation/Deposition of Sodium Sulfate in/from Combustion Gases

Processes related to the hot corrosion of gas turbine components were examined in two separate investigations. Monochromatic laser light was used to probe condensation onset and condensate film growth (via interference of reflected light) on electrically heated ribbons immersed in seeded, flat flame combustion product gases. Boron trichloride is used as the seed gas in these preliminary experiments conducted to obtain precise measurements of the dew point/deposition rates. Because of the importance of gaseous Na(g) as a precursor to NaSO4 formation, the kinetics and mechanisms of the heterogeneous reaction H(g) + NaCl(s) yields Na(g) + HCl(g) was studied using atomic absorption spectroscopy combined with microwave discharge-vacuum flow reactor techniques at moderate temperatures. Preliminary results indicate the H-atom attack of solid NaCl vaporization is negligible; hence the corresponding gas phase (homogeneous) reaction no role in the observed Na(g) production.

Rosner, D. E.↗