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Schaefer, Charles

Publications and source records attributed to Schaefer, Charles.

Spectral induced polarization (SIP) measurements across a PFAS-contaminated source zone

There is a pressing need for the development of field-scale, in situ screening technologies for assessing variations in aqueous film forming foam (AFFF) concentrations in soils at former fire training and storage sites. Field-scale Spectral Induced Polarization (SIP) geophysical measurements were acquired on a transect crossing an AFFF source zone. Soil samples were acquired from ten locations and used to determine variations in poly- and per-fluoroalkyl substances (PFAS) concentrations in soils and soil texture. These samples were also used to create triplicate soil columns for laboratory-grade SIP measurements. Field and laboratory observations provide evidence that SIP measurements are sensitive to the concentration of AFFF constituents associated with the pore surface in soils. The phase of the SIP measurements on the laboratory samples was linearly correlated with total soil-sorbed PFAS concentration. The phase from the field SIP measurements was highest over the location of maximum PFAS concentration measured on the laboratory samples, although a significant correlation between field-measured phase and laboratory-measured total PFAS concentration was not established. The sensitivity of the SIP response to the removal of soil PFAS using a methanol wash procedure (total PFAS concentration drop of 366 ppb) adds evidence for the case for SIP characterization of AFFF source zones. The results of these studies suggest that SIP might be developed into a field-scale technology for rapid, indirect assessment of AFFF source zones. Such a technology could improve the effectiveness of AFFF source zone characterization at reduced costs.

58 GEOSCIENCES↗

Preliminary Transverse Shielding Analysis for the 1010-C RF Building

EIC is planning to construct a new building on the outer ring berm at 10 o’clock which will provide RF power to cryogenically-cooled beam line components in the electron and hadron storage rings. The distance of the building from the RHIC Tunnel and the amount of soil shielding required are the focus of this report. Siting the building closer to the RHIC Tunnel is desirable from an RF operations viewpoint since the waveguide runs and RF power losses will be minimized, but this may require the use of higher density shield materials, e.g., concrete, in addition to soil shielding. The radiological source terms are the prompt radiation hazards from the Hadron Storage Ring (HSR) and Electron Storage Ring (ESR) beam losses in the 10 o’clock sector and the lateral dose rates propagated through the shields. See Figure 1 below.

43 PARTICLE ACCELERATORS↗

Geophysical signatures of soil AFFF contamination from spectral induced polarization and low field nuclear magnetic resonance methods

Few field methods are available for characterizing source zones contaminated with aqueous film forming foam (AFFF). Non-invasive geophysical characterization of AFFF source zone contamination in situ could assist with the delineation and characterization of these sites, allowing for more informed sampling regimes aimed at quantifying subsurface poly- and perfluoroalkyl substances (PFAS) contamination. In this study, we present initial results from the investigation of the sensitivity of two existing surface and borehole-deployable geophysical technologies, spectral induced polarization (SIP), and low field nuclear magnetic resonance (NMR), to soils impacted with AFFF. To investigate the sensitivity of these methods to AFFF-impacted soil, bench-scale column experiments were conducted on samples consisting of natural and synthetic soils and groundwater. While our findings do not show strong evidence of NMR sensitivity to soil PFAS contamination, we do find evidence that SIP has sufficient sensitivity to detect PFAS sorption to soils. This finding is based on evidence that AFFF constituents associated with the pore surface produce a measurable polarization response in both freshly contaminated synthetic soils and in soils historically impacted with AFFF.

54 ENVIRONMENTAL SCIENCES↗

Preliminary Shielding Analysis for the 1012 400 MeV Linac Building

EIC is planning to purchase a 400 MeV turnkey pre-injector linear accelerator (Linac) which will be in a new building at the end of an existing RHIC tunnel at 12 o’clock. The building will contain the Linac Tunnel and associated accelerating structures, Klystron Gallery and waveguides, laser, utility, and control rooms. This report only examines the radiation source term produced by operating the Linac and not supplemental shielding that may be required to shield the Klystrons or solid state amplifiers in the Klystron Gallery from the x rays they emit. Normal Portland concrete blocks are planned to provide shielding between the Linac vault and the occupiable portions of the building per the attached drawing. It is expected that this facility will not be routinely occupied during operations (post commissioning). The shielding design considers EIC’s draft Shielding Policy that states shielding and other controls for areas where access is controlled for radiological purposes will be designed so that an ambient dose of 100 mrem per year to a worker is not likely.

43 PARTICLE ACCELERATORS↗