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Shaw, J. H.

Publications and source records attributed to Shaw, J. H..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Measurements of CH4, N2O, CO, H2O and O3 in the middle atmosphere by the ATMOS experiment on Spacelab 3

The volume mixing ratios of five minor gases (CH4, N2O, CO, H2O, and O3) were retrieved through the middle atmosphere from the analysis of 0.01/cm resolution infrared solar occultation spectra recorded near 28 N and 48 S latitudes with the ATMOS (Atmospheric Trace Molecule Spectroscopy) instrument, flown on board Spacelab 3. The results, which constitute the first simultaneous observations of continuous profiles through the middle atmosphere for these gases, are in general agreement with reported measurements from ground, balloon and satellite-based instruments for the same seasons. In detail, the vertical profiles of these gases show the effects of the upper and middle atmospheric transport patterns dominant during the season of these observations. The profiles inferred at different longitudes around 28 N suggest a near-uniform zonal distribution of these gases. Although based on fewer observations, the sunrise occultation measurements point to a larger variability in the vertical distribution of these gases at 48 S.

Gunson, M. R.↗
NASA NTRS1985

Application of nonlinear least squares methods to the analysis of solar spectra

A fast method of retrieving vertical temperature profiles in the atmosphere and of determining the paths of the rays producing the ATMOS occultation spectra has been developed. The results from one set of occultation data appear to be consistent with other available data. A study of sources of error, a search for other suitable features for measurement in the spectra, and modification of the program to obtain mixing ratio profiles have been initiated.

Shaw, J. H.↗
NASA NTRS1985

Atmospheric temperature profiles and ray paths from occultation spectra

Simulated equivalent width data of weak lines in occultation spectra have been analyzed to retrieve both the atmospheric temperature profile and the tangent heights of the rays. The SNR of these widths varied from 5 to 100. The mixing ratio of the absorbing gas and sea level pressure were assumed but not the satellite position. Temperature and tangent heights with accuracies of 1 K and 0.25 km, respectively, were determined from lines with temperature-dependent and temperature-independent intensities.

Hoke, M. L.↗
NASA NTRS1984

Effects of systematic errors on the mixing ratios of trace gases obtained from occultation spectra

The influence of systematic errors in the parameters of the models describing the geometry and the atmosphere on the profiles of trace gases retrieved from simulated solar occultation spectra, collected at satellite altitudes, is investigated. Because of smearing effects and other uncertainties, it may be preferable to calibrate the spectra internally by measuring absorption lines of an atmospheric gas such as CO2 whose vertical distribution is assumed rather than to rely on externally supplied information.

Shaffer, W. A.↗
NASA NTRS1984

Analysis of carbon dioxide bands near 2.2 micrometers

Carbon dioxide is one of the more important atmospheric infrared-absorbing gases due to its relatively high, and increasing, concentration. The spectral parameters of its bands are required for understanding radiative heat transfer in the atmosphere. The line intensities, positions, line half-widths, rotational constants, and band centers of three overlapping bands of CO2 near 2.2 microns are presented. Non-linear least squares (NLLS) regression procedures were employed to determine these parameters.

Abubaker, M. S.↗
NASA NTRS1984

A spectrum of methane from 700 to 5500 cm-1

An atlas of CH4 lines between 700 and 5,500 cm(-1) obtained from long-path-length samples at 296 K is presented. Many of the line centers are marked and their positions tabulated.

Baddar, H.↗
NASA NTRS1984

Least squares methods of analyzing spectroscopic data

The development of efficient techniques for extracting the maximum amount of information from the spectra of atmospheric molecules with a minimum of observer bias is discussed. In particular, an overview of the methods of line by line and whole band analysis is presented.

Shaw, J. H.↗
NASA NTRS1983

Resolution of vertical mixing-ratio profiles of atmospheric constituents retrieved from solar spectra

The relationship between the uncertainty and the resolution of the mixing-ratio profiles of absorbing gases retrieved from simulated occultation data has been investigated by analyzing sets of absorber amounts, corresponding to a constituent with a constant vertical mixing-ratio profile, along atmospheric paths observed by instruments at 0, 30, and 500 km. The vertical resolution below the instrument is limited by the number of observations and the SNR; it degrades exponentially with height and is independent of the instrument altitude; it is nearly 50 times better than the resolution obtainable above the instrument. An estimate of the resolution obtained by analyzing line shapes is included for comparison.

Shaffer, W. A.↗
NASA NTRS1983

Nitrogen-, oxygen-, and air-broadened widths and relative intensities of N2O lines near 2450 per cm

Spectra of the v sub 1 + 2v sub 2 and the weak underlying v sub 1 + 3v sub 2 - v sub 2 band of N2O near 2450/cm were analyzed by the nonlinear, least squares, whole band technique. The oxygen, nitrogen, and air broadened line widths and the relative line intensities were determined. The air broadened widths, for /m/3, are in agreement with those in the 1980 AFGL line listing and the relative band intensities also agree, within about 20 percent with the values in this listing. Previously announced in STAR as N82-30201

Hawkins, R. L.↗
NASA NTRS1983

Effects of systematic errors on the mixing ratios of trace gases obtained from occulation spectra

The influence of systematic errors in the parameters of the models describing the geometry and the atmosphere on the profiles of trace gases retrieved from simulated solar occultation spectra, collected at satellite altitudes, is investigated. Because of smearing effects and other uncertainties, it may be preferable to calibrate the spectra internally by measuring absorption lines of an atmospheric gas such as CO2 whose vertical distribution is assumed rather than to relay on externally supplied information.

Shaffer, W. A.↗
NASA NTRS1983

Simultaneous retrieval of atmospheric temperatures and ray paths from occultation spectra

Simulated equivalent width data of weak lines in solar occultation spectra were analyzed to retrieve both the solar atmospheric temperature profile and the tangent heights of the rays. It was assumed that the mixing ratio of the absorbing gas was known, but it is not necessary to know the satellite height. By analyzing lines with temperature dependent and temperature independent intensities, temperatures accurate to 1 K and tangent heights to 0.25 km were determined over the range 20 to 90 km.

Hoke, M. L.↗
NASA NTRS1982

Analysis of CO2 bands near 2600 per cm

The parameters of three bands of CO2 near 2600 per cm have been determined by the nonlinear least squares method of whole-band analysis. Careful modeling of the effect of the Fourier transform spectrometer on the spectrum has made it possible to reduce the difference between the observed and calculated spectra to values close to the estimated noise in the experimental spectrum. In particular, it is found necessary to model the effects of phase error even though these are difficult to observe in the experimental spectra.

Hoke, M. L.↗
NASA NTRS1982

Rotational analysis of CO2 bands near 4 microns

The band constants of CO2 bands near 2600 per cm have been estimated by the nonlinear least squares method and spectral curve fitting. The synthetic spectra calculated from these constants predict experimental values accurately and give very similar values for the line positions (to within 0.003 per cm for all but the weakest lines).

Hoke, M. L.↗
NASA NTRS1982

Parameters of CO2 bands near 3.6 microns

The intensities, widths, and positions of lines of three CO2 bands near 2750/cm were determined. The results are in general agreement with other measured and estimated values.

Hoke, M. L.↗
NASA NTRS1981

A spectrum of ozone from 760 to 5800 cm-1

An atlas of O3 lines between 760 and 5800/cm obtained from a low pressure, long-path-length sample of O3 at 296K is presented. Many of the line centers are marked and their positions tabulated.

Damon, E.↗