Engineering topics
Publications and source records attributed to Sutton, S. R..
Oxidation state microanalyses for V in glass have been made by calibrating XANES spectral features with optical spectroscopic measurements. The oxidation state change with fugacity of O2 will strongly influence partitioning results.
Using in-situ x-ray fluorescence, we determined the Cr/Fe, Mn/Fe and Ni/Fe of a particle captured in aerogel on MIR are approximately chondritic, indicating an extraterrestrial origin. Impurity of the aerogel precluded determining the Cu and Zn.
The topics discussed include the following: noble gas content and release temperatures; trace element abundances; heating summary of cluster fragments; isotopic measurements; and trace organic chemistry.
Trace-element abundances have proven important in understanding the evolution of and interrelationships between different meteorites. Preliminary investigations of the trace-element contents of interplanetary dust particles indicate that trace-element abundances will prove equally important in distinguishing between micrometeorites of different types, comparing the interplanetary dust to the meteorites, and assessing the degree of thermal alteration experienced either on the parent body or during the collection process. Sample collection, delivery, and curation must be accomplished in a manner to avoid contamination with even trace amounts of the elements to be analyzed. The present SXRF sensitivity for micrometeorite analysis is of order 1 femtogram, but anticipated improvements in sensitivity will require sample contamination substantially below this level. Sample collection and handling equipment should be constructed from materials selected for ultrahigh purity, and serious consideration should be given in selecting the particular set of elements from which the collection apparatus is composed so as not to compromise useful information.
The oxidation state of Cr in 200-micron regions within individual lunar olivine and pyroxene grains from lunar basalt 15555 was inferred using X-ray Absorption Near Edge Structure (XANES). Reference materials had previously been studied by optical absorption spectroscopy and included Cr-bearing borosilicate glasses synthesized under controlled oxygen fugacity and Cr-doped olivines. The energy dependence of XANES spectral features defined by these reference materials indicated that Cr is predominantly divalent in the lunar olivine and trivalent in the pyroxene. These results, coupled with the apparent f(02)-independence of partitioning coefficients for Cr into olivine, imply that the source magma was dominated by divalent Cr at the time of olivine crystallization.
Trace element abundances in 51 chondritic Interplanetary Dust Particles (IDP's) were measured by Synchrotron X-Ray Fluorescence (SXRF). The data allow us to determine an average composition of chondritic IDP's and to examine the questions of volatile loss during the heating pulse experienced on atmospheric entry and possible element addition due to contamination during atmospheric entry, stratospheric residence, and curation.
The degree of heating of interplanetary dust particles (IDP's) on Earth atmospheric entry is important in distinguishing cometary particles from main-belt asteroidal particles. Depletions in the volatile elements S and Zn were proposed as chemical indicators of significant entry heating. The S and Zn contents of cosmic dust particles were correlated with physical indicators of atmospheric entry heating, such as the production of magnetite and the loss of solar wind implanted He. The results indicate that the Zn content of IDP's is a useful indicator of entry heating, but the S content seems to be less useful.
Low-Ni particles with major element abundances, optical properties, and morphologies sufficiently similar to chondritic interplanetery dust particles (IDP's) to receive JSC Cosmic Dust Catalog classifications of C or C?-types were shown to have trace element contents and mineralogies similar to igneous material. Examination of the JSC Catalog EDX spectra by Cooke et al. has shown that 13 percent of the C-type and 38 percent of the C?-type particles are potentially low-Ni particles. Two new low-Ni particles were identified, and it was shown that an additional fragment from the L2002*C cluster has an igneous composition. A newly analyzed fragment of the W7066*A cluster has a chondritic composition. The W7066*A cluster is important because it has yielded a fragment of igneous composition and another fragment having high concentrations of He and Ne suggesting an extraterrestrial origin.
A wavelength dispersive spectrometer (WDS) was tested on the synchrotron x ray fluorescence microprobe at Brookhaven National Laboratory. Compared to WDS spectra using an electron microprobe, the synchrotron WDS spectra have much better sensitivity and, due to the absence of bremsstrahlung radiation, lower backgrounds. The WDS spectrometer was successfully used to resolve REE L fluorescence spectra from standard glasses and transition metal K fluorescence spectra from kamacite.
The synchrotron x-ray microprobe is being used to obtain oxidation state information on planetary materials with high spatial resolution. Initial results on chromium in olivine from various sources including laboratory experiments, lunar basalt, and kimberlitic diamonds are reported. The lunar olivine was dominated by Cr(2+) whereas the diamond inclusions had Cr(2+/Cr(3+) ratios up to about 0.3. The simpliest interpretation is that the terrestrial olivine crystallized in a more oxidizing environment than the lunar olivine.
An exploratory application of x ray absorption near edge structure (XANES) analysis using the synchrotron x ray microprobe was undertaken to obtain Fe XANES spectra on individual sub-millimeter grains in conventional polished sections. The experiments concentrated on determinations of Fe valence in a suite of iron oxide minerals for which independent estimates of the iron speciation could be made by electron microprobe analysis and x ray diffraction.
Major and minor element abundances in pyroxene, principally pigeonite, from Zagami meteorite samples were determined by electron microprobe; abundances of trace elements Ni, Cu, Zn, and Ga were obtained by synchrotron X-ray (SXRF) microprobe. Abundances of Ni and Cr in the magnesian zones and cores are partially decoupled from abundances of other compatible (Mg) and incompatible (Fe,Ti) elements. The textures, chemical zoning, and element decouplings in the pigeonites are consistent with igneous crystal growth at moderate cooling rates, not isothermally or near equilibrium. From element partitioning and mass balance, Zagami is estimated to contain 20 +/- 5 percent or less cumulus pyroxene (half augite and half pigeonite), half the proportion suggested by equilibrium distribution of Fe/Mg between pigeonite and melt. This inconsistency may be resolved if all pigeonite/melt element partitioning was affected by the rapid growth of the pigeonites. The inference that the pyroxene zoning patterns reflect only magmatic events is consistent with an igneous age of 180 m.y. for Zagami.
Major-element abundances in 11 C, C?, and TCA cosmic dust particles have been measured using SEM and TEM energy dispersive X-ray (EDX) systems. The Fe/Ni ratio, when coupled with major element abundances, appears to be a useful discriminator of cosmic particles. Three particles classified as C?, but having Fe/Ni peak height ratios similar to those measured on the powdered Allende meteorite sample in their HSC EDX spectra, exhibit chondritic minor-/trace-element abundance patterns, suggesting they are extraterrestrial. The one particle classified as C-type, but without detectable Ni in its JSC EDX spectrum, exhibits an apparently nonchondritic minor-/trace-element abundance pattern. A class of particles that are chondritic except for large depletions in the volatile elements Zn and S has been identified. It is likely that these particles condensed with a C1 abundance pattern and that Zn and S were removed by some subsequent process.
The existence of two populations of stony micrometeorites of distinctly different densities would result in significantly different orbital evolution properties for particles from each group. The densities inferred from deceleration of meteors in the earth's atmosphere suggest a substantial amount of the meteoric material has densities of 1 g/cu cm or less (Verniani, 1973). However, measurements of microcraters on lunar rock surfaces led Brownlee et al. (1973) to the conclusion that most micrometeoroids impacting the moon had densities in the 2-4 g/cu cm range, and low-density micrometeoroids were rare. The recovery of stony micrometeorites from the earth's stratosphere after atmospheric deceleration provides the opportunity to resolve the discrepancies. Here, the densities of 12 stony micrometeorites are determined, using synchrotron X-ray fluorescence to infer the particle mass and optical microscope measurements of the volumes. The particles fall into two distinct density groups, with mean values of 0.6 and 1.9 g/cu cm. The factor of 3 difference in the mean densities between the two populations implies differences in the orbital evolution time scales.
Optical microscopy and synchrotron X-ray fluorescence (SXRF) are used to analyze the chemical composition of seven dark-appearing cosmic-dust particles obtained in the stratosphere during NASA Johnson Large Area Collector flights. The experimental setup and procedures are outlined, and the results are presented in extensive tables. Three of the particles had abundances similar to those of chondrites (except for low Ca values in one particle); two had a metallic appearance and spectra dominated by Fe and Zn; one contained Cu and Cr plus small amounts of Fe and Zn; and one had igneous-type abundances of minor and trace elements while containing all of the elements seen in chondritic particles, suggesting it may be of extraterrestrial origin.
Trace element abundance determinations were performed using synchrotron X-ray fluorescence on nine particles collected from the stratosphere and classified as cosmic. Improvements to the Synchrotron Light Source allowed the detection of all elements between Cr and Mo, with the exceptions of Co and As, in our largest particle. The minor and trace element abundance patterns of three Ni-depleted particles were remarkably similar to those of extraterrestrial igneous rocks. Fe/Ni and Fe/Mn ratios suggest that one of these may be of lunar origin. All nine particles exhibited an enrichment in Br, ranging from 1.3 to 38 times the C1 concentration. Br concentrations were uncorrelated with particle size, as would be expected for a surface correlated component acquires from the stratosphere.
Interplanetary dust represents a potential source of environmentally important chemical species in the earth's atmosphere. Previous studies have used computational models of atmospheric evolution of meteor debris to conclude that the steady-state stratospheric component of extraterrestrial matter is a small fraction of the total aerosol load. Observational data suggest such calculations may underestimate stratospheric residence times and, thus, concentrations. Two computational methods were employed here to obtain reasonable limits for the stratospheric contents of halogens and sulfur from extraterrestrial sources. The lower limit was based on the total stratospheric aerosol load and the relative influxes from interplanetary dust and tropospheric sources. The upper limit was obtained using a viscous settling method. These results suggest that the steady-state extraterrestrial influxes of halogens are minor compared to tropospheric sources but the sulfur input may be comparable to the present observed stratospheric content. Temporal enhancements in the meteoroid flux, such as passage through comet debris lanes or impact by large bodies, may produce significant chemical perturbations in the atmosphere.
Trace element analyses were performed on bulk cosmic dust particles by Proton Induced X Ray Emission (PIXE) and Synchrotron X Ray Fluorescence (SXRF). When present at or near chondritic abundances the trace elements K, Ti, Cr, Mn, Cu, Zn, Ga, Ge, Se, and Br are presently detectable by SXRF in particles of 20 micron diameter. Improvements to the SXRF analysis facility at the National Synchrotron Light Source presently underway should increase the range of detectable elements and permit the analysis of smaller samples. In addition the Advanced Photon Source will be commissioned at Argonne National Laboratory in 1995. This 7 to 8 GeV positron storage ring, specifically designed for high-energy undulator and wiggler insertion devices, will be an ideal source for an x ray microprobe with one micron spatial resolution and better than 100 ppb elemental sensitivity for most elements. Thus trace element analysis of individual micron-sized grains should be possible by the time of the comet nucleus sample return mission.