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Wright, Ruishu [NETL] (ORCID:0000000260849220)

Publications and source records attributed to Wright, Ruishu [NETL] (ORCID:0000000260849220).

Hydrogen Detection via a Low-Cost Prototype Fiber-Optic Sensing System

The developed low-cost prototype sensing system successfully detects hydrogen concentrations across a wide range, demonstrating immediate feasibility for commercial deployment. Utilizing fiber-optic technology, the system delivers stable, reproducible performance from parts-per-million levels up to 100% pure H2 environments. Environmental and chemical cross-sensitivity evaluations confirm robust selectivity against methane and temperature changes, establishing its readiness for near-term commercialization.

fiber-optic H2 sensor↗

Detecting rare earth elements via optically detected magnetic resonance (ODMR) and spin-relaxometry using nitrogen vacancy centers in nanodiamonds

Nanodiamonds embedded with nitrogen-vacancy (NV) centers are emerging as powerful tools in quantum sensing due to their remarkable sensitivity to local variations in electromagnetic fields, temperature, and pressure. These point defects in the diamond lattice can be probed using optically detected magnetic resonance (ODMR) and spin relaxometry techniques, allowing for the detection and characterization of magnetic nanoparticles and ions. The sensing mechanism relies on laser-induced excitation of the NV center's non-degenerate triplet ground state, which promotes electrons to an excited state. Subsequent photoluminescence (PL) emission, which is spin-state dependent, is then measured. These spin states are highly responsive to magnetic perturbations in the surrounding environment. By analyzing changes in the ODMR spectra and spin relaxation times, we can effectively monitor how magnetic species influence the NV center's spin dynamics, thus enabling sensitive and selective characterization of nanoscale magnetic materials. These techniques have been applied for the characterization of transition metals and rare earth elements which shows natural ferromagnetic properties.

magnetic nanopartgicles and ions↗

Pilot-Scale Validation of Distributed Optical Fiber Sensors for Underground Pipeline Monitoring

Monitoring parameters such as hoop strain, pressure, and acoustic vibrations is key to detecting potential leaks, intrusions, or structural issues. Distributed optical fiber sensor (DOFS) systems provide a compelling solution for continuous, real-time monitoring over long distances. This paper details the development and pilot-scale implementation of DOFS systems for underground pipeline monitoring, evolving from a proof-of-concept stage. Multiple custom-designed DOFS interrogator units—such as optical frequency-domain reflectometry (OFDR), Brillouin optical time-domain analysis (BOTDA), and multimodal interferometer-based fiber acoustic sensor systems were tested to measure the key parameters, such as hoop strain, pipe pressure, surrounding soil temperature, and acoustic vibrations. The underground product pipeline’s outer diameter is 30 inches, the wall thickness is 1.28 inches, and 3 feet deep from the surface. The fiber deployment strategies and sensing data acquisition methods for these systems are discussed. The results demonstrate the effectiveness of DOFS in detecting hoop strain, temperature changes, and acoustic vibrations, showcasing their potential for real-time monitoring and enhancing pipeline safety. These findings from pilot-scale testing offer valuable insights into advancing pipeline monitoring technologies and improving the reliability of underground pipeline systems.

fiber optic sensors↗

Improving Stability of an Optical Fiber pH Sensor with a Calcined Polyethylenimine-Coating at High Pressures and Temperatures

With an increased interest in subsurface gas storage technology for various energy applications, monitoring wellbore structural stability and subsurface geochemistry has become more pressing, and pH is a key parameter to measure. As high pressure and elevated temperatures in subsurface conditions are comparatively harsh relative to that expected for most standard pH sensor designs, any pH monitoring hardware must be designed for extended exposure to high pressures and temperatures. We previously reported that an optical fiber pH sensor functionalized with a calcined polyethylenimine coating had shown some promise as a high temperature and pressure pH sensor but with some drifting when operating for longer than 8 hours. In this paper, we investigated the coating composition and potential cause of the drifting and improved the stability of the prepared coating to minimize sensor drift under simulated wellbore conditions. Scanning electron microscopy (SEM) had previously shown moderate cracking at high pressures over short tests. By applying X-ray photoelectron spectroscopy (XPS) to characterize the sensor coating before and after one week of testing in an H2/CH4 gas blend at 80 °C and 900 psi, a compositional change in the coating was observable, which may indicate susceptibility to alteration by subsurface gas storage conditions. Non-reducing (CH4, N2) environments were also tested, and confirmed that both temperature and pressure were also contributing to the drift.

energy infrastructure↗

Fusion of Experiments and Simulations for Real-Time Identification of Pipeline Defects

In this study, we explored fusion of experiments and simulations for real time identification of pipeline defects across physical and non-physical domains. The challenges associated to data processing were addressed and a combined classification models was presented via CNN models. In addition, regression model based on XGBOOST is built to determine the defect location and defect dimension from data-driven features of guided wave signals captured by SMS fiber optic sensor.

deep learning↗

Improving Stability of an Optical Fiber pH Sensor with a Calcined Polyethylenimine-Coating at High Pressures and Temperatures

With an increased interest in subsurface gas storage technology for various energy applications, monitoring wellbore structural stability and subsurface geochemistry has become more pressing, and pH is a key parameter to measure. As high pressure and elevated temperatures in subsurface conditions are comparatively harsh relative to that expected for most standard pH sensor designs, any pH monitoring hardware must be designed for extended exposure to high pressures and temperatures. We previously reported that an optical fiber pH sensor functionalized with a calcined polyethylenimine coating had shown some promise as a high temperature and pressure pH sensor but with some drifting when operating for longer than 8 hours. In this paper, we investigated the coating composition and potential cause of the drifting and improved the stability of the prepared coating to minimize sensor drift under simulated wellbore conditions. Scanning electron microscopy (SEM) had previously shown moderate cracking at high pressures over short tests. By applying X-ray photoelectron spectroscopy (XPS) to characterize the sensor coating before and after one week of testing in an H2/CH4 gas blend at 80°C and 900 psi, a compositional change in the coating was observable, which may indicate susceptibility to alteration by subsurface gas storage conditions. Non-reducing (CH4, N2) environments were also tested, and confirmed that both temperature and pressure were also contributing to the drift.

energy infrastructure↗

Fusion of Experiments and Simulations for Real-Time Identification of Pipeline Defects

In this study, we explored fusion of experiments and simulations for real time identification of pipeline defects across physical and non-physical domains. The challenges associated to data processing were addressed and a combined classification models was presented via CNN models. In addition, regression model based on XGBOOST is built to determine the defect location and defect dimension from data-driven features of guided wave signals captured by SMS fiber optic sensor.

deep learning↗

Pilot-Scale Validation of Distributed Optical Fiber Sensors for Underground Pipeline Monitoring

Distributed fiber optic sensing is a cutting-edge technology that has found extensive applications in the monitoring of Ensuring the safety, integrity, and operational efficiency of underground product pipelines is vital for maintaining the nation’s critical infrastructure. Monitoring parameters such as hoop strain, pressure, and acoustic vibrations is key to detecting potential leaks, intrusions, or structural issues. Distributed optical fiber sensor (DOFS) systems provide a compelling solution for continuous, real-time monitoring over long distances. This paper details the development and pilot-scale implementation of DOFS systems for underground pipeline monitoring, evolving from a proof-of-concept stage. Multiple custom-designed DOFS interrogator units—such as optical frequency-domain reflectometry (OFDR), Brillouin optical time-domain analysis (BOTDA), and multimodal interferometer-based fiber acoustic sensors—were employed to measure key parameters like hoop strain, pressure, and acoustic vibrations. The underground product pipeline's outer diameter is 30 inches, the wall thickness is 1.28 inches, and the 3-foot depth. The fiber deployment strategies, and sensing data acquisition methods for these systems are discussed. The results demonstrate the effectiveness of DOFS in detecting hoop strain, temperature changes, and acoustic vibrations, showcasing their potential for real-time monitoring and enhancing pipeline safety.

distributed fiber sensing↗

Efficient Signal Processing in BOTDA: Utilizing PCA and PCA-Based Neural Networks for Temperature Monitoring

This work presents a comparative analysis of the various signal processing techniques used in the Brillouin gain spectrum (BGS) peak estimation. Traditional fitting methods such as Lorentzian curve fitting (LCF) are slow and less effective in noisy data. PCA-based methods were tested on the experimental data: A Euclidian distance-based approach, and a probabilistic deep neural network (PDNN) based approach, both using 5 principal components to represent a single BGS. Both methods significantly reduce computational time with respect to LCF, whereas PDNN offers uncertainty insights along with the parameter value. Measuring a range of temperatures, analyzing accuracy, and speed, it can be concluded that PCA trained PDNN outperforms other methods, and appears to be helpful in scenario where large datasets are generated.

Brillouin optical time domain analysis↗

Brillouin Sensing with PCA, and PCA-Based Neural Networks for Efficient Temperature Monitoring

This work explores peak estimation techniques in Brillouin Optical Time Domain Analysis (BOTDA), emphasizing both accuracy and efficiency. Euclidean distance measurement method is applied to principal components derived from Brillouin Gain Spectrum data. It offers a major speed advantage being 180 170 times faster than traditional curve fitting methods such as Lorentzian curve fitting, while maintaining similar accuracy. Additionally, a PCA- based neural network model shows significant reduction of peak estimation time compared to Lorentzian fitting. Results show Brillouin frequency shift errors lie under 0.75 MHz in both Euclidean distance-based and neural network-based methods, both of which utilize PCA components. For large data sets and long length fibers, PCA- assisted neural network for peak estimation would be an efficient solution.

Distributed optical fiber sensing↗

Optical Fiber H2 Sensor Operating in Harsh Environments of Subsurface H2 Storage Reservoirs

Monitoring hydrogen concentration in the subsurface storage reservoirs is vital to ensure the integrity and safety of the storage facilities. An optical fiber hydrogen sensor consisting of a palladium-based sensing layer and a protective polymer layer was developed and evaluated in simulated subsurface hydrogen storage conditions. The developed optical fiber hydrogen sensor has demonstrated successful sensing performance at ~80 °C, ~1,000 psi, and ~100% RH. In addition, the sensor was exposed to real subsurface microbial samples in the harsh environments to monitor microbially induced changes in hydrogen concentration. The sensor has shown stable H2 sensing responses in the replicated underground hydrogen storage conditions without deterioration or loss of H2 sensitivity in the presence of biological samples.

filter layer↗

Fe-Coated Optical Fiber for Distributed Corrosion Monitoring in Soil and Aqueous Environment

Natural gas pipeline corrosion represents a substantial cost and safety concern during normal operations. The effective and real-time monitoring of corrosion is important to detect and mitigate pipeline risks before corrosion-related catastrophic events happen. Here, we describe the use of iron (Fe) coated optical fiber sensors (OFS) for distributed corrosion monitoring where Fe acts as a corrosion proxy. By using an optical backscattering reflectometer (OBR), corrosion was monitored based on the increase in the backscattered intensity amplitude of the light being passed as Fe underwent corrosion. The Fe-coated OFSs were prepared with a film thickness between 25–225 nanometers (nm) by an electroless plating approach and corroded by a carbon dioxide (CO2)-saturated acidic electrolyte. The corrosion rate (CR) was approximately 2.5 millimeters (mm)/year for Fe with a film thickness of 30 nm and increased with film thickness. Backscattering-based CRs were supported by visible light transmission measurements, which have been previously demonstrated. Additionally, a correlation between the intermittent transmission and residual Fe film thickness during the corrosion of Fe was established. The corrosion sensor was also tested in soil at > 1 foot depth. Fe-coated OFS was loaded into a Draka cable, which provides mechanical support during fiber deployment and installation into either acidified soil, top-soil, or sandy soil (50/50).

corrosion↗

Fe-Coated Optical Fiber for Distributed Corrosion Monitoring in Soil and Aqueous Environments

Natural gas pipeline corrosion represents a substantial cost and safety concern during normal operations. The effective and real-time monitoring of corrosion is important to detect and mitigate pipeline risks before corrosion-related catastrophic events happen. Here, we describe the use of iron (Fe) coated optical fiber sensors (OFS) for distributed corrosion monitoring where Fe acts as a corrosion proxy. By using an optical backscattering reflectometer (OBR), corrosion was monitored based on the increase in the backscattered intensity amplitude of the light being passed as Fe underwent corrosion. The Fe-coated OFSs were prepared with a film thickness between 25–225 nanometers (nm) by an electroless plating approach and corroded by a carbon dioxide (CO2)-saturated acidic electrolyte. The corrosion rate (CR) was approximately 2.5 millimeters (mm)/year for Fe with a film thickness of 30 nm and increased with film thickness. Backscattering-based CRs were supported by visible light transmission measurements, which have been previously demonstrated. Additionally, a correlation between the intermittent transmission and residual Fe film thickness during the corrosion of Fe was established. The corrosion was measurable out to > 100 meters (m), which is a significant improvement over our previous work, which showed corrosion sensing at < 10 m. The corrosion sensor was also tested in soil at > 1 foot depth.

corrosion↗

Fe-Coated Optical Fiber for Distributed Corrosion Monitoring in Soil and Aqueous Environments

Natural gas pipeline corrosion represents a substantial cost and safety concern during normal operations. The effective and real-time monitoring of corrosion is important to detect and mitigate pipeline risks before corrosion-related catastrophic events happen. Here, we describe the use of iron (Fe) coated optical fiber sensors (OFS) for distributed corrosion monitoring where Fe acts as a corrosion proxy. By using an optical backscattering reflectometer (OBR), corrosion was monitored based on the increase in the backscattered intensity amplitude of the light being passed as Fe underwent corrosion. The Fe-coated OFSs were prepared with a film thickness between 25–225 nanometers (nm) by an electroless plating approach and corroded by a carbon dioxide (CO2)-saturated acidic electrolyte. The corrosion rate (CR) was approximately 2.5 millimeters (mm)/year for Fe with a film thickness of 30 nm and increased with film thickness. Backscattering-based CRs were supported by visible light transmission measurements, which have been previously demonstrated. Additionally, a correlation between the intermittent transmission and residual Fe film thickness during the corrosion of Fe was established. The corrosion was measurable out to > 100 meters (m), which is a significant improvement over our previous work, which showed corrosion sensing at < 10 m. The corrosion sensor was also tested in soil at > 1 foot depth.

aqueous environment↗

Fe Coated Optical Fiber for Distributed Corrosion Monitoring in Soil and Aqueous Environment

Natural gas pipeline corrosion represents a substantial cost and safety concern during normal operations. Effective monitoring of corrosion is important to detect and mitigate pipeline risks before corrosion-related catastrophic events happen. Here, we describe the use of Fe-coated optical fiber sensors (OFS) for distributed corrosion monitoring where Fe acts as a corrosion proxy. By using an optical backscatterring reflectometer (OBR), corrosion was monitored based on the increase in backscattered intensity amplitude of the light being passed as Fe undergoes corrosion. The Fe-coated OFSs were prepared with a film thickness between 25-225 nm by an electroless plating approach and corroded by a CO2-saturated acidic electrolyte. The corrosion rate was approximately 2.5 mm/yr for Fe with a film thickness of 30 nm and increased with film thickness. Backscattering-based corrosion rates were supported by visible light transmission measurements, which have been previously demonstrated. Additionally, a correlation between the intermittent transmission and residual Fe film thickness during corrosion of Fe was established. Corrosion was measurable out to > 100 m which is a significant improvement over our previous work showing corrosion sensing at < 10 m. The corrosion sensor was also tested in soil at >1 ft depth. Fe-coated OFS was loaded into a Draka cable which provides mechanical support during fiber deployment and installation into either acidified soil, top-soil, or sandy soil.

aqueous environment↗