A method to estimate critical volumes

Abstract

Methods for estimating the volume of the critical temperature used for the estimation of thermodynamic properties of substances are described. The possibility to estimate the critical temperature by using a combination of only eighteen atomic and structural contributions is shown. These contributions are listed and the critical temperature is given by a linear expression. By comparing the Vetere (1976) and Lydersen (1955) methods with the method discussed it is noted that while all three methods yield about the same average error (about 3%), the new method is superior in that it requires a smaller number of increments to fit data points.