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DOE OSTI · 1240259

Technologies for pre-screening IAEA swipe samples

Smith, Nicholas A.·Steeb, Jennifer L.·Lee, Denise L.·Huckabay, Heath A.·Ticknor, Brian W.
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Abstract

During the course of International Atomic Energy Agency (IAEA) inspections, many samples are taken for the purpose of verifying the declared facility activities and identifying any possible undeclared activities. One of these sampling techniques is the environmental swipe sample. Due to the large number of samples collected, and the amount of time that is required to analyze them, prioritizing these swipes in the field or upon receipt at the Network of Analytical Laboratories (NWAL) will allow sensitive or mission-critical analyses to be performed sooner. As a result of this study, technologies were placed into one of three categories: recommended, promising, or not recommended. Both neutron activation analysis (NAA) and X-ray fluorescence (XRF) are recommended for further study and possible field deployment. These techniques performed the best in initial trials for pre-screening and prioritizing IAEA swipes. We learned that for NAA more characterization of cold elements (such as calcium and magnesium) would need to be emphasized, and for XRF it may be appropriate to move towards a benchtop XRF versus a handheld XRF due to the increased range of elements available on benchtop equipment. Promising techniques that will require additional research and development include confocal Raman microscopy, fluorescence microscopy, and infrared (IR) microscopy. These techniques showed substantive responses to uranium compounds, but expensive instrumentation upgrades (confocal Raman) or university engagement (fluorescence microscopy) may be necessary to investigate the utility of the techniques completely. Point-and-shoot (handheld) Raman and attenuated total reflectance–infrared (ATR-IR) measurements are not recommended, as they have not shown enough promise to continue investigations.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL PROTECTIONCALCIUMEQUIPMENTFLUORESCENCEIAEAIAEA SAFEGUARDSINFRARED RADIATIONINSPECTIONMAGNESIUMMICROSCOPYNEUTRON ACTIVATION ANALYSISOPTIMIZATIONRECOMENDATIONSSafeguardsSAMPLINGURANIUM COMPOUNDSX-RAY FLUORESCENCE ANALYSIS

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Smith, Nicholas A., Steeb, Jennifer L., Lee, Denise L., Huckabay, Heath A., Ticknor, Brian W.. 2015-11-09. Technologies for pre-screening IAEA swipe samples. https://doi.org/10.2172/1240259

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