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DOE OSTI · 1762740

Controlled current-rate AC flash sintering of uranium dioxide

Ingraci Neto, Rubens R.·McClellan, Kenneth James·Byler, Darrin David·Kardoulaki, Erofili
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Abstract

Uranium dioxide (UO2) pellets with controlled microstructures were densified up to 93.4% of their theoretical density in less than 25 minutes at a furnace temperature of 873 K, utilizing controlled current-rate alternating current (AC) flash sintering (FS). Using this AC-FS method it was possible to control the sintering rate and thermal gradients, resulting in dense pellets with no appreciable hourglassing and good mechanical integrity. Moreover, the apparent sintering activation energy for FS and for conventionally sintered samples was estimated to be 108 kJ mol -1 and 380 kJ mol -1 , respectively using the master sintering curve method. The apparent activation energy for FS was remarkably close to those reported in the literature for spark plasma sintering of UO 2 . Furthermore, both these field assisted sintering methods utilize fast heating rates and electrical effects that are likely enhancing the grain boundary diffusion mechanism. Finally controlled current-rate AC-FS has been demonstrated as a technological advancement, capable of producing ceramic nuclear fuels in a fraction of the conventional processing time.

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11 NUCLEAR FUEL CYCLE AND FUEL MATERIALSAnisotropic shrinkageField assisted sinteringFlash sinteringMaster sintering curveNuclear fuelUranium dioxide

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Ingraci Neto, Rubens R., McClellan, Kenneth James, Byler, Darrin David, Kardoulaki, Erofili. 2021-01-14. Controlled current-rate AC flash sintering of uranium dioxide. https://doi.org/10.1016/j.jnucmat.2021.152780

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