DOE OSTI · 1836286
Evaluating Laser-Induced Breakdown Spectroscopy Sensor Technology for Rapid Source Characterization of Rare Earth Elements
Abstract
A prototype Laser Induced Breakdown Spectroscopy (LIBS) sensor is tested for the determination of rare earth elements (Eu and Yb) in liquid and solid samples. The sensor head, built using a monolithic passively Q-switched (PQSW) Nd:YAG laser, produced a 1064 nm laser beam with 3.3 ns pulses and an energy of 4.2 mJ. The measurements show good calibration linearity for both Eu and Yb with R 2 values above 0.99 for all analyzed spectral lines in liquid and solid samples. Limits of Detection (LODs) obtained were as low as 1 ppm, which are comparable to or better than those reported previously by using table top actively Q-switched systems. This study aims to develop a high sensitivity, field deployable sensor for characterizing existing and new sources of rare earth elements
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Hartzler, Daniel A., Bhatt, Chet R., Jain, Jinesh C., McIntyre, Dustin L.. 2019-03-11. Evaluating Laser-Induced Breakdown Spectroscopy Sensor Technology for Rapid Source Characterization of Rare Earth Elements. https://doi.org/10.1115/1.4042747
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