Electron transitions in a Ce(iii)-catecholate metal–organic framework

Knapp, Julia G.; Ray, Debmalya; Calio, Paul B.; Wasson, Megan C.; Scott, Thais R.; Gagliardi, Laura; Farha, Omar K.

doi:10.1039/d1cc06440a

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Electron transitions in a Ce(iii)-catecholate metal–organic framework

Knapp, Julia G.·Ray, Debmalya·Calio, Paul B.·Wasson, Megan C.·Scott, Thais R.·Gagliardi, Laura·Farha, Omar K.

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Abstract

A rare three-dimensional catecholate-based Ce(III) metal–organic framework (MOF), denoted as NU-1701, has been synthesized and crystallographically characterized. Density functional theory calculations highlight various possible electronic transitions that may present in NU-1701. These transitions are competitive and indicate increased lanthanide character of Ce(III).

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Knapp, Julia G., Ray, Debmalya, Calio, Paul B., Wasson, Megan C., Scott, Thais R., Gagliardi, Laura, Farha, Omar K.. 2021-12-15. Electron transitions in a Ce(iii)-catecholate metal–organic framework. https://doi.org/10.1039/d1cc06440a

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